Thermodynamic modeling of REE behavior in oxidized hydrothermal fluids of high sulfate sulfur concentrations

Thermodynamic calculations using the HCh software were made for mineral equilibriums including REEs in the fluoride–sulfide–chloride–carbonate–sulfate–system in the presence of Na, Ca, and P with fluids of various acidities–alkalinities [11]. The obtained thermodynamic characteristics of thenardite allowed us to carry out the calculations for this phase under complicated hydrothermal conditions simulating the presence of oxidized fluids at 500–100°C and 2000–125 bar. Among other solid phases, REEs–fluorite, monazite, and REE–F–apatite were formed as CaF₂–(Ln,Y)F₃, LnPO₄, and Ca₅(PO₄)₃F–(Ln,Y)₃(PO₄)₃ ideal solid solutions, respectively, where Ln is La, Ce, Pr, Nd, Sm, Eu, and Gd. Xenotime, anhydrite, elemental sulfur, and calcite were found as well.     

Thermodynamic model for sorption of bivalent heavy metals on calcite in natural-technogenic environments

Approaches to the construction of thermodynamic models for sorption of trace-element cations on carbonates are considered. To calculate thermodynamic equilibria by the method of Gibbs free-energy minimization, the existing database of reaction constants and thermodynamic potentials was extended. Different types of models are illustrated by the example of precipitation of Cd, Cu, Pb, and Zn from the water of a drainage stream flowing out of the impoundment of barite-polymetallic ore-dressing wastes. It is shown that the mobility of metals in such cases can be controlled by their sorption by calcite present in bottom sediments and suspension. Any approach can be successfully applied to both the modeling of experimental data on cation sorption and the prediction of the ecologo-geochemical situation in the districts of dressing works.     

Typochemical features of the rare-earth component of monazites from the Ilmen’ reserve

By means of X-ray fluorescence with synchroton radiation (XRF-SR), the contents of all 14 rare-earth elements (REEs) and that of Y were determined in 12 monazite samples from different veins in the Ilmen’ Reserve (South Urals). It was found that, in anphibole-micaceous-carbonate mineralized zones within metabasites, monazites were pronouncedly depleted in middle and, especially, in heavy rare-earth elements (HREEs) (from 0.25% and below for Sm, 0.08% or below for Gd, 0.03% for Dy, 0.01% for Er and Tm, below 0.005% for Yb, trace amounts of other odd HREEs, at a Y content of 0.1% or below). Monazites from the veins of granitic pegmatites were characterized by vastly decreased La contents (4–8 compared to 11–13% for the group above), at high values for Pr (to 3%), Nd (to 8%), Sm (to 1.3%), Gd (to 1.1%), Dy (to 0.9%), Er (to 0.2%), Yb (to 0.05%), and Y (from 0.2 to 1.7%). Here, the values for odd REEs are also quite high compared to the group above (to 0.2% for Tb, to 0.08% for Ho, and to 0.1% for Tm).

     

Prediction of gold forms in sulfides: Evidence from experiments and calculations

Doklady Earth Sciences -