Ferroan calcite replacement indicates former magnesian calcite skeletons

The replacement by ferroan calcite with preservation of the original structures can be used as a new criterion for identifying skeletons originally composed of high-magnesian calcite. This applies to bryozoa, rugose corals, echinoderms, many foraminifera, most ostracods, red algae, and serpulids. On the other hand, skeletons originally composed of low-magnesian calcite were never replaced by ferroan calcite, as shown by belemnites, brachiopods, and most of the pelecypods. Using this criterion, an original low-magnesian calcite composition is inferred for Tentaculites and some ostracods and foraminifera, whereas a previous high-magnesian calcite composition is inferred for trilobites, oligostegina and certain ooids. Chemical instability of high-magnesian calcite is suggested to be the driving force of the replacement by ferroan calcite. In most of the thirty-seven samples investigated, of Oligocene to Devonian age, the ferrous iron concentration of the interstitial fluid increased during diagenesis, as shown by well established sequences of cement A and B and fissure fill. This offers a relative time scale for diagenetic processes. Ferroan calcites contain up to 6 mol % FeCO₃ and up to 5 mol % MgCO₃. In this range of concentration, the distribution coefficients for Fe and Mg between calcite and solution at about 25°C are about 1 to 0-03, respectively, according to experiments. Possible sources of iron are iron oxides and hydroxides as well as clay minerals including glauconite. Though a submarine origin below the sediment surface is conceivable for ferroan calcite, there are serious limiting conditions such as low Eh and, at the same time, lack in sulphate-reducing bacteria. On the other hand, ferroan ‘dedolomite’, compositional zonality in individual ferroan calcite overgrowths, low δ¹⁸C and δ¹⁸O values, and low Mg concentrations point more to a meteoric-phreatic origin of many ferroan calcite occurrences.     

Reconciliation of excess 14C-constrained global CO2 piston velocity estimates

Oceanic excess radiocarbon data is widely used as a constraint for air–sea gas exchange. However, recent estimates of the global mean piston velocity  〈 k 〉  from Naegler et al., Krakauer et al., Sweeney et al. and Müller et al. differ substantially despite the fact that they all are based on excess radiocarbon data from the GLODAP data base. Here I show that these estimates of  〈 k 〉  can be reconciled if first, the changing oceanic radiocarbon inventory due to net uptake of CO₂ is taken into account; second, if realistic reconstructions of sea surface  Δ¹⁴C  are used and third, if  〈 k 〉  is consistently reported with or without normalization to a Schmidt number of 660. These corrections applied, unnormalized estimates of  〈 k 〉  from these studies range between 15.1 and 18.2 cm h⁻¹. However, none of these estimates can be regarded as the only correct value for  〈 k 〉  . I thus propose to use the 'average' of the corrected values of  〈 k 〉  presented here (16.5 ± 3.2 cm h⁻¹) as the best available estimate of the global mean unnormalized piston velocity  〈 k 〉  , resulting in a gross ocean-to-atmosphere CO₂ flux of 76 ± 15 PgC yr⁻¹ for the mid-1990s.     

Sedimentology and architecture of the Douglas Creek terminal splay,Lake Eyre,central Australia

Douglas Creek terminal splay, sited on the western shoreline of Lake Eyre North, central Australia, covers a surface area of approximately 4 km² with a down‐system length of 2·5 km from the distributary channels terminus to the splay fringe. Two distributary channels feed two sediment lobes which have amalgamated to form the terminal splay. Three primary facies associations have been identified sub‐dividing the creek terminus into distributary channel, proximal and distal splay sections. Proximal splay sediments are characterized by erosionally based, relatively thick (> 100 mm), stacked sheets of coarse to medium sand which commonly display trough and planar cross‐bedding, whereas the distal splay is characterized by thin (generally < 50 mm) massive beds of very fine sand, silt and clay. The change in splay sedimentology is interpreted as reflecting the transition from bedload‐dominated deposition to suspended load‐dominated deposition from decelerating sheetfloods as they spread out from the channel onto the dry lake bed. A proximal to distal splay transition zone is also noted where deposits of both facies associations interfinger laterally and vertically. In scale, geometry and facies associations, the Douglas Creek terminal splay is very different to the often cited Neales terminal splay complex located 70 km to the north. It is suggested that these architectural differences reflect variations in discharge volume, input sediment distribution and the degree of vegetation cover. Understanding the variation in terminal splay architecture has very significant implications for the modelling of analogous subsurface petroleum systems, which at present relies on few modern‐day analogues.     

