Comparison of environmental tracers including organic micropollutants as groundwater exfiltration indicators into a small river of a karstic catchment

Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human-impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon-222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady-state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP-derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in-stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m³ s⁻¹), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.     

Sublethal toxicity of orchard stormwater runoff in Sacramento splittail (Pogonichthys macrolepidotus) larvae

The sublethal effects of stormwater runoff from sections of a plum orchard treated with esfenvalerate or diazinon were evaluated in 7-day-old Sacramento splittail (Pogonichthys macrolepidotus) larvae. Fish were exposed to eight runoff samples using the USEPA standard static renewal method for 96 h acute toxicity testing, then transferred to clean water for three-month to assess the survival, growth, histopathological abnormalities, and heat stress proteins (hsp). No significant mortality was observed at 96 h in exposed fish. At one week, histopathological abnormalities included severe glycogen depletion, cytoplasmic protein droplets, vacuolar degeneration, and cell necroses in liver of all exposure groups. Pyknotic nerve cells were seen in brain of one exposure group. Significantly higher cumulative mortality, lower condition factor, and elevated hsp60 and hsp70 levels (p < 0.05) were occurred in several exposure groups. No histopathological abnormalities were observed after three months in any exposure group. This study confirms that standard acute toxicity tests have underestimated the toxicity of stormwater runoff, and although splittail larvae survived the 96 h exposure, they exhibited reduced survival and growth and showed signs of cellular stress even after a three month recovery period.     

Community strategies to promote sustainable wetland-based food security in rural areas of Zimbabwe

This article explores the various strategies rural households employ to sustain wetland use and conservation in the context of the restrictions imposed by the existing legal framework in Zimbabwe. Wetland cultivation is a common feature of the rural landscape and is mainly triggered by subsistence households endeavouring to stabilize their food security, especially in semi-arid and arid environments of the developing countries. Data was collected through a household questionnaire survey, key informant interviews, document review and direct observations. Quantitative data was analysed using ANOVA, Spearman Correlation Coefficient and Wilcoxon in Statistical Package for Social Scientists, whereas qualitative data was subjected to thematic analysis. The results revealed that most households adjacent to wetlands were food secure as wetland conditions enable the provision of a wide range of crops and natural products, contributing almost half of the food directly consumed and 48.2 % of average annual household total cash income. It was also observed that various soil and water conservation practices were adopted and local institutional arrangements were put in place to oversee their effective implementation. Thus, the general result has been increased wetland productivity, improved livelihoods and ecosystem protection. This has largely rendered the impact of legislation restricting wetland cultivation subtle in the local context. The study concluded that there is a need to promote participatory wetland management based on low-cost approaches sensitive to local conditions and the needs and practices of the local communities.     

Selenium-induced teratogenicity in Sacramento splittail (Pogonichthys macrolepidotus)

Selenium is a potent reproductive and teratogenic environmental contaminant and there are concerns over possible reproductive effects of selenium on the Sacramento splittail (Pogonichthys macrolepidotus) population, a threatened species, in California, USA. In this study, the teratogenic effects of selenium were examined in splittail embryos exposed to 0.0, 5.0, and 15.0 mg l(-1) sodium selenite for 48-h at 18.0 degrees C under static conditions, with renewal every 12 h. Embryo development was evaluated daily for abnormalities from initiation of exposure (stage 27) to initiation of exogenous feeding. At the end of evaluation, prelarvae were preserved for histological analysis. There were no significant differences in mortality or hatching success between control and exposed embryos. Exposed fish had pericardial edema and deformities of skeletal tissues (loss of tail, lordosis, scoliosis, and kyphosis). Other histological alterations were limited to dysplasia, hyperplasia and metaplasia of skeletal tissues in the deformed fish. This study showed that a short exposure of embryos during somite development has significant effects on the musculoskeletal development.     

Probabilistic Visibility Forecasting Using Neural Networks

Statistical methods are widely applied in visibility forecasting. In this article, further improvements are explored by extending the standard probabilistic neural network approach. The first approach is to use several models to obtain an averaged output, instead of just selecting the overall best one, while the second approach is to use deterministic neural networks to make input variables for the probabilistic neural network. These approaches are extensively tested at two sites and seen to improve upon the standard approach, although the improvements for one of the sites were not found to be of statistical significance.     

