Mechanism of enrichment of trace metals on fine sludges collected from filtration plants

Fine sludges were collected from five filtration plants, and the partitioning of ten metals (Ag, Cd, Mn, Zn, Pb, Cu, Sn, Co, Ni, and Fe) in them was determined by selective leaching techniques. (1) The available amounts, which shows the total of each metal leached between 1 M CH₃COONH₄ and 30 percent H₂O₂, for Ag, Cd and Mn, ranged from 51 to 98 percent for five sludges. (2) The available amounts for Zn, Pb, Cu, and Sn were 47–92 percent for five sludges. (3) The most important fraction for Co, Ni, and Fe, except the Inagawa sludge, which is markedly polluted by organic matter, was the crystalline particle. Therefore, the above metals, except Co, Ni, and Fe, are thought to be enriched on ion-exchangeable sites, organic matter, hydrous Fe/Mn oxides, and sulfides in fine sludges.     

Polar and neutral isopranyl glycerol ether lipids as biomarkers of archaea in near-surface sediments from the Nankai Trough

The molecular and carbon isotopic compositions of polar isopranyl glycerol ether lipids, which are direct indicators of viable archaea, and neutral isopranyl glycerol ether lipids, which are derived from polar lipids via hydrolysis, in near-surface sediments from a methane seep in the Nankai Trough (off central Japan) were investigated. Procedures for extracting, separating and derivatizing polar and neutral ether lipids for detection using gas chromatography were first examined with one sediment sample and a cultivated methanogen. For all sediment samples, archaeol and hydroxyarchaeol were detected in both the polar and neutral ether lipid fractions. Acyclic and cyclic biphytanes were also detected in both types of lipid fractions after treatment with HI/LiAlH₄ for ether cleavage and alkylation. The δ¹³C values of archaeol, sn-2-hydroxyarchaeol, and sn-3-hydroxyarchaeol in the sample from 0.82 m below the seafloor were lower than −100‰ relative to PDB, indicating that diverse living methanotrophic archaea are present in the seep sediments. Biphytanes released from polar ether lipids in the same sample were less depleted in δ¹³C (−71‰ to −36‰). The wide range of δ¹³C values suggests that the biphytanes were derived not only from methanotrophic but also from non-methanotrophic archaea, and that the relative contributions of the methanotrophic and non-methanotrophic archaea differed, depending on the biphytane compound. The vertical profiles and δ¹³C values of the neutral ether lipids were similar to those of the intact polar ether lipids, suggesting that neutral ether lipids derived from fossil archaea in the samples had mainly been lost by the time of sampling.     

RbSr dating of the Yatsushiro granite and gneiss,Kyushu, Japan

RbSr measurements on the Yatsushiro granite and gneiss, which had been considered stratigraphically to be of possible Precambrian age, are reported. The whole rock isochron for the granite gives an age of 352 ± 8 my with a low initial⁸⁷Sr/⁸⁶Sr ratio of 0.7037 ± 0.0006. Data for constituent minerals of the granites are dispersed irregularly around the whole rock isochron (possibly by later tectonic events). For the gneiss, a metamorphic event around 410 my is indicated by the muscovite RbSr ages. The present results do not support the possibility that the Yatsushiro granite and gneiss are Precambrian in age.     

Non‐linear system identification of the versatile‐typed structures by a novel signal processing technique

Non‐linear structural identification problems have raised considerable research efforts since decades, in which the Bouc–Wen model is generally utilized to simulate non‐linear structural constitutive characteristic. Support vector regression (SVR), a promising data processing method, is studied for versatile‐typed structural identification. First, a model selection strategy is utilized to determine the unknown power parameter of the Bouc–Wen model. Meanwhile, optimum SVR parameters are selected automatically, instead of tuning manually. Consequently, the non‐linear structural equation is rewritten in linear form, and is solved by the SVR technique. A five‐floor versatile‐type structure is studied to show the effectiveness of the proposed method, in which both power parameter known and unknown cases are investigated. Copyright © 2007 John Wiley & Sons, Ltd.     

地下RC结构物地震响应特征土工离心试验的模拟

地下结构物抗震稳定性的研究具有重要实际意义。基于动态土工离心试验,应用有效应力法分析了不同水平地震作用下土层和地下RC结构物的最大水平位移、不同埋深的土层加速度和超孔隙水压力变化规律,以及结构物的破坏发展特征,并进一步与试验结果进行了相互验证和对比,取得了较好效果,为重要地下结构物的抗震设计提供了依据和参考。     

A note on climate change adaptation for seaports: a challenge for global ports, a challenge for global society

