Determination of the lithium and rubidium in sea water by double channel flame emission spectrophotometry

A precise and accurate technique for the determination of Li and Rb in sea water has been developed by using a double channel flame emission spectrophotometer. The advantage of this technique is that it is possible to correct the background emission by making use of the double channel system of the apparatus and to obtain constant intensity of emission even if there are large scale changes in the salinity of the sample. Sea water samples collected in the open sea and coastal areas of Japan were analyzed by this method. In one of the coastal areas, an extraordinarily high concentration of Li was found.     

Evapotranspiration from citrus trees growing in sandy soilunder drip irrigation with saline water

An experiment on evapotranspiration from citrus trees under irrigation with saline waterwas carried out for 4 months. Two lysimeters planted with a citrus tree in the green house wereused. One lysimeter was irrigated with saline water (NaCl and CaCl2 of 2000 mg/L equivalence,EC = 3.8 dS/m, SAR = 5.9) and the other was irrigated with freshwater using drip irrigation. Theapplied irrigation water was 1.2 times that of the evapotranspiration on the previous day.Evapotranspiration was calculated as the change in lysimeter weight recorded every 30 minutes.The lysimeters were filled with soil with 95.8% sand. The results of the experiment were as follows.(i) The evapotranspiration from citrus tree was reduced after irrigation with saline water. Theevapotranspiration returns to normal after leaching. However it takes months to exhaust the saltfrom the tree. ( ii ) To estimate the impact of irrigation with saline water on the evapotranspirationfrom citrus trees, the reduction coefficient due to salt stress (Ks) was used in this experiment.Evapotranspiration under irrigation with saline water (ETs) can be calculated from evapotranspira-tion under irrigation with freshwater (ET) by the equation ETs = Ks× ET. Ks can be expressed as afunction of ECsw. (iii) The critical soil-water electrical conductivity (ECsw) is 9.5 dS/m, beyondwhich adverse effects on evapotranspiration begin to appear. If ECsw can be controlled at below9.5 dS/m, saline water can be safely used for irrigation.     

Interpretation of charging on fracture or frictional slip surface of rocks

Fracturing and frictional sliding of quartz and granite under dry condition generates fractoluminescence, charged particle emission and electromagnetic radiation. Various kinds of experiments indicate that surface charge density on fracture or frictional slip surface of quartz and granite is 10⁻⁴ to 10⁻² C/m² which is larger than bound charges induced by the disappearance of piezoelectricity due to the release of stress. Hole and electron trapping centers, which is found in semiconductor devices with the Si–SiO₂ system, are causes of surface charging on fracture or frictional slip surface of quartz crystal. The quantity of the surface charge is enough to cause corona discharge that can generate earthquake lights. The mechanism considering the hole and electron trapping centers has a probability to explain why non-piezoelectric minerals or rocks generate electromagnetic phenomena. It can be one of origins of seismo-electromagnetic phenomena (SEP).     

Construction and Visualization of a Three Dimensional Geologic Model Using GRASS GIS

The present work aims at introducing a basic theory, implementing methodology and algorithms for 3‐D modeling, and visualizing a geologic model using the Open Source Free GIS GRASS environment. A 3‐D geologic model is constructed from the boundary surfaces of geologic units and the logical model of geologic structure. The algorithms for construction and visualization of the proposed model are based on the geologic function g . The geologic function g assigns a unique geologic unit to every point in the objective 3‐D space. The boundary surface that divides the objective space into two subspaces is estimated using data from field survey. The logical model showing the hierarchical relationship between these boundary surfaces and geologic units can be automatically generated based on the stratigraphic sequence and knowledge of geologic structures. Based on these algorithms, a 3‐D geologic model can be constructed virtually in the GRASS GIS. Applying this model, various geologic surfaces and section models can be visualized in the GRASS GIS environment. “Nviz” was used for dynamic visualization of geologic cross‐sections and generation of animated image sequences. Further, the described algorithms and methods are applied and an online 3‐D geologic modeling system is developed.     

Formation and shortening deformation of a back-arc rift basin revealed by deep seismic profiling, central Japan

The northern Fossa Magna (NFM) basin is a Miocene rift system produced in the final stages of the opening of the Sea of Japan. It divides the major structure of Japan into two regions, with north-trending geological structures to the NE of the basin and EW trending structures to the west of the basin. The Itoigawa-Shizuoka Tectonic Line (ISTL) bounds the western part of the northern Fossa Magna and forms an active fault system that displays one of the largest slip rates (4–9 mm/year) in the Japanese islands. Deep seismic reflection and refraction/wide-angle reflection profiling were undertaken in 2002 across the northern part of ISTL in order to delineate structures in the crust, and the deep geometry of the active fault systems. The seismic images are interpreted based on the pattern of reflectors, the surface geology and velocities derived from refraction analysis. The 68-km-long seismic section suggests that the Miocene NFM basin was formed by an east dipping normal fault with a shallow flat segment to 6 km depth and a deeper ramp penetrating to 15 km depth. This low-angle normal fault originated as a comparatively shallow brittle/ductile detachment in a high thermal regime present in the Miocene. The NFM basin was filled by a thick (>6 km) accumulation of sediments. Shortening since the late Neogene is accommodated along NS to NE–SE trending thrust faults that previously accommodated extension and produce fault-related folds on their hanging wall. Based on our balanced geologic cross-section, the total amount of Miocene extension is ca. 42 km and the total amount of late Neogene to Quaternary shortening is ca. 23 km.     

High-reliability zircon separation for hunting the oldest material on Earth: An automatic zircon separator with image-processing/microtweezers-manipulating system and double-step dating

Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.     

Landslides triggered by the 2016 Mj 7.3 Kumamoto,Japan, earthquake

The aim of this study is to establish a detailed and complete inventory of the landslides triggered by the Mj 7.3 (Mw 7.0) Kumamoto, Japan, earthquake sequence of 15 April 2016 (16 April in JST). Based on high-resolution (0.5–2 m) optical satellite images, we delineated 3,467 individual landslides triggered by the earthquake, occupying an area of about 6.9 km². Then they were validated by aerial photographs with very high-resolution (better than 0.5 m) and oblique field photos. Of them, 3,460 landslides are distributed in an elliptical area about 6000 km², with a NE-SW directed 120-km-long long axis and a 60-km-long NW-SE trending short axis. Most of the landslides are shallow, disrupted falls and slides, with a few flow-type slides and rock and soil avalanches. The analysis of correlation between the landslides and several control factors shows the areas of elevation 1000–1200 m, stratum of Q₃-Hvf, seismic intensity VIII and VIII+, and peak ground acceleration (PGA) 0.4–0.6 g register the highest landslide abundance. This study also discussed the relationship between the spatial pattern of the landslides and the seismotectonic structure featured by a strike-slip fault with a normal component and the volcanism in the study area.