The quaternary glacial history of the Lahul Himalaya,northern India

This paper presents the first glacial chronology for the Lahul Himalaya, Northern India. The oldest glaciation, the Chandra Glacial Stage, is represented by glacially eroded benches at altitudes greater than 4300 m above sea-level. This glaciation was probably of a broad valley type. The second glaciation, the Batal Glacial Stage, is represented by highly weathered and dissected lateral moraines, which are present along the Chandra valley and some of its tributaries. This was an extensive valley glaciation. The third major glaciation, the Kulti Glacial Stage, is represented by well-preserved moraines in the main tributary valleys of the Chandra valley. This represents a less extensive valley glaciation. Two minor glacial advances, the Sonapani I and II, are represented by small sharp-crested moraines, which are within a few hundred metres or few kilometres of the present-day glaciers. The change in style and extent of glaciation is attributed to an increase in aridity throughout the Quaternary, due either to global climatic change or uplift of the Pir Panjal mountains to the south of Lahul, which restricted the northward penetration of the south Asian summer monsoon. © 1996 John Wiley & Sons, Ltd.     

Cu(II) adsorption at the calcite-water interface in the presence of natural organic matter: Kinetic studies and molecular-scale characterization

We have characterized the adsorption of Suwannee River humic acid (SRHA) and Cu(II) on calcite from preequilibrated solutions at pH 8.25. Sorption isotherms of SRHA on calcite follow Langmuir-type behavior at SRHA concentrations less than 15 mg C L⁻¹, whereas non-Langmuirian uptake becomes evident at concentrations greater than 15 mg C L⁻¹. The adsorption of SRHA on calcite is rapid and mostly irreversible, with corresponding changes in electrostatic properties. At pH 8.25, Cu(II) uptake by calcite in the presence of dissolved SRHA decreases with increasing dissolved SRHA concentration, suggesting that formation of Cu-SRHA aqueous complexes is the primary factor controlling Cu(II) sorption at the calcite surface under the conditions of our experiments. We also observed that surface-bound SRHA has little influence on Cu(II) uptake by calcite, suggesting that Cu(II) coordinates to calcite surface sites rather than to surface-bound SRHA.Cu K-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopic results show that the local coordination of Cu adsorbed at the calcite surface is very similar in the presence and absence of SRHA. Ca backscatterers at ∼3.90 Å indicate that Cu(II) forms tetragonally distorted inner-sphere adsorption complexes in both binary and ternary systems. Subtle differences in the XANES and EXAFS between binary sorption samples and ternary sorption samples, however, prevent us from ruling out the formation of ternary Cu-SRHA surface complexes. Our findings demonstrate that SRHA plays an important role in controlling the fate and transport of Cu(II) in calcite-bearing systems.     

Clues from Current High CO2 Environments on the Effects of Ocean Acidification on CaCO3 Preservation

Acidification of surface seawater owing to anthropogenic activities has raised serious concerns on its consequences for marine calcifying organisms and ecosystems. To acquire knowledge concerning the future consequences of ocean acidification (OA), researchers have relied on incubation experiments with organisms exposed to future seawater conditions, numerical models, evidence from the geological record, and recently, observations from aquatic environments exposed to naturally high CO₂ and low pH, e.g., owing to volcanic CO₂ vents, upwelling, and groundwater input. In the present study, we briefly evaluate the distribution of dissolved CO₂–carbonic acid parameters at (1) two locations in the Pacific and the Atlantic Ocean as a function of depth, (2) a mangrove environment in Bermuda, (3) a seasonally stratified body of water in a semi-enclosed sound in Bermuda, and (4) in temporarily isolated tide pools in Southern California. We demonstrate that current in situ conditions of seawater pCO₂, pH, and CaCO₃ saturation state (Ω) in these environments are similar or even exceed the anticipated changes to these parameters in the open ocean over the next century as a result of OA. The observed differences between the Pacific and Atlantic Oceans with respect to seawater CO₂–carbonic acid chemistry, preservation of CaCO₃ minerals, and the occurrence and distribution of deep-sea marine calcifiers, support the hypothesized negative effects of OA on the production and preservation of CaCO₃ in surface seawater. Clues provided from shallow near-shore environments in Bermuda and Southern California support these predictions, but also highlight that many marine calcifiers already experience relatively high seawater pCO₂ and low pH conditions.     

