Modelling of deformation response and chemo‐mechanical coupling in chalk

A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.     

Geochemical and structural evolution of micas in the Rožná and Dobrá Voda pegmatites,Czech Republic

Summary The chemistry, structural parameters, polytypism, optical properties and Rb-Sr isotopes were examined in 11 to 60 samples of biotite, muscovite and lepidolite from the pegmatites at Roná (the type locality of lepidolite; 323 ± 4Ma) and Dobrá Voda (306 ± 9Ma) in western Moravia. At both localities, early endocontact biotite is followed inwards by muscovite and lepidolite, which is concentrated in and around the core. At Roná, a 1M lepidolite follows after 2M₁ muscovite but all later generations of lepidolite are 2M₂, close to Tri₅₀ Ply₅₀ and in part associated with muscovite 2M₁. At Dobrá Voda, all lepidolite types are 1M and free of muscovite, and the late varieties approximate Tri₃₀ Ply₇₀. At both localities, a trend of increasing HF is indicated during the progress of mica crystallization, culminating in precipitation of topaz. Polytypism of lepidolite is not correlatable with any compositional or growth feature, or their combination. Throughout the mica crystallization, Rb/Cs decreases but K/Rb becomes reversed after an initial decrease. Boron is partitioned preferentially into muscovite (up to 1.10 wt.% B₂O₃) but Be, Zn, Mn and Sc are enhanced in lepidolite. A slight increase in Fe, Ba and Cl in the last generation of lepidolite might be possibly due to mixing of residual pegmatite fluids with metamorphic pore solutions.

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Geochemische und strukturelle Entwicklung der Glimmer in den Pegmatiten von Roná und Dobrá Voda, Tschechische Republik

Zusammenfassung In 11 bis 60 Proben von Biotit, Muskovit und Lepidolith aus den Pegmatiten von Roná (Typlokalität des Lepidoliths; 323 ± 9 Ma) in Westmähren wurden Chemie, Struktur-parameter, Polytypie, optische Eigenschaften und Rb-Sr-Isotopie untersucht. An beiden Lokalitäten wird früher Biotit an Endokontakten nach Innen von Muskovit und Lepidolith gefolgt, letzterer ist in und um den Kern konzentriert. In Roná folgt 1M-Lepidolith auf 2M₁-Muskovit, aber alle späteren Lepidolithgenerationen sind 2M₂, nahe Tri₅₀Ply₅₀ und zum Teil mit 2M₁-Muskovit vergesellschaftet. In Dobrá Voda sind alle Lepidolithe vom Typ 1M und frei von Muskovit, die späten Varietäten kommen Tri₅₀Ply₅₀ nahe. An beiden Lokalitäten ist während des Fortschreitens der Glimmerkristallisation eine Tendenz von steigendem HF angezeigt, die in der Ausfällung von Topas ihren Höhepunkt findet. Die Polytypie des Lepidoliths kann nicht mit irgendeiner Eigenheit der Zusammensetzung oder des Wachstums korreliert worden, auch nicht mit einer Kombination von diesen. Während der ganzen Glimmerkristallisation nimmt Rb/Cs ab, aber die Tendenz von K/Rb ändert sich nach anfänglichem Abfall. Das Bor verteilt sich bevorzugt auf den Muskovit (bis zu 1.10 Gew. -% B₂O₃), aber die Be-, Zn-, Mn- und Sc-Gehalte sind im Lepidolith erhöht. Ein leichter Ansteig von Fe, Ba und Cl in der letzten Lepidolithgeneration könnte vielleicht durch eine Mischung von pegmatitischen Restlösungen mit metamorphen Porenlösungen verursacht sein.

