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1.
The complete travel-time equation of state (CT-EOS) is presented by utilizing thermodynamics relations, such as; $$K_T = K_S (1 + \alpha \gamma T)^{ - 1} , \gamma = \frac{{\alpha K_S }}{{\rho C_P }}, \left. {\frac{{\partial C_P }}{{\partial P}}} \right)_T = - \frac{T}{\rho }\left[ {\alpha ^2 + \left. {\frac{{\partial \alpha }}{{\partial T}}} \right)_P } \right], etc.$$ The CT-EOS enables us to analyze ultrasonic experimental data under simultaneous high pressure and high temperature without introducing any assumption, as long as the density, or thermal expansivity, and heat capacity are also available as functions of temperature at zero pressure. The performance of the CT-EOS was examined by using synthesized travel-time data with random noise of 10?5 and 10?4 amplitude up to 4 GPa and 1500 K. Those test conditions are to be met with the newly developed GHz interferometry in a gas medium piston cylinder apparatus. The results suggest that the combination of the CT-EOS and accurate experimental data (10?4 in travel time) can determine thermodynamic and elastic parameters, as well as their derivatives with unprecedented accuracy, yielding second-order pressure derivatives (?2 M/?P 2) of the elastic moduli as well as the temperature derivatives of their first-order pressure derivatives ?2 M/?P?T). The completeness of the CT-EOS provides an unambiguous criterion to evaluate the compatibility of empirical EOS with experimental data. Furthermore because of this completeness, it offers the possibility of a new and absolute pressure calibration when X-ray (i.e., volume) measurements are made simultaneously with the travel-time measurements. 相似文献
2.
Tadashi Kondo Hiroshi Sawamoto Akira Yoneda Manabu Kato Akihito Matsumuro Takehiko Yagi Takumi Kikegawa 《Pure and Applied Geophysics》1993,141(2-4):601-611
A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm3 is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation. 相似文献
3.
Single-crystal elasticity of stishovite was examined using a new experimental technique and an empirical macroscopic model. Employing high-frequency resonant ultrasound spectroscopy, single-crystal elastic constants of stishovite were determined: C11 = 443(3), C33 = 781(4), C12 = 193(2), C23 = 199(2), C44 = 256(2), and C33 = 316(2) GPa. The frequency range of the resonant ultrasound spectroscopy techniques was 6–20 MHz, which is much lower than the ~10 GHz range of the Brillouin scattering technique. Of the elastic constants, the shear elastic constants C44 and C66 are consistent with the average value of the previously mentioned Brillouin scattering. Conversely, the four elastic constants, C11, C33, C12, and C23, slightly deviate outside the range of previous Brillouin scattering results. The present results, except those for C12, are consistent with recent lattice dynamic analysis of inelastic X-ray scattering data. The adiabatic bulk modulus was calculated as 298 GPa, which is smaller and more consistent with the result of compression experiments than any other Brillouin scattering results (301–312 GPa). The present result shows greater P-wave velocity anisotropy (24.7%) than any preceding work. To understand the unique elastic properties of stishovite, the Gingham check model was proposed and examined. The result shows that the octahedron of 6-coordinated Si in stishovite crystal has stiffness comparable to that of diamond. 相似文献
4.
Horizontal bidirectional loading tests are conducted for real-sized high-damping rubber (HDR) bearings with diameters of 700 mm (HDR700) and 1300 mm (HDR1300). The hysteresis loops of these bearings under bidirectional horizontal loadings are compared with those under unidirectional loadings. The results show that the bearing force measurement in the primary direction of loading increases when there is displacement in the orthogonal direction. Unusually, the maximum restoring force in the orthogonal direction to the primary loading direction occurs near zero displacement. On the basis of the observations of the restoring forces, a rate-independent model is proposed. This model simulates well the test results under both bidirectional loading and unidirectional loading. It can reproduce the irregular restoring forces characteristics around zero displacement as described above. Bidirectional loading induced twist deformation in the HDR bearings that increased local shear strains. This phenomenon results in an early failure as observed in HDR700. The additional shear strain is estimated based on the twist deformation measured by video image analysis. The comparison of the nominal total shear stress demonstrates that the increase of shear stress because of bidirectional loading occurs when the average shear strain is larger than about 200%. The larger the shear strain, the greater the bidirectional effect. It is shown that the nominal total shear stress of average strain of 350% under bidirectional circular loading pattern is approximately the same as the average shear strain of 400% under unidirectional loading. This means that the average shear strain of 350% under a bidirectional circular loading corresponds to a local shear strain of 400%. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
5.