Compound‐Specific Isotope Analyses to Assess TCE Biodegradation in a Fractured Dolomitic Aquifer

The potential for trichloroethene (TCE) biodegradation in a fractured dolomite aquifer at a former chemical disposal site in Smithville, Ontario, Canada, is assessed using chemical analysis and TCE and cis‐DCE compound‐specific isotope analysis of carbon and chlorine collected over a 16‐month period. Groundwater redox conditions change from suboxic to much more reducing environments within and around the plume, indicating that oxidation of organic contaminants and degradation products is occurring at the study site. TCE and cis‐DCE were observed in 13 of 14 wells sampled. VC, ethene, and/or ethane were also observed in ten wells, indicating that partial/full dechlorination has occurred. Chlorine isotopic values (δ³⁷Cl) range between 1.39 to 4.69‰ SMOC for TCE, and 3.57 to 13.86‰ SMOC for cis‐DCE. Carbon isotopic values range between ?28.9 and ?20.7‰ VPDB for TCE, and ?26.5 and ?11.8‰ VPDB for cis‐DCE. In most wells, isotopic values remained steady over the 15‐month study. Isotopic enrichment from TCE to cis‐DCE varied between 0 and 13‰ for carbon and 1 and 4‰ for chlorine. Calculated chlorine‐carbon isotopic enrichment ratios (?_Cl/?_C) were 0.18 for TCE and 0.69 for cis‐DCE. Combined, isotopic and chemical data indicate very little dechlorination is occurring near the source zone, but suggest bacterially mediated degradation is occurring closer to the edges of the plume.     

The Evolution of Sunspot Magnetic Fields Associated with a Solar Flare

Solar flares occur due to the sudden release of energy stored in active-region magnetic fields. To date, the precursors to flaring are still not fully understood, although there is evidence that flaring is related to changes in the topology or complexity of an active-region’s magnetic field. Here, the evolution of the magnetic field in active region NOAA 10953 was examined using Hinode/SOT-SP data over a period of 12 hours leading up to and after a GOES B1.0 flare. A number of magnetic-field properties and low-order aspects of magnetic-field topology were extracted from two flux regions that exhibited increased Ca ii H emission during the flare. Pre-flare increases in vertical field strength, vertical current density, and inclination angle of ≈ 8° toward the vertical were observed in flux elements surrounding the primary sunspot. The vertical field strength and current density subsequently decreased in the post-flare state, with the inclination becoming more horizontal by ≈ 7°. This behavior of the field vector may provide a physical basis for future flare-forecasting efforts.     

Geophysical constraints on deep weathering and water storage potential in the Southern Sierra Critical Zone Observatory

The conversion of bedrock to regolith marks the inception of critical zone processes, but the factors that regulate it remain poorly understood. Although the thickness and degree of weathering of regolith are widely thought to be important regulators of the development of regolith and its water‐storage potential, the functional relationships between regolith properties and the processes that generate it remain poorly documented. This is due in part to the fact that regolith is difficult to characterize by direct observations over the broad scales needed for process‐based understanding of the critical zone. Here we use seismic refraction and resistivity imaging techniques to estimate variations in regolith thickness and porosity across a forested slope and swampy meadow in the Southern Sierra Critical Zone Observatory (SSCZO). Inferred seismic velocities and electrical resistivities image a weathering zone ranging in thickness from 10 to 35 m (average = 23 m) along one intensively studied transect. The inferred weathering zone consists of roughly equal thicknesses of saprolite (P‐velocity < 2 km s^?1) and moderately weathered bedrock (P‐velocity = 2–4 km s^?1). A minimum‐porosity model assuming dry pore space shows porosities as high as 50% near the surface, decreasing to near zero at the base of weathered rock. Physical properties of saprolite samples from hand augering and push cores are consistent with our rock physics model when variations in pore saturation are taken into account. Our results indicate that saprolite is a crucial reservoir of water, potentially storing an average of 3 m³ m^?2 of water along a forested slope in the headwaters of the SSCZO. When coupled with published erosion rates from cosmogenic nuclides, our geophysical estimates of weathering zone thickness imply regolith residence times on the order of 10⁵ years. Thus, soils at the surface today may integrate weathering over glacial–interglacial fluctuations in climate. Copyright © 2013 John Wiley & Sons, Ltd.     

Market access,population density,and socioeconomic development explain diversity and functional group biomass of coral reef fish assemblages

There is overwhelming evidence that many local-scale human activities (e.g. fishing) have a deleterious effect on coral reef fish assemblages. Our understanding of how broad social phenomena (e.g. socioeconomic development) affect the diversity and function of coral reef fish assemblages however, is still poor. Here, we use structural equation models to reveal how human population density, socioeconomic development, and market access affect fishing pressure and coral cover to, in turn, explain the diversity and biomass of key functional groups of reef fish assemblages within Solomon Islands. Fishing pressure is predominantly driven by both market access and local population density, and has a clear negative effect on the diversity and function of coral reef fishes. The strong positive effect of market access on fishing pressure makes clear the importance of understanding social-ecological linkages in the context of increasingly connected societies. This study highlights the need to address broad social phenomena rather than focusing on proximate threats such as fishing pressure, to ensure the continued flow of coral reef goods and services in this time of rapid global social and environmental change.