Magmatic Differentiation in the Uwekahuna Laccolith, Kilauea Caldera, Hawaii

Petrographic and chemicoal studies of a suite of rocks fromthe Uwekahuna laccolith of Kilauea Volcano show that the originalmafic tholeiitic magma differentiated into tholeiitic picrite,tholeiitic olivine gabbro, and an aphanitic rock approachingquartz-basalt in composition. Mechanisms involved were an initialgravity settling of olivine and a final filter pressing of theresidual liquid. The range of composition represented by therocks of the laccolith is as great as that found among all hithertoanalysed lavas of the volcano. ²Present address: U.S. Geological Survey, Menlo Park, California     

Tsunami backwash deposits with Chicxulub impact ejecta and dinosaur remains from the Cretaceous–Palaeogene boundary in the La Popa Basin,Mexico

The La Popa Basin in north‐eastern Mexico features outstanding, continuous three‐dimensional exposures of the Cretaceous–Palaeogene boundary event deposit in shallow shelf environments pierced by salt stocks. In the area to the south‐east of the El Papalote diapir, the Cretaceous–Palaeogene deposit consists of two superimposed sedimentary units and erosively overlies upper Maastrichtian sand‐siltstones with soft‐sediment deformation and liquefaction structures. The basal unit 1 is an up to 8 m thick chaotic, carbonate‐rich bed that discontinuously fills incised gutters and channels. Besides abundant silicic and carbonate ejecta spherules from the Chicxulub impact, unit 1 includes large sandstone boulders and abundant shallow‐water debris (for example, mud clasts, algae, bivalve shells, gastropod shells and vertebrate remains). Unit 1 is conformably overlain by unit 2. Distal to the diapir, unit 2 consists of a centimetre to decimetre‐thick conglomeratic, coarse bioclast and spherule‐bearing sandstone bed. Closer to the diapir, unit 2 becomes a metre‐thick series of four to eight conglomeratic to fine‐grained graded sandstone beds rich in shell debris and ejecta spherules. Unit 2 is conformably overlain by structureless to parallel laminated sandstone beds that may mark the return to the pre‐event depositional regime. The sedimentary characteristics of the Cretaceous–Palaeogene deposit, including its erosive base, its sheet‐like geometry, the presence of multiple, graded beds, evidence for upper flow regime conditions and the absence of bioturbation, support an origin by a short‐term multiphase depositional event. The occurrence of soft‐sediment deformation structures (for example, liquefaction) below the Cretaceous–Palaeogene deposit suggests that earthquakes were the first to occur at La Popa. Then, shelf collapse and strong backflow from the first tsunami waves may have triggered erosion and deposition by violent ejecta‐rich hyperconcentrated density flows (unit 1). Subsequently, a series of concentrated density flows resulting from tsunami backwash surges may have deposited the multiple‐graded bedding structures of unit 2. The specific depositional sequence and the Fe‐Mg‐rich as well as Si‐K‐rich composition of the ejecta spherules both provide a critical link to the well‐known deep marine Cretaceous–Palaeogene boundary sites in the adjacent Burgos basin in north‐eastern Mexico. Moreover, the pulse‐like input of Chicxulub ejecta material at the base of the event deposit allows for correlation with other Cretaceous–Palaeogene boundary sites in the Gulf of Mexico and the Atlantic, as well as in Central and Northern America. The presence of diverse dinosaur and mosasur bones and teeth in the event deposit is the first observation of such remains together with Chicxulub ejecta material. These findings indicate that dinosaurs lived in the area during the latest Maastrichtian and suggest that the tsunami waves not only eroded deltas and estuaries but the coastal plain as well.