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With 9 Figures     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

Mid-late Holocene anthropogenic and natural variations in geochemistry and sedimentation in the Yazoo Basin: Clark Lake,Sharkey County,Mississippi

A 4000-yr history at Clark Lake reveals natural variations in sediment geochemistry and nutrient levels and anthropogenic influence on twentieth century sedimentation rates. Sediment texture and ridge and swale topography indicate that the channel system creating Clark Lake is now occupied by the Yazoo River. Between 1.24 and 0.60 m (2522–865 cal yr BP), total carbon percentages and the C/N ratio average 42% and 17, respectively. The base of the 1650-yr interval and onset of high organic activity in the lake coincides with the abandonment of the Yazoo Meander Belt. The top of the interval is marked by a drop in C/N ratio to 11 and a geochemical transition zone. No change in the rate of sediment accumulation or clay mineralogy was observed despite increased cumulative percentages of Al, Fe, K, Mg, Mn, Ca, and Na. The decrease in organic activity at 865 cal yr BP is attributed to unfavorable growth conditions related to the entrenchment of the Yazoo River and changes in the hydroperiod of the area. Significant floodplain alteration was completed in 1978, but the only major effect was increased sedimentation in the late twentieth century due to the completion of the Whittington Auxiliary Channel.     

Assessment of slope stability in cohesive soils due to a rainfall

The primary focus in this work is on proposing a methodology for the assessment of stability of natural/engineered slopes in clayey soils subjected to water infiltration. In natural deposits of fine‐grained soils, the presence of water in the vicinity of minerals results in an interparticle bonding. This effect cannot be easily quantified as it involves complex chemical interactions at the micromechanical level. Here, the evolution of strength properties, including the apparent cohesion resulting from initial suction at the irreducible fluid saturation, is described by employing the framework of chemoplasticity. The paper provides first the formulation of the problem; this involves specification of the constitutive relation, development of an implicit return mapping scheme, and the outline of a coupled transient formulation. The framework is then applied to examine the stability of a slope subjected to a prolonged period of intensive rainfall. It is shown that the water infiltration may trigger the loss of stability resulting from the degradation of material properties. Copyright © 2013 John Wiley & Sons, Ltd.     

Description of deformation process in inherently anisotropic granular materials

The main focus in this work is on modeling of mechanical response of granular materials that display inherent anisotropy. Both the experimental and numerical investigations are described. First, the results of direct shear as well as drained/undrained triaxial tests that involve crushed limestone with elongated angular‐shaped particles are reviewed. Afterward, a mathematical framework is presented for modeling of elastic/ inelastic deformation that incorporates the multi‐laminate approach. The deformation is monitored on a set of randomly oriented planes, and the formulation incorporates the thickness of the shear band that is associated with sliding/separation process. A systematic procedure for identification of material functions/ parameters is outlined that is based on the results of direct shear tests, and the framework is later applied to simulate the behavior under triaxial conditions. The results of numerical simulations are compared with the experimental data. Copyright © 2011 John Wiley & Sons, Ltd.     

A review of inverse methods in seismic site characterization

Journal of Seismology - Seismic site characterization attempts to quantify seismic wave behavior at a specific location based on near-surface geophysical properties, for the purpose of mitigating...     

A COMBINED REFRACTION-DIFFRACTION-DISSIPATION MODEL OF WAVE PROPAGATION

A numerical model based on the mild-slope equation of water wave propagation over complicated bathymetry,taking into account the combined effects of refraction,diffraction and dissipation due to wavebreaking is presented.Wave breaking is simulated by modifying the wave height probability density func-tion and the wave energy dissipation mechanism is parameterized according to that of the hydraulic jumpformulation.Solutions of the wave height,phase function,and the wave direction at every grid point areobtained by finite difference approximation of the governing equations,using Gauss-Seidel Iterative Method(GSIM)row by row.Its computational convenience allows it to be applied to large coast regions tostudy the wave transformation problem.Several case studies have been made and the results compare verywell with the experiment data and other model solutions.The capability and utility of the model forreal coast areas are illustrated by application to a shallow bay of northeast Australia.     

On the mechanical response of saturated cemented materials—part II: Experimental investigation and numerical simulations

Results of experimental investigation and numerical simulations of the mechanical response of the saturated cemented materials are reported. Saturated as well as dry samples cored from commercially available fire bricks are used. The samples were tested in a triaxial rock cell at different initial confining pressures. The tests have been simulated using the constitutive framework proposed in Part I of this paper. The results both experimental and numerical, provide the evidence in support of the proposed stress decomposition, thereby questioning the validity of Terzaghi's principle for the considered class of materials.