Diagenetisch gebildeter Magnesit und Dolomit in den Grödener Schichten des Dobratsch im Gailtal,Kärnten — österreich

Dolomite, magnesite, calcite and aragonite are described from sandstones and conglomerates of the Grödener Schichten of the Dobratsch in the Gailtal Alps, Carinthia — Austria. The carbonates occur as early and late diagenetic cements, as recrystallized matrix of more or less laminated carbonate layers (up to 0.5 m thick), as concretions, as fillings of early diagenetic shrinkage cracks and late diagenetic fissures and as crystals in open cavities and clefts. The formation of dolomite and magnesite may have been caused by pore solutions highly enriched in magnesium, which are likely to have formed by evaporation in a hypersaline environment. Magnesite and dolomite most probably have been formed diagenetically from aragonite and/or calcite during progressive evaporation cycles. Because of magnesite is a common constituent in Permo-Scythian sediments of the Eastern Alps, its presence is of importance for the evaluation of the environment. Additionally the wide-spread occurrence of magnesite within these post variscian sediments has important implications regarding the paleogeographical reconstruction and the evaluation of diagenetic processes.     

Polarized single-crystal FTIR-spectra of natural staurolite

Polarized infrared absorption spectra of thin single-crystal slabs parallel to (010) and (001) of a staurolite from Pizzo Forno, Ticino, with analyzed composition (Fe_2.9Mg_0.9Zn_0.1Mn_0.1)Al_17.5Ti_0.1(Si_7.7Al_0.3)O₄₈H₃ have been measured in the range of 3000–4000 cm^?1. From the pleochroitic behaviour of the OH-vibrations three groups of bands can be distinguished: the bands of group I, a strong band at 3445 cm^?1 plus a weak shoulder at 3358 cm^?1, and the bands of group II, a weak band centered at 3677 cm^?1 plus a shoulder at 3635 cm^?1, are assigned to the H1 and H2 protons, respectively. The bands of group III, a weak band at 3577 cm^?1 plus a shoulder, cannot be interpreted on the basis of the proton positions known so far. We assign them to an additional proton H3, which is bonded to O1 and shows a bifurcated hydrogen bridge to two O5 in a vacant T2 site.     

A sulfur isotope study of volcanogenic massive sulfide deposits of the Eastern Black Sea province,Turkey

Kuroko-type massive sulfide deposits of the Eastern Black Sea province of Turkey are related to the Upper Cretaceous felsic lavas and pyroclastic rocks, and associated with clay and carbonate alteration zones in the footwall and hangingwall lithologies. A complete upward-vertical section of a typical orebody consists of a stringer-disseminated sulfide zone composed mainly of pyrite and chalcopyrite; a massive pyrite zone; a massive yellow ore consisting mainly of chalcopyrite and pyrite; a black ore made up mainly of galena and sphalerite with minor amounts of chalcopyrite, bornite, pyrite and various sulfosalts; and a barite zone. Most of the deposits in the province are associated with gypsum in the footwall or hangingwall. The paragenetic sequence in the massive ore is pyrite, sphalerite, chalcopyrite, bornite, galena and various sulfosalts, with some overlap between the mineral phases. Massive, stringer and disseminated sulfides from eight kuroko-type VMS deposits of the Eastern Black Sea province have a ³⁴S range of 0–7 per mil, consistent with the ³⁴S range of felsic igneous rocks. Sulfides in the massive ore at Madenköy (4.3–6.1 per mil) differ isotopically from sulfides in the stringer zone (6.3–7.2 per mil) suggesting a slightly increased input of H₂S derived from marine sulfate with time. Barite and coarse-grained gypsum have a ³⁴S range of 17.7–21.5 per mil, a few per mil higher than the ³⁴S value of contemporaneous seawater sulfate. The deposits may, therefore, have formed in restricted basins in which bacterial reduction of sulfate was taking place. Fine-grained, disseminated gypsum at Kutlular and Tunca has ³⁴S values (2.6–6.1 per mil) overlapping those of ore sulfides, indicating sulfide oxidation during waning stages of hydrothermal activity.     

