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晶质石墨是一种新兴战略矿产。近年在河北省北部发现了多处大中型晶质石墨矿床,主要赋矿层位于新太古代崇礼上岩群、古元古代红旗营子岩群等,具有良好的成矿潜力。通过系统的野外地质调查与采样、分析测试工作,详细研究了赋矿层位的岩相学、地球化学特征,并对碳质来源进行了分析。结果表明:赋矿岩石主要为含石墨黑云斜长变粒岩、片麻岩与透辉岩,原岩恢复以砂泥质碎屑岩、钙质沉积岩为主。主量元素含量变化较大, SiO2含量为38.90%~80.42%, CaO+MgO为2.05%~31.93%, Al2O3为1.50%~15.34%;稀土元素含量为79.1~321.4μg/g, PAAS标准化分布模式一般具有右倾或较平坦分布特征, δCe略具负异常,部分具有δEu异常。微量元素特征指示沉积环境为滨浅海环境,部分地区存在富氧条件,局部为还原环境或存在热液加入。石墨中碳同位素值为–26.0‰~–20.7‰,主要来源于生物成因有机碳;大理岩碳同位素值为–3.8‰~1.1‰,主要来源于碳酸盐岩成因无机碳。区内晶质石墨矿层分布受到地层、岩性、岩相控制,含矿... 相似文献
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V.?YobouéEmail author C.?Galy-Lacaux J.?P.?Lacaux S.?Silué 《Journal of Atmospheric Chemistry》2005,52(2):117-141
From the IGAC-DEBITS Africa network (IDAF), data sets on precipitation chemistry collected from the ‘wet savanna ecosystem’ site of Lamto (Côte d'Ivoire), are analyzed (1995–2002). Inorganic (Ca2 +, Mg2 +, Na+, K+, NH4 +, Cl?, SO4 2 ?, NO3 ?) and organic (HCOO?, CH3COO?) ions content were determined using Ion Chromatography. The analyzed 631 rainfall events represent 8420.9 mm of rainfall from a 9631.1 mm total. The precipitation chemistry at Lamto is influenced by four main sources: natural biogenic emissions from savanna soils (NO x and NH3), biomass burning (savanna and domestic fires), terrigeneous particles emissions from dry savanna soils, and marine compounds embedded in the summer monsoon. The inter-annual variability of the weighted volume mean concentration of chemical species linked with wet deposition fluctuates by ~ 20% over the period. Ammonium concentration is found to be the highest (17.6 μ eq.l? 1) from all IDAF sites belonging to the West Africa ecosystems. Ammonia sources are from domestic animals, fertilizers and biomass burning. In spite of the high potential acidity of 30.5 μ eq.l? 1 from NO3 ?, SO4 2 ?, HCOO? and CH3COO?, a relatively weak acidity is measured: 6.9 μ eq.l? 1. The 40% acid neutralization is explained by the acid gas – alkaline soil particles interaction. The remaining neutralization is from inclusion of gaseous ammonia. When results from Lamto, are compared with those from Banizoumbou (dry savanna) and Zoetele (equatorial forest), a regional view for wet tropospheric chemistry processes is obtained. The high concentration of the particulate phase in precipitation emphasizes the importance of multiphases processes between gases and particles in the atmospheric chemistry of the West Africa ecosystems. For example, the nss Ca2 + precipitation content, main indicator of terrigeneous particles, goes from 30.8 μ eq.l? 1 in dry savanna to 9.2 μ eq.l? 1 at Lamto and 8.9 μ eq.l? 1 in the Cameroon forest. A similar gradient is obtained for rainfall mineral particles precipitation content with contribution of 80% in dry savanna, 40% in wet savanna, and 20% in the equatorial forest. 相似文献
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