CO<Subscript>2</Subscript> Flux Measurements over the Sea Surface by Eddy Correlation and Aerodynamic Techniques

The measurements of the vertical transport of CO₂ were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO₂ fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO₂ fluxes during sea breeze conditions: −0.001 to −0.08 mg m⁻²s⁻¹ with the mean of −0.05 mg m⁻²s⁻¹. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO₂ flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO₂ concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.     

Preparation of a New Geological Survey of Japan Geochemical Reference Material: Coral JCp-1

A new geochemical reference material, coral Porites sp. JCp-1 has been prepared by the Geological Survey of Japan (GSJ). Provisional values for twenty one major, minor and trace elements are presented. The homogeneity tests showed that all elements studied are considered to be homogeneously distributed.     

Stability Dependence and Diurnal Change of Large-Scale Turbulence Structures in the Near-Neutral Atmospheric Boundary Layer Observed from a Meteorological Tower

Based on the analysis of observations from a 213-m tall meteorological tower at Tsukuba, Japan, we have investigated the favourable conditions for the predominant existence of large-scale turbulence structures in the near-neutral atmospheric boundary layer (ABL). From the wavelet variance spectrum for the streamwise velocity component ( $u$ ) measured by a sonic anemometer-thermometer at the highest level (200 m), large-scale structures (time-scale range of 100–300 s) predominantly exist under slightly unstable and close to neutral conditions. The emergence of large-scale structures also can be related to the diurnal evolution of the ABL. The large-scale structures play an important role in the overall flow structure of the lower boundary layer. For example, $u$ velocity components at the 200-m and 50-m levels show relatively high correlation with the existence of large-scale structures. Under slightly unstable (near-neutral) conditions, a low-speed region in advance of the high-speed structure shows a positive deviation of temperature and appears as the plume structure that is forced by buoyancy in the heated lower layer. In spite of the difference in buoyancy effects between the near-neutral and unstable cases, large-scale structures are frequently observed in both cases and the same vertical correlation of $u$ components is indicated. However, the vertical wind shear is smaller in the unstable cases. On the other hand, in near-neutral cases, the transport efficiency of momentum at the higher level and the flux contribution of sweep motions are larger than those in the unstable cases.     

Determination of Arsenic and Antimony in Eighty-Five Geochemical Reference Samples by Automated Hydride Generation and Electrothermal Atomic Absorption Spectrometry

The arsenic and antimony contents of 85 geochemical reference samples have been determined by atomic absorption spectrometry with hydride generation and heated quartz cell atomizer. The sample is decomposed with a mixture of perchloric, nitric and hydrofluoric acids and potassium permanganate solution; interferences are eliminated by addition of potassium iodide, aluminium chloride and ascorbic acid. The agreement between the present results and published data is fairly good.     

Determination of Beryllium in Eighty Geological Reference Samples by Atomic Absorption Spectrometry

The beryllium content of eighty geological reference samples has been determined by atomic absorption spectrometry using a nitrous oxide-acetylene flame or a carbon tube atomizer, after extraction of beryllium as acetylacetonate with methylisobutylketone (MIBK). The agreement between the present results and published data is generally good.     

Evolution of Planetesimal Velocities Based on Three-Body Orbital Integrations and Growth of Protoplanets

We obtain the viscous stirring and dynamical friction rates of planetesimals with a Rayleigh distribution of eccentricities and inclinations, using three-body orbital integration and the procedure described by Ohtsuki (1999, Icarus137, 152), who evaluated these rates for ring particles. We find that these rates based on orbital integrations agree quite well with the analytic results of Stewart and Ida (2000, Icarus 143, 28) in high-velocity cases. In low-velocity cases where Kepler shear dominates the relative velocity, however, the three-body calculations show significant deviation from the formulas of Stewart and Ida, who did not investigate the rates for low velocities in detail but just presented a simple interpolation formula between their high-velocity formula and the numerical results for circular orbits. We calculate evolution of root mean square eccentricities and inclinations using the above stirring rates based on orbital integrations, and find excellent agreement with N-body simulations for both one- and two-component systems, even in the low-velocity cases. We derive semi-analytic formulas for the stirring and dynamical friction rates based on our numerical results, and confirm that they reproduce the results of N-body simulations with sufficient accuracy. Using these formulas, we calculate equilibrium velocities of planetesimals with given size distributions. At a stage before the onset of runaway growth of large bodies, the velocity distribution calculated by our new formulas are found to agree quite well with those obtained by using the formulas of Stewart and Ida or Wetherill and Stewart (1993, Icarus106, 190). However, at later stages, we find that the inclinations of small collisional fragments calculated by our new formulas can be much smaller than those calculated by the previously obtained formulas, so that they are more easily accreted by larger bodies in our case. The results essentially support the previous results such as runaway growth of protoplanets, but they could enhance their growth rate by 10-30% after early runaway growth, where those fragments with low random velocities can significantly contribute to rapid growth of runaway bodies.     

