Time–space fractional governing equations of transient groundwater flow in confined aquifers: Numerical investigation

In order to model non‐Fickian transport behaviour in groundwater aquifers, various forms of the time–space fractional advection–dispersion equation have been developed and used by several researchers in the last decade. The solute transport in groundwater aquifers in fractional time–space takes place by means of an underlying groundwater flow field. However, the governing equations for such groundwater flow in fractional time–space are yet to be developed in a comprehensive framework. In this study, a finite difference numerical scheme based on Caputo fractional derivative is proposed to investigate the properties of a newly developed time–space fractional governing equations of transient groundwater flow in confined aquifers in terms of the time–space fractional mass conservation equation and the time–space fractional water flux equation. Here, we apply these time–space fractional governing equations numerically to transient groundwater flow in a confined aquifer for different boundary conditions to explore their behaviour in modelling groundwater flow in fractional time–space. The numerical results demonstrate that the proposed time–space fractional governing equation for groundwater flow in confined aquifers may provide a new perspective on modelling groundwater flow and on interpreting the dynamics of groundwater level fluctuations. Additionally, the numerical results may imply that the newly derived fractional groundwater governing equation may help explain the observed heavy‐tailed solute transport behaviour in groundwater flow by incorporating nonlocal or long‐range dependence of the underlying groundwater flow field.     

Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

Changes in hillslope hydrology in a perched,shallow soil system due to clearcutting and residual biomass removal

Sustainable fuels legislation and volatility in energy prices have put additional pressures on the forestry sector to intensify the harvesting of biomass for “advanced biofuel” production. To better understand how residual biomass removal after harvest affects forest hydrology in relatively low slope terrain, a Before-After-Control-Impact (BACI) study was conducted in the USDA Forest Service's Marcell Experimental Forest, Minnesota, USA. Hydrological measurements were made from 2010–2013 on a forested hillslope that was divided into three treatment blocks, where one block was harvested and residual biomass removed (Biomass Removed), the second was harvested and residual biomass left (Biomass Left), and the last block was left as an Unharvested Control. The pre-harvest period (2 years) was 2010–11 and post-harvest (2 years) was 2012–13. Water table elevation at the upslope and downslope position, subsurface runoff, and soil moisture were measured between May–November. Mixed effect statistical models were used to compare both the before-after and “control” treatment ratios (ratios between harvested hillslopes and the Unharvested Control hillslope). Subsurface runoff significantly increased (p < .05) at both harvested hillslopes but to a greater degree on the Biomass Left hillslope. Greater subsurface runoff volumes at both harvested hillslopes were driven by substantial increases during fall, with additional significant increases during summer on the Biomass Left hillslope. The hydrological connectivity, inferred from event runoff ratios, increased due to harvesting at both hillslopes but only significantly on the Biomass Left hillslope. The winter harvest minimized soil disturbance, resulting in no change to the effective hydraulic conductivity distribution with depth. Thus, the observed hydrological changes were driven by increased effective precipitation and decreased evapotranspiration, increasing the duration that both harvested hillslopes were hydrologically active. The harvesting of residual biomass appears to lessen hydrological connectivity relative to leaving residual biomass on the hillslope, potentially decreasing downstream hydrological impacts of similar forestry operations.     

Active capture and anomalous adsorption: New mechanisms for the incorporation of heavy noble gases

Abstract— Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ?1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q.     

Identification of mercurian volcanism: Resolution effects and implications for MESSENGER

Abstract— The possibility of volcanism on Mercury has been a topic of discussion since Mariner 10 returned images of half the planet's surface showing widespread plains material. These plains could be volcanic or lobate crater ejecta. An assessment of the mechanics of the ascent and eruption of magma shows that it is possible to have widespread volcanism, no volcanism on the surface whatsoever, or some range in between. It is difficult to distinguish between a lava flow and lobate crater ejecta based on morphology and morphometry. No definite volcanic features have been identified on Mercury. However, known lunar volcanic features cannot be identified in images with similar resolutions and viewing geometries as the Mariner 10 dataset. Examination of high‐resolution, low Sun angle Mariner 10 images reveals several features which are interpreted to be flow fronts; it is unclear if these are volcanic flows or ejecta flows. This analysis implies that a clear assessment of volcanism on Mercury must wait for better data. MESSENGER (MErcury: Surface, Space ENvironment, GEochemistry, Ranging) will take images with viewing geometries and resolutions appropriate for the identification of such features.     

Spectroscopic studies of three novae

We present our spectroscopic observations of the novae V1425, V1493, and V1494 Aql carried out with the 125-cm telescope at the Crimean Station of the Sternberg Astronomical Institute in the wavelength range 4000–11000 Å. We measured the emission-line intensities, determined the nova shell expansion velocities from the line profile FWHMs and components, and estimated the interstellar reddening from the first members of the Balmer series. The chemical composition of the nova shells is analyzed. Nitrogen and oxygen were found to be overabundant in V1425 and V1494 Aql; the helium abundance turned out to be normal in the two stars.