Formation and deformation processes of the late Paleogene sedimentary basins related to a strike–slip fault system in southern central Hokkaido are described by a combination of paleomagnetic study and numerical analysis. After correction of the Miocene counter‐clockwise rotation associated with back‐arc opening of the Japan Sea, paleomagnetic declination data obtained from surface outcrops in the Umaoi and Yubari areas show significant easterly deflections. Although complicated differential rotation is anticipated as a result of recent thrust movements, clockwise rotation in the study areas is closely linked with development of the Paleogene Minami‐naganuma Basin as a pull‐apart depression along the north–south fault system. Numerical modeling suggests that 30 km of strike–slip is required to restore the distribution and volume of the Minami‐naganuma Basin. The relative slip rate on the long‐standing fault system is about 10 mm/yr, which corresponds to global‐scale plate motion. It has inevitably caused regional rearrangement of the eastern Eurasian margin. A rotation field simulated by simplified dextral motion using dislocation modeling basically accords with the paleomagnetic data around the pull‐apart basin. 相似文献
6.
The Sm and Gd isotopic compositions of silicates from six mesosiderites (Dalgaranga, Estherville, Morristown, Northwest Africa (NWA) 1242, NWA 2932, and Vaca Muerta) and one iron meteorite (Udei Station) were determined to elucidate the cosmic-ray exposure records. All seven samples showed significant 150Sm/149Sm and 158Gd/157Gd isotopic shifts from neutron capture reactions corresponding to neutron fluences of (1.3-21.8) × 1015 n cm−2. In particular, Vaca Muerta showed a significantly higher neutron fluences than the other six samples. The parameter for the degree of neutron thermalization (εSm/εGd) also showed a significant difference between Vaca Muerta (0.76) and the other samples (0.93-1.20). These results suggest a two-stage irradiation of the Vaca Muerta silicates in the parent body (>50 Ma) before formation of the mesosiderite and during its transit to Earth (138 Ma). This is consistent with the 81Kr-Kr cosmic-ray exposure age data of a Vaca Muerta pebble from a previous noble gas isotopic study. 相似文献
7.
8.
S. Ono E. Ito T. Katsura A. Yoneda M. J. Walter S. Urakawa W. Utsumi K. Funakoshi 《Physics and Chemistry of Minerals》2000,27(9):618-622
In situ synchrotron X-ray experiments in the system SnO2 were made at pressures of 4–29 GPa and temperatures of 300–1400 K using sintered diamond anvils in a 6–8 type high-pressure
apparatus. Orthorhombic phase (α-PbO2 structure) underwent a transition to a cubic phase (Pa3ˉ structure) at 18 GPa. This transition was observed at significantly lower pressures in DAC experiments. We obtained the
isothermal bulk modulus of cubic phase K
0 = 252(28) GPa and its pressure derivative K
′=3.5(2.2). The thermal expansion coefficient of cubic phase at 25 GPa up to 1300 K was determined from interpolation of the
P-V-T data obtained, and is 1.7(±0.7) × 10−5 K−1 at 25 GPa.
Received: 7 December 1999 / Accepted: 27 April 2000 相似文献
9.
The effects of water residence time and anoxic conditions on the mobilization and speciation of As in a calcite- and pyrite-bearing altered rock excavated during a road-tunnel project has been evaluated using batch and column laboratory experiments. Higher infiltration rates (i.e., shorter water residence times) enhanced the leaching of As due to the higher pH values of the effluents and more rapid transport of dissolved As through the columns. The concentration of As in the effluent also increased under anoxic conditions regardless of the water residence time. This enhanced leaching of As under anoxic conditions could be attributed to a significant pH increase and decreased Fe oxyhydroxide/oxide precipitation compared to similar experiments done under ambient conditions. Processes that controlled the evolution of pH and the temporal release mechanisms of As under anoxic conditions were identical to those previously observed under ambient conditions: the dissolution of soluble phases, pyrite oxidation, co-precipitation and/or adsorption/desorption reactions. Speciation of As in the column experiments could partly be attributed to the pH-dependent adsorption of As species onto Fe oxyhydroxide/oxide precipitates. Moreover, apparent equilibrium of the total As and As[III] concentrations was delayed under anoxic conditions in both batch and column experiments. 相似文献
10.
Hiroshi HIDAKA Shigekazu YONEDA Kunihiko NISHIIZUMI 《Meteoritics & planetary science》2010,45(12):1973-1981
Abstract– The isotopic compositions of Sm and/or Gd of nine documented drill core samples of the Jilin H5 chondrite were determined to study the neutron capture records of individual meteorite samples. All the samples showed significant isotopic shifts of 150Sm/149Sm and/or 158Gd/157Gd corresponding to neutron fluences of (1.3–1.7) × 1015 n cm?2. Considering the short 4π irradiation age of 0.32 Ma during the second stage, the 2π irradiation of 7 Ma during the first stage is the main influence on the Sm and Gd isotopic shifts of the Jilin chondrite. Although a depth dependence of the neutron capture effects was expected from the isotopic variations of 150Sm/149Sm and 158Gd/157Gd in the Jilin chondrite core samples that were possibly drilled perpendicular to the surface of the large object with a radius of >10 m in the 2π‐geometry, no clear evidence was observed in this study. The data from the combination of the isotopic shifts between Sm and Gd defined as εSm/εGd suggest that the neutrons produced in the 2π‐geometry of the Jilin chondrite follow the similar energy spectra as the neutrons in lunar samples, although the present analytical quality is not enough to discuss a critical discussion for the thermalization of the neutron energy levels. 相似文献