Evaluation of a spatial rainfall generator for generating high resolution precipitation projections over orographically complex terrain

Space–time variability of precipitation plays a key role as driver of many environmental processes. The objective of this study is to evaluate a spatiotemporal (STG) Neyman–Scott Rectangular Pulses (NSRP) generator over orographically complex terrain for statistical downscaling of climate models. Data from 145 rain gauges over a 5760-km² area of Cyprus for 1980–2010 were used for this study. The STG was evaluated for its capacity to reproduce basic rainfall statistical properties, spatial intermittency, and extremes. The results were compared with a multi-single site NRSP generator (MSG). The STG performed well in terms of average annual rainfall (+1.5 % in comparison with the 1980–2010 observations), but does not capture spatial intermittency over the study area and extremes well. Daily events above 50 mm were underestimated by 61 %. The MSG produced a similar error (+1.1 %) in terms of average annual rainfall, while the daily extremes (>50-mm) were underestimated by 11 %. A gridding scheme based on scaling coefficients was used to interpolate the MSG data. Projections of three Regional Climate Models, downscaled by MSG, indicate a 1.5–12 % decrease in the mean annual rainfall over Cyprus for 2020–2050. Furthermore, the number of extremes (>50-mm) for the 145 stations is projected to change between ?24 and +2 % for the three models. The MSG modelling approach maintained the daily rainfall statistics at all grid cells, but cannot create spatially consistent daily precipitation maps, limiting its application to spatially disconnected applications. Further research is needed for the development of spatial non-stationary NRSP models.     

Meta-analysis of electron cyclotron resonance absorption features detected in high-mass X-ray binaries

Using recent compilations of detailed X-ray observations and spectral models of exceptional quality, we record the electron cyclotron resonance absorption(ECRA) features that have been detected in 45 pulsating high-mass X-ray binaries(HMXBs) and ultraluminous X-ray(ULX) sources harboring neutron stars, although seven of these detections are still questionable and another 21 are single and/or not independently confirmed. From the comprehensive catalogs of Jaisawal Naik and Staubert et al.and from several additional recent observations, we produce two lists of HMXB ECRA sources: a list of 17 sources in which multiple ECRA lines or single very low-energy lines are seen, in which we can reasonably assume that the lowest energy reveals the fundamental cyclotron level for each source; and a"contaminated" list of 38 sources including the 21 detections of single ECRA lines that may(not) be higherlevel harmonics. Both lists confirm a previous result that we have obtained independently by modeling the propeller lines of Magellanic HMXB pulsars: the surface dipolar magnetic fields B*of HMXB neutron stars are segregated around five distinct values with B*= 0.28 ± 0.08, 0.55 ± 0.11, 1.3 ± 0.37, 3.0 ± 0.68 and 7.9 ± 3.1, in units of TG. However, an explanation of this phenomenon is currently lacking. We have found no correlation between these B*values and the corresponding observed spin periods, spin period derivatives, orbital periods, maximum X-ray luminosities, neutron star masses or companion star masses.     

A striking confluence between theory and observations of high-mass X-ray binary pulsars

We analyze the most powerful X-ray outbursts from neutron stars in eleven Magellanic high-mass X-ray binaries and three pulsating ultraluminous X-ray sources. Most of the outbursts rise to L_(max) which is about the level of the Eddington luminosity, while the remaining more powerful outbursts also appear to recognize that limit when their emissions are assumed to be anisotropic and beamed toward our direction. We use the measurements of pulsar spin periods P_S and their derivatives P_S to calculate the X-ray luminosities L_p in their faintest accreting("propeller-line") states. In five cases with unknown P_S, we use the lowest observed X-ray luminosities, which only adds to the heterogeneity of the sample. Then we calculate the ratios L_p/L_(max) and we obtain an outstanding confluence of theory and observations from which we conclude that work done on both fronts is accurate and the results are trustworthy: sources known to reside on the lowest Magellanic propeller line are all located on/near that line, whereas other sources jump higher and reach higher-lying propeller lines. These jumps can be interpreted in only one way, higher-lying pulsars have stronger surface magnetic fields in agreement with previous empirical results in whichP_S and L_p values were not used.     

Sedimentology of Turonian Sandstone bodies and paleogeographic conclusions,Aba Omega area,Eastern Nigeria

The texture and mineralogy of some sandstone bodies in the Aba-Omega area of Southeastern Nigeria suggest that these sediments were products of rapid sedimentation. Two sediment sources are suggested: a nearby metamorphic to low rank plutonic terrain probably the Oban Massif, and a sedimentary or distant basement area. Paleogeographic reconstructions further suggest that movement along the Abakaliki axis of uplift may have been initiated by Lower Turonian.     

Voronoi Diagrams and Spatial Analysis of Crime

A range of spatial analyses are used in the field of crime mapping, such as kernel density estimation, Ripley's K-function, and spatial autocorrelation, but there is limited use of Voronoi diagrams (VDs). The goal of this article is to contribute to the spatial analysis of crime through the use of VDs. We use four years of commercial robbery data from Campinas, Brazil, and employ several VD techniques: (1) We analyze crime concentrations through the properties of VDs—area and number of vertices—and coverage curve; (2) we introduce a new crime geovisualization with VD in three dimensions; and (3) we apply a network VD technique to crime analysis. The results demonstrate associations between these VD techniques and the ability of the researcher to recognize crime patterns associated with crime concentration, crime along pathways, and the highly regularized distribution of crime in limited areas spatially.