Depositional environments and facies of the Late Triassic Abu Ruweis Formation, Jordan

The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture, gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite, which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O¹⁸ content ranges from 1.45 to 8.38% PDB and the C¹³ content ranges from −1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted conditions were provided by the development of beach barriers.     

Chemical characteristics of groundwater in parts of mountainous region, Alvand, Hamadan, Iran

Eighty-seven groundwater samples have been collected from a mountainous region (Alvand, Iran) for hydrochemical investigations to understand the sources of dissolved ions and assess the chemical quality of the groundwater. Most water quality parameters are within World Health Organization acceptable limits set for drinking water. The least mineralized water is found closest to the main recharge zones and the salinity of water increased towards the north of the basin. The most prevalent water type is Ca–HCO₃ followed by water types Ca–NO₃, Ca–Cl, Ca–SO₄ and Mg–HCO₃. The Ca–NO₃ water type is associated with high nitrate pollution. Agricultural and industrial activities were associated with elevated level of NO₃⁻. Mineral dissolution/weathering of evaporites dominates the major element hydrochemistry of the area. Chemical properties of groundwater in Alvand region are controlled both by natural geochemical processes and anthropogenic activities.     

On the mechanism of winter cyclogenesis in relation to vertical axis tilt

Summary ?This work is concerned with the behavior of the vertical trough axis tilt during the development of a Mediterranean cyclone. The period covering stages of the development of the depression is from 1200 UTC 18 January to 1200 UTC 25 January 1981. Two procedures have been used to illustrate the behavior of the vertical axis tilt with the development of our case study. In the first direct procedure we trace the centers of the cyclone for each level for each day and determine its longitude. In the second indirect procedure we compute the values and signs of the product of the perturbation of temperature and meridional velocity over the computational domain. The energetics of the depression is studied and the partition of available potential energy and kinetic energy into zonal and eddy component is adopted. The energy contents and their changes in different atmospheric levels are discussed in the course of the cyclone’s development. Received April 27, 2001; Revised December 12, 2001     

Optimal design of structures for earthquake loads by a hybrid RBF-BPSO method

The optimal seismic design of structures requires that time history analyses （THA） be carried out repeatedly. This makes the optimal design process inefficient, in particular, if an evolutionary algorithm is used. To reduce the overall time required for structural optimization, two artificial intelligence strategies are employed. In the first strategy, radial basis function （RBF） neural networks are used to predict the time history responses of structures in the optimization flow. In the second strategy, a binary particle swarm optimization （BPSO） is used to find the optimum design. Combining the RBF and BPSO, a hybrid RBF-BPSO optimization method is proposed in this paper, which achieves fast optimization with high computational performance. Two examples are presented and compared to determine the optimal weight of structures under earthquake loadings using both exact and approximate analyses. The numerical results demonstrate the computational advantages and effectiveness of the proposed hybrid RBF-BPSO optimization method for the seismic design of structures.     

Removal of cadmium (II) from aqueous solution and natural water samples using polyurethane foam/organobentonite/iron oxide nanocomposite adsorbent

A novel