Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.     

Water release patterns of heated speleothem calcite and hydrogen isotope composition of fluid inclusions

Speleothem fluid inclusions are a potential paleo-precipitation proxy to reconstruct past rainwater isotopic composition (δ¹⁸O, δD). To get a better insight in the extraction of inclusion water from heated speleothem calcite, we monitored the water released from crushed and uncrushed speleothem calcite, heated to 900 °C at a rate of 300 °C/h, with a quadrupole mass spectrometer. Crushed calcite released water in three not well individualised peaks between 25 and 360 °C, 360 and 650 °C and between 650 and 800 °C while uncrushed calcite released water in two distinct temperature intervals: between 25 and 550 °C and between 550 and 900 °C.Water from two speleothems from the Han-sur-Lesse cave was recovered using three different techniques: i) the crushing and heating to 360 °C technique, ii) the decrepitation by heating to 550 °C and iii) the decomposition by heating to 900 °C technique. Measurements of the δD of water recovered by the decomposition of Han-sur-Lesse calcite heated to 900 °C did not show a 20 to 30‰ offset as found by previous authors. However a difference of 7‰ was observed between water released before and after decomposition of the calcite. Water recovery from the Han-sur-Lesse samples suggests that a simple heating technique (up to 550 °C) without crushing could both (a) recover water with δD representative of that of the drip water and (b) double the water yield as compared to the crushing and heating method.Our study warns for possible contamination of the recovered inclusion water with hydration water of lime, responsible for the recovery of water with very negative δD values.     

Formation of the mid-fifteenth century Kuwae caldera (Vanuatu) by an initial hydroclastic and subsequent ignimbritic eruption

In the mid-fifteenth century, one of the largest eruptions of the last 10 000 years occurred in the Central New Hebrides arc, forming the Kuwae caldera (12x6 km). This eruption followed a late maar phase in the pre-caldera edifice, responsible for a series of alternating hydromagmatic deposits and airfall lapilli layers. Tuffs related to caldera formation ( 120 m of deposits on a composite section from the caldera wall) were emitted during two main ignimbritic phases associated with two additional hydromagmatic episodes. The lower hydromagmatic tuffs from the precaldera maar phase are mainly basaltic andesite in composition, but clasts show compositions ranging from 48 to 60% SiO₂. The unwelded and welded ashflow deposits from the ignimbritic phases and the associated intermediate and upper hydromagmatic deposits also show a wide compositional range (60–73% SiO₂), but are dominantly dacitic. This broad compositional range is thought to be due to crystal fractionation. The striking evolution from one eruptive style (hydromagmatic) to the other (magmatic with emission of a large volume of ignimbrites) which occurred either over the tuff series as a whole, or at the beginning of each ignimbritic phase, is the most impressive characteristic of the caldera-forming event. This strongly suggests triggering of the main eruptive phases by magma-water interaction. A three-step model of caldera formation is presented: (1) moderate hydromagmatic (sequences HD 1–4) and magmatic (fallout deposits) activity from a central vent, probably over a period of months or years, affected an area slightly wider than the present caldera. At the end of this stage, intense seismic activity and extrusion of differentiated magma outside the caldera area occurred; (2) unhomogenized dacite was released during a hydromagmatic episode (HD 5). This was immediately followed by two major pyroclastic flows (PFD 1 and 2). The vents spread and intense magma-water interaction at the beginning of this stage decreased rapidly as magma discharge increased. Subsequent collapse of the caldera probably commenced in the southeastern sector of the caldera; (3) dacitic welded tuffs were emplaced during a second main phase (WFD 1–5). At the beginning of this phase, magma-water interaction continued, producing typical hydromagmatic deposits (HD 6). Caldera collapse extended to the northern part of the caldera. Previous C¹⁴ dates and records of explosive volcanism in ice from the south Pole show that the climactic phase of this event occurred in 1452 A.D.     

Uncertainties in field-line tracing in the magnetosphere. Part II: the complete internal geomagnetic field