Semidiurnal Dynamics of Salinity, Nutrients and Suspended Particulate Matter in an Estuary in the Seto Inland Sea, Japan, during a Spring Tide Cycle

The physical and chemical variability of the water column at subtidal station of an estuary in the Seto Inland Sea, Japan, was studied over a 24-hour period during a spring tide (tidal range ca. 2 m) in May 1995. Surface water and several depths through the water column were monitored every one and two hours, respectively. At each occasion, water temperature, salinity and dissolved oxygen concentration were measured and water samples were collected for the determination of nutrients and suspended particulate matter (SPM). Disruptive changes in the physical and chemical characteristics of the water was produced by the tidal cycle and the mixing of water masses of different origin. These changes were highly significant both spatially and temporally, yet with varying effects on physical parameters, nutrients and the different components of SPM. Significant differences in nutrient concentrations were also observed when the data-set was divided into ebb and flood components, irrespective of the depth. Nitrate and nitrite rose to 1.8 times higher during the flood. Spatial differences of SPM were less marked than those of nutrients, only particulate organic carbon (POC) being significantly higher at the surface than in the intermediate and the lower layer. Both POC and pheopigment concentrations increased markedly through the water column, being highest shortly before the lower low tide. In contrast, suspended solid (SS) content increased sharply after the lower low tide (>40 mg l⁻¹) and this coincided with a marked decrease of the C/SS content (<20 mg g⁻¹). The lagtime between POC and SS tidal transport was caused by particle resuspension from the exposed intertidal sediments as the tidal level rose, and particle transport selection in relation to the tidal state. This revised version was published online in August 2006 with corrections to the Cover Date.     

Diatoms grow faster using ammonium in rapidly flushed eutrophic Dokai Bay,Japan

The importance of the nitrogen source for phytoplankton growth in a highly eutrophic embayment, Dokai Bay, was investigated. The DIN concentration often exceeded 100 μM of which 40–70% was NH₄ ⁺. During two incubation experiments, the natural assemblage of mainly diatoms took up NH₄ ⁺ instead of NO₃ ⁻. The growth of two Skeletonema species isolated in Dokai Bay were significantly faster on NH₄ ⁺ (1.86 and 1.27 div. d⁻¹ respectively) than on NO₃ ⁻ (1.55 and 1.04 div. d⁻¹ respectively). Our results indicated that these diatoms could grow faster by using NH₄ ⁺ compared to NO₃ ⁻ in this eutrophic bay.     

Strain and tilt changes measured during a water injection experiment at the Nojima Fault zone, Japan

Abstract In order to make geophysical and geological investigations of the Nojima Fault on Awaji Island, Japan, three boreholes measuring 1800 m, 800 m and 500 m deep were drilled into the fault zone. The fault is one of the seismic source faults of the 1995 Hyogo-ken Nanbu earthquake of M 7.2. A new multicomponent borehole instrument was installed at the bottom of the 800 m borehole and continuous observations of crustal strain and tilt have been made using this instrument since May 1996. A high-pressure water injection experiment within the 1800 m borehole was done in February and March 1997 to study the geophysical response, behavior, permeability, and other aspects of the fault zone. The injection site was located approximately 140 m horizontally and 800 m vertically from the instrument. Associated with the water injection, contraction of approximately 0.7 × 10⁻⁷ str (almost parallel to the fault) and tilt of approximately 1 × 10^-7 rad in the sense of upheaval toward the injection site were observed. In addition to these controlled experiments, the strainmeter and tiltmeter also recorded daily variations. We interpret strain and tilt changes to be related to groundwater discharge and increased ultra-micro seismicity induced by the injected water.