Chemical weathering of carbonates and silicates in the Han River basin,South Korea

A detailed investigation of the fluvial geochemistry of the Han River system allows to estimate the rates of chemical weathering and the consumption of CO₂. The Han River drains approximately 26,000 km² and is the largest river system in South Korea in terms of both water discharge and total river length. It consists of two major tributaries: the North Han River (NHR) and the South Han River (SHR). Distinct differences in basin lithology (silicate vs. carbonate) between the NHR and SHR provide a good natural laboratory in which to examine weathering processes and the influence of basin geology on water quality. The concentrations of major elements and the Sr isotopic compositions were obtained from 58 samples collected in both summer and winter along the Han River system in both 2000 and 2006. The concentrations of dissolved loads differed considerably between the NHR and SHR; compared with the SHR, the NHR had much lower total dissolved solids (TDS), Sr, and major ion concentrations but a higher Si concentration and ⁸⁷Sr/⁸⁶Sr ratio. A forward model showed that the dissolved loads in the NHR came primarily from silicate weathering (55 ± 11%), with a relatively small portion from carbonates (30 ± 14%), whereas the main contribution to the dissolved loads in the SHR was carbonate weathering (82 ± 3%), with only 11 ± 4% from silicates. These results are consistent with the different lithologies of the two drainage basins: silicate rocks in the NHR versus carbonate rocks in the SHR. Sulfuric acid derived from sulfide dissolution in coal-containing sedimentary strata has played an important role in carbonate weathering in the SHR basin, unlike in the NHR basin. The silicate weathering rate (SWR) was similar between the NHR and SHR basins, but the rate of CO₂ consumption in the SHR basin was lower than in the NHR basin due to an important role of sulfuric acid derived from pyrite oxidation.     

ENSO stability in coupled climate models and its association with mean state

In this study, using the Bjerknes stability (BJ) index analysis, we estimate the overall linear El Niño-Southern Oscillation (ENSO) stability and the relative contribution of positive feedbacks and damping processes to the stability in historical simulations of Coupled Model Intercomparison Project Phase 5 (CMIP5) models. When compared with CMIP3 models, the ENSO amplitudes and the ENSO stability as estimated by the BJ index in the CMIP5 models are more converged around the observed, estimated from the atmosphere and ocean reanalysis data sets. The reduced diversity among models in the simulated ENSO stability can be partly attributed to the reduced spread of the thermocline feedback and Ekman feedback terms among the models. However, a systematic bias persists from CMIP3 to CMIP5. In other words, the majority of the CMIP5 models analyzed in this study still underestimate the zonal advective feedback, thermocline feedback and thermodynamic damping terms, when compared with those estimated from reanalysis. This discrepancy turns out to be related with a cold tongue bias in coupled models that causes a weaker atmospheric thermodynamical response to sea surface temperature changes and a weaker oceanic response (zonal currents and zonal thermocline slope) to wind changes.     

Thin electron beam propagation in plasmas

The propagation of dense electron beams and the interaction with the ambient plasmas are studied by using two-dimensional electrostatic simulations. When the width of the beam is of the order of electron gyro-radius, the beam electrons move across the magnetic field lines and the beam-plasma interaction becomes prominent with the reduced beam density. When the width of the beam is of the order of ion gyro-radius, the propagation of beam electrons is possible only with the formation of the ion channel. However, since the time scale of the ionic motion is much longer than that of the electronic motion, most of the beam electrons return back to the original beam injection region     

Optimal seismic retrofit model for steel moment resisting frames with brittle connections

Based on performance-based seismic engineering, this paper proposes an optimal seismic retrofit model for steel moment resisting frames (SMRFs) to generate a retrofit scheme at minimal cost. To satisfy the acceptance criteria for the Basic Safety Objective (BSO) specified in FEMA 356, the minimum number of upgraded connections and their locations in an SMRF with brittle connections are determined by evolutionary computation. The performance of the proposed optimal retrofitting model is evaluated on the basis of the energy dissipation capacities, peak roof drift ratios, and maximum interstory drift ratios of structures before and after retrofitting. In addition, a retrofit efficiency index, which is defined as the ratio of the increment in seismic performance to the required retrofitting cost, is proposed to examine the efficiencies of the retrofit schemes derived from the model. The optimal seismic retrofit model is applied to the SAC benchmark examples for threestory and nine-story SMRFs with brittle connections. Using the retrofit efficiency index proposed in this study, the optimal retrofit schemes obtained from the model are found to be efficient for both examples in terms of energy dissipation capacity, roof drift ratio, and maximum inter-story drift ratio.     

A review on vegetation models and applicability to climate simulations at regional scale

The lack of accurate representations of biospheric components and their biophysical and biogeochemical processes is a great source of uncertainty in current climate models. The interactions between terrestrial ecosystems and the climate include exchanges not only of energy, water and momentum, but also of carbon and nitrogen. Reliable simulations of these interactions are crucial for predicting the potential impacts of future climate change and anthropogenic intervention on terrestrial ecosystems. In this paper, two biogeographical (Neilson’s rule-based model and BIOME), two biogeochemical (BIOME-BGC and PnET-BGC), and three dynamic global vegetation models (Hybrid, LPJ, and MC1) were reviewed and compared in terms of their biophysical and physiological processes. The advantages and limitations of the models were also addressed. Lastly, the applications of the dynamic global vegetation models to regional climate simulations have been discussed.     