Hydrochemical characterisation of ground and surface water at Dörtyol/Hatay/Turkey

The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.     

Boron incorporation into mullite

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria     

Petrogenesis of the ü?kap?l? Granitoid and its Mafic Enclaves in Elmal? Area (Ni?de, Central Anatolia, Turkey)

The Late Cretaceous ükapili Granitoid including mafic microgranular enclaves intruded into metapelitic and metabasic rocks, and overlain unconformably by Neogene ignimbrites in the Ni de area of Turkey. It is mostly granite and minor granodiorite in composition, whereas its enclaves are dominantly gabbro with a few diorites in composition. The ükapili Granitoid is composed mainly of quartz, K-feldspar, plagioclase, biotite, muscovite and minor amphibole while its enclaves contain mostly plagioclase, amphibole, minor pyroxene and biotite. The ükapili Granitoid has calcalkaline and peraluminous (A/CNK= 1.0-1.3) geochemical characteristics. It is characterized by high LILE/HFSE and LREE/HREE ratios ((La/Lu) N = 3-33), and has negative Ba, Ta, Nb and Eu anomalies, resembling those of collision granitoids. The ükapili Granitoid has relatively high 87Sr/86Sr (i) ratios (0.711189-0.716061) and low εNd (t) values (-5.13 to -7.13), confirming crustal melting. In contrast, the enclaves are tholeiitic and metaluminous, and slightly enriched in LILEs (K, Rb) and Th, and have negative Ta, Nb and Ti anomalies; propose that they were derived from a subduction-modified mantle source. Based on mineral and whole rock chemistry data, the ükapili granitoid is H-(hybrid) type, post-collision granitoid developed by mixing/mingling processes between crustal melts and mantle-derived mafic magmas.     

Late Ordovician climbing‐dune cross‐stratification: a signature of outburst floods in proglacial outwash environments?

Climbing dune‐scale cross‐statification is described from Late Ordovician paraglacial successions of the Murzuq Basin (SW Libya). This depositional facies is comprised of medium‐grained to coarse‐grained sandstones that typically involve 0·3 to 1 m high, 3 to 5 m in wavelength, asymmetrical laminations. Most often stoss‐depositional structures have been generated, with preservation of the topographies of formative bedforms. Climbing‐dune cross‐stratification related to the migration of lower‐flow regime dune trains is thus identified. Related architecture and facies sequences are described from two case studies: (i) erosion‐based sandstone sheets; and (ii) a deeply incised channel. The former characterized the distal outwash plain and the fluvial/subaqueous transition of related deltaic wedges, while the latter formed in an ice‐proximal segment of the outwash plain. In erosion‐based sand sheets, climbing‐dune cross‐stratification results from unconfined mouth‐bar deposition related to expanding, sediment‐laden flows entering a water body. Within incised channels, climbing‐dune cross‐stratification formed over eddy‐related side bars reflecting deposition under recirculating flow conditions generated at channel bends. Associated facies sequences record glacier outburst floods that occurred during early stages of deglaciation and were temporally and spatially linked with subglacial drainage events involving tunnel valleys. The primary control on the formation of climbing‐dune cross‐stratification is a combination between high‐magnitude flows and sediment supply limitations, which lead to the generation of sediment‐charged stream flows characterized by a significant, relatively coarse‐grained, sand‐sized suspension‐load concentration, with a virtual absence of very coarse to gravelly bedload. The high rate of coarse‐grained sand fallout in sediment‐laden flows following flow expansion throughout mouth bars or in eddy‐related side bars resulted in high rates of transfer of sands from suspension to the bed, net deposition on bedform stoss‐sides and generation of widespread climbing‐dune cross‐stratification. The later structure has no equivalent in the glacial record, either in the ancient or in the Quaternary literature, but analogues are recognized in some flood‐dominated depositional systems of foreland basins.