Geochemistry and quality of the groundwater from the karstic and coastal aquifer of Geropotamos River Basin at north-central Crete, Greece

In Geropotamos River Basin, located on the north-central part of Crete, Greece, two main factors were believed to be affecting the geochemistry of the groundwater with high salt contents: seawater intrusion and/or Miocene evaporates. To identify the origin of the high salinity in groundwater, a hydrogeochemical and isotopic study was performed. Water samples from 22 wells and 2 springs were analyzed for physico-chemical parameters, major ions analysis, as well as stable isotopes (??¹⁸O, ??D). From the present survey, in which detailed hydrogeochemical investigation was conducted, the uncertainty of the contamination sources was decreased in the northern part of Geropotamos Basin. The results complement the scenario in which seawater and the widespread human activities are the principal sources of groundwater contamination. Moreover, the results of the stable isotopes analyses (??¹⁸O and ??D) support the same hypothesis and make seawater intrusion the most probable cause for the highest salinity waters. It is indicated that saline intrusion is likely to occur along fractures in a fault zone through otherwise low-permeability phyllite?Cquartzite bedrock, which demonstrates the critical role of fracture pathways in salination problems of coastal aquifers.     

Experimental Evidences of the Effect of Fibres in Reinforcing a Sandy Gravel

Studies regarding fibre-reinforcement are restricted to clays, silty and sandy soils. No information is available on gravels. It is worth checking the effect of randomly oriented discrete fibres also on such soils to see if they can be beneficial and to get a better insight into the grain to soil interaction mechanism. In this paper, the effect of a small amount of fibres having high aspect ratio on a sandy gravel was analysed by means of tests carried out in a large triaxial apparatus. Specimens of both natural and fibre-reinforced sandy gravel were prepared by wet tamping at different relative densities, and were tested along monotonic and cyclic stress paths. The results show that the addition of a small amount of fibres causes a slight increase in peak strength and a larger increase in ultimate strength at small confining stress, with an overall more ductile behaviour. The cyclic tests at small confining stress and intermediate strain levels show that, for the lowest applied strain (of the order of 10⁻²%), the stiffness was larger for the reinforced specimens, with a much sharper decrease at larger strains and final values similar for the reinforced and non-reinforced materials.     

PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

Contribution of Sponge Spicules to the Composition of Biogenic Silica in the Ligurian Sea

Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.     

Study of temperature and precipitation variations in Italy based on surface instrumental observations

In this paper we present a study concerning the climatic behaviour of two principal observables, temperature and precipitation as obtained from the measurements carried out at 50 Italian meteorological stations, since 1961. Analyses of WMO Climate Normals (CliNo) from 1961 to 1990 have been performed dividing the 50 Italian stations in three different classes: mountain (11 stations), continental (17) and coastal areas (21).The comparison of the CliNo 1961–1990 with the trend of temperature and precipitation for the period 1991–2000 showed a sharp significant increase of summer temperatures over Italy starting from 1980. This phenomenon was particularly evident for mountain stations, where a significant temperature increase has been recorded also during the autumn. Moreover, the analysis of precipitation data permitted to point out that, starting from 1980, mountain stations have been affected by a significant increase of precipitation events during autumn and winter, while for the rest of the Italian territory a reduction of precipitations has been recorded during early spring.     

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.