Monitoring trace metals in seawater using a diffusive gradient in thin film probe in Ulsan Bay,East Sea,Korea: Comparison with transplanted mussels

To evaluate the applicability of a diffusive gradient in thin film (DGT) probe for monitoring dissolved metals in coastal seawater, DGT-labile metal concentrations were compared with total dissolved metal concentrations using spiked and natural seawater samples in the laboratory and transplanted mussels (Mytilus galloprovincialis). This was achieved through the simultaneous deployment of DGT probes and transplanted mussels in Ulsan Bay during winter and summer. DGT-labile metal concentrations were 45% (Cu) ~ 90% (Zn) of total dissolved concentrations, and the order of non-labile concentrations was Cu > Pb > Co ~ Ni > Cd ~ Zn in both metal-contaminated and non-contaminated seawater samples, which was similar to the order of stability of metal complexes in the Irving–Williams series. The overall variability of the DGT probe results within and between tanks was less than 10% (relative standard deviation: RSD) for all the metals tested during a 48-h deployment. The accumulation of metals, as determined by DGT probes, represented the spatial gradients better than the transplanted mussels did for all of the metals tested, and the extent of metal accumulation in mussels differed depending on the metal. The comparison of results for the DGT probe and the transplanted mussels in two seasons (winter and summer) suggested that metal accumulation in mussels was controlled by the physiological factors of mussels and partly by their diet (particulate metal loadings). The DGT probe could be used as a monitoring tool for dissolved metals in coastal seawater because its results explained only labile species. When using the DGT probe, slightly more than half of the total dissolved concentration in seawater samples for all the metals investigated displayed timeintegrated properties and distinct spatial gradients from pristine to metal-contaminated seawater.     

Genetic Implications of Two Different Ultramafic Rocks from Hongseong Area in the Southwestern Gyeonggi Massif, South Korea

Two distinct ultramafic bodies occur in Baekdong and Bibong in the Hongseong area within Gyeonggi massif of South Korea. The Hongseong area is now extensively documented as an extension of the Dabie-Sulu collision belt in China. The Baekdong ultramafic body has a NWW elongation direction. This elongation trend is similar to the general trend of the Dabie-Sulu collision belt. The Bibong ultramafic body is elongated in a NNE direction and runs parallel to the direction of the main fault in the study area. The Baekdong ultramafic bodies show porphyroclastic and mylonitic textures while those at Bibong exhibit a mosaic texture. Both were grouped into peridotite and serpentinite based on their modal abundance of serpentine. In the olivine (Fo) vs. spinel [Cr# = Cr/ (Cr+Al)] diagram, both ultramafic rocks fall with in olivine spinel mantle array. The compositions of olivine, orthopyroxene and spinel indicate that the Baekdong ultramafic rock formed in deeper parts of the upper-mantle under passive margin tectonic setting. The SREE content of Baekdong ultramafic rock vary from 0.19 to 5.7, exhibits a flat REE pattern in the chondrite-normalized diagram, and underwent 5% partial melting. Conversely, large variation in SREE (0.5 21.53) was observed for Bibong ultramafic rocks with an enrichment of LREE with a negative slope and underwent 17 24% partial melting. The Baekdong ultramafic rocks experienced three stages of metamorphism after a high pressure residual mantle stage. The first stage of metamorphism occurred under the eclogite-granulite transitional facies (1123 911°C, >16.3 kb) the second under the granulite facies (825 740°C, 16.3 11.8 kb) and the third is the retrogressive metamorphism under amphibolite facies (782 718°C, 8.2 8.7 kb) metamorphism. The Baekdong ultramafic rocks had undergone high-P/T metamorphism during subduction of the South China Block, and experienced a fast isothermal uplift, and finally cooled down isobarically. Evidences for metamorphism were not identified in Bibong ultramafic rocks. Hence, the Baekdong ultramafic rocks with in the Hongseong area may indicate a link on the Korean counterpart of Dabie-Sulu collision belt between North and South China Blocks.     

Shaking table tests on a high‐rise RC building model having torsional eccentricity in soft lower storeys

A series of shaking table tests on a 1:12‐scale model using scaled TaftN21E earthquake records were conducted to investigate the seismic performance of a 17‐storey high‐rise reinforced concrete structure with a high degree of torsional eccentricity and soft‐storey irregularities in the bottom two storeys. Based on the analysis of test results, the following conclusions were drawn: (1) the model responded mainly in the coupled mode of translation and torsion or in the torsional mode. Under severe table shaking, the flexible side underwent large inelastic deformation, and the predominant mode of the model changed from the coupled mode to the torsional mode, resulting in greatly increased torsional stiffness, thereby limiting damage in the flexible frame; (2) the shear force and deformation of the flexible side were governed by the torsional behaviour, whereas those of the stiff side were affected mainly by the overturning deformation. The lateral stiffness of the shear wall in the torsional mode was about four times that in the coupled mode because the warping deformation due to torsion counteracted the flexural deformation due to overturning moment in the torsional mode; and (3) the reversed cyclic overturning moments predicted by linear elastic dynamic analysis in the direction transverse to the table excitations contradicted unilateral overturning moments of the serviceability‐level test results, which showed a bias towards tension or compression in the columns. Copyright © 2006 John Wiley & Sons, Ltd.