With 80 % of world trade carried by sea, seaports provide crucial linkages in global supply-chains and are essential for the ability of all countries to access global markets. Seaports are likely to be affected directly and indirectly by climatic changes, with broader implications for international trade and development. Due to their coastal location, seaports are particularly vulnerable to extreme weather events associated with increasing sea levels and tropical storm activity, as illustrated by hurricane “Sandy”. In view of their strategic role as part of the globalized trading system, adapting ports in different parts of the world to the impacts of climate change is of considerable importance. Reflecting the views of a diverse group of stakeholders with expertise in climate science, engineering, economics, policy, and port management, this essay highlights the climate change challenge for ports and suggests a way forward through the adoption of some initial measures. These include both “soft” and “hard” adaptations that may be spearheaded by individual port entities, but will require collaboration and support from a broad range of public and private sector stakeholders and from society at large. In particular, the essay highlights a need to shift to more holistic planning, investment and operation.     

Observation of hydrogen peroxide concentrations in a Japanese red pine forest

In order to study the concentrations of hydrogen peroxide (H₂O₂) and the factors controlling its concentrations, we monitored concentrations of H₂O₂ and other gases such as sulfur dioxide, ozone, and NO _x as well as meteorological factors such as air temperature, relative humidity, and wind direction/speed during eight measurement periods from 2000 to 2002 in a Japanese red pine forest in Japan. The H₂O₂ concentrations ranged from below 0.01 to 1.64 ppb, and analysis of the diurnal variation in H₂O₂ concentration showed high concentrations around noon, and low concentrations in the morning and late afternoon. The H₂O₂ concentrations were high in early summer, when O₃ concentration, temperature, and solar radiation were high, and were low in fall, when O₃ concentration, temperature, and solar radiation were low. We propose that O₃ concentration affects the production of H₂O₂ in the monitored region during the period under study, but that high H₂O₂ concentrations were sometimes caused by the transport of polluted air from urban regions. H₂O₂ concentrations decreased remarkably when SO₂ concentrations increased by transported volcanic emission on Miyake Island. In the absence of the effects of SO₂, H₂O₂ concentrations increased with increasing O₃ concentration and temperature.     

Baroclinic oscillations of tidal frequency at ocean weather station P

Abstract

We analyse time series records of isopleth depths derived from two extended sequences of hourly and bi‐hourly sampled profiles taken at Ocean Weather Station P during the summers of 1961 and 1969. Vertical displacements to 240‐m depth are mainly of semidiurnal frequency with r.m.s. amplitudes of 1–4 m. Displacements at diurnal and near‐inertial frequencies are typically less than a metre and have little statistical significance. Within the semidiurnal band, motions appear to be predominantly at the principal solar (S₂) rather than the principal lunar (M₂) semidiurnal frequency. The phase of the M₂ baroclinic tide is roughly equal to that of the M₂ barotropic tide (as extrapolated from coastal and seamount observations); phases of other constituents differ appreciably from barotropic values.     

Across-arc variation of lava chemistry in the Izu-Bonin Arc: identification of subduction components

In order to understand the role of the subducted lithosphere in producing the geochemical characteristics of arc magmas, major- and trace-element along with Sr- and Nd-isotope compositions have been determined for Quaternary volcanic rocks from the Izu-Bonin intra-oceanic arc. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios decrease away from the volcanic front of this arc and lie on mixing lines between the assumed isotopic compositions of fluid phases mainly derived from the basalt layer of the subducted lithosphere and upper-mantle materials in the sub-arc wedge. This across-arc variation can be explained through a simple sequence of processes involving initial release of fluid phases from the subducted oceanic crust to produce hydrous peridotite at the base of the mantle wedge. This hydrous peridotite is dragged downward with the slab and releases a second-stage metasomatizing fluid beneath the volcanic arc. The higher concentrations of both Sr and Nd in the fluid beneath the volcanic front than those beneath the back-arc side may be a possible cause of the observed across-arc variation in Sr-Nd isotopic ratios. The difference in compositions of fluid phases is attributed to the different hydrous phases which decompose in the hydrous peridotite layer; amphibole beneath the volcanic front and phlogopite beneath the back-arc side of the volcanic arc. The mineralogically controlled fluid addition may also be responsible for the across-arc variation in Rb/K and Rb/Zr ratios, increasing away from the volcanic front.     

Symmetrical fft technique and its applications to earthquake engineering

The objective of this paper is to propose an FFT technique symmetrical for time and frequency, in which the symmetrization is done by introducing generating functions. By the symmetrical treatment, it becomes possible to derive several complementary relations in the time and frequency domains. Based on the idea of the symmetrical FFT technique, the phase problem of seismic waves is discussed not only in the frequency domain but also in the time domain. Furthermore, the deconvolution technique to evaluate the minimum-phase-shift and all-pass functions of seismic waves, which is not discussed sufficiently in earthquake engineering, is developed in the two domains. Numerical examples to present these basic ideas are also illustrated in the symmetrical framework.