The discussion in the preceding paper is restricted to the uncertainties in magnetic-field-iine tracing in the magnetosphere resulting from published standard errors in the spherical harmonic coefficients that define the axisymmetric part of the internal geomagnetic field (i.e. g_n⁰ ± g_n⁰). Numerical estimates of these uncertainties based on an analytic equation for axisymmetric field lines are in excellent agreement with independent computational estimates based on stepwise numerical integration along magnetic field lines. This comparison confirms the accuracy of the computer program used in the present paper to estimate the uncertainties in magnetic-field-line tracing that arise from published standard errors in the full set of spherical harmonic coefficients, which define the complete (non-axisymmetric) internal geomagnetic field (i.e. g_n^m ± g_n^m and h_n^m ± h_n^m). An algorithm is formulated that greatly reduces the computing time required to estimate these uncertainties in magnetic-field-line tracing. The validity of this algorithm is checked numerically for both the axisymmetric part of the internal geomagnetic field in the general case (1 n 10) and the complete internal geomagnetic field in a restrictive case (0 m n, 1 n 3). On this basis it is assumed that the algorithm can be used with confidence in those cases for which the computing time would otherwise be prohibitively long. For the complete internal geomagnetic field, the maximum characteristic uncertainty in the geocentric distance of a field line that crosses the geomagnetic equator at a nominal dipolar distance of 2 R_E is typically 100 km. The corresponding characteristic uncertainty for a field line that crosses the geomagnetic equator at a nominal dipolar distance of 6 R_E is typically 500 km. Histograms and scatter plots showing the characteristic uncertainties associated with magnetic-field-line tracing in the magnetosphere are presented for a range of illustrative examples. Finally, estimates are given for the maximum uncertainties in the locations of the conjugate points of selected geophysical observatories. Numerical estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, including the associated uncertainties in thelocations of the conjugate points of geophysical observatories, should be regarded as first approximations in the sense that these estimates are only as accurate as the published standard errors in the full set of spherical harmomic coefficients. As in the preceding paper, howerver, all computational techniques developed in this paper can be used to derive more realistic estimates of the uncertainties in magnetic-field-line tracing in the magnetosphere, following further progress in the determination of more accurate standard errors in the spherical harmonic coefficients.Also Visiting Reader in Physics, University of Sussex, Palmer, Brighton, BN1 9QH, UK     

The ups and downs of “Tectonic Quiescence”—recognizing differential subsidence in the epicontinental sea of the Oxfordian in the Swiss Jura Mountains

Recent studies in northern Switzerland have shown that epicontinental areas thought to have been tectonically stable during the Mesozoic were not necessarily as rigid as presumed. By comparing Oxfordian facies boundaries and depocenters in their palinspastic position with known faults in the basement, a direct relationship between the two can be demonstrated. Previously, the lack of obvious synsedimentary tectonic features has lulled scientists into believing that the realm of the Swiss Jura was tectonically stable during the Mesozoic. However, it can be shown that facies and sedimentary structures are largely influenced by tectonics. Subsurface data provide evidence for the presence of Paleozoic troughs in the basement which, apparently, were prone to reactivation during the Pan-European stress-field reorganization taking place in the Late Jurassic. This led to differential subsidence along pre-existing lineaments within the study area, which can be recognized in the distribution of Oxfordian epicontinental basins and their coeval shallow-water counterparts. Eustatic sea-level fluctuations played an important role in the development of shallow-water facies patterns, but a subordinate role in the control of accommodation space in basins.

While tectonic activity is often recorded in the sedimentary record in the form of platform break-ups and associated sedimentary debris, more subtle indicators may be overlooked or even misinterpreted. Sedimentary structures and isopach maps, as well as subsurface data in the study area suggest that subtle synsedimentary tectonic movements led to the formation of two shallow, diachronous epicontinental basins during the Late Jurassic. It becomes possible to recognize and differentiate the combined effects of local and regional tectonism, eustasy and sedimentation.     

Rates of deformation of an extensional growth fault/raft system (offshore Congo, West African margin) from combined accommodation measurements and 3-D restoration

The aim of this paper is to quantify the evolution in time and space of the accommodation (space available for sedimentation) in the case of a growth fault structure resulting from gravity‐induced extension comprising a listric fault/raft system located along the West African margin. To achieve this, use was made of an original approach combining two complementary techniques (accommodation variation measurements and 3‐D restoration) in order to quantify vertical and horizontal displacement related to deformation, using a data set made up of a 3‐D seismic survey and well logs. We applied sequence stratigraphic principles to (i) define a detailed stratigraphic framework for the Albo‐Cenomanian and (ii) measure subsidence rates from accommodation variations. 3‐D restoration was used to (iii) reconstruct the evolution of the 3‐D geometry of the fault system. The rates of horizontal displacement of structural units were measured and linked to successive stages in the growth of the fault system. Subsidence of the structural units exhibits three scales of variation: (1) long‐term variation (10 Ma) of c. 80 m Ma^?1 for a total subsidence of about 1400 m, compatible with the general subsidence of a passive margin, and (2) short‐term variations (1–5 Ma) corresponding to two periods of rapid subsidence (about 150–250 m Ma^?1) alternating with periods of moderate subsidence rate (around 30 m Ma^?1). These variations are linked to the development of the fault system during the Albian (with downbuilding of the raft and development of the initial basin located in between). During the Cenomanian, the development of the graben located between the lower raft and the initial basin did not seem to affect the vertical displacements. (3) High‐frequency variations (at the scale of genetic unit sets) range between ?50 and 250 m for periods of 0.2–2 Ma. Accommodation variations governed these cycles of progradation/retrogradation rather than sediment flux variations. In addition, the nine wells display a highly consistent pattern of variation in accommodation. This suggests that the genetic unit sets were controlled at a larger scale than the studied system (larger than 20 km in wavelength), for example, by eustatic variations. Translation rates are between 3 and 30 times higher than subsidence rates. Therefore, in terms of amplitude, the main parameter controlling the space available for sedimentation is the structural development of the fault system, that is to say, the seaward translation of the raft units, itself resulting from a regional gravity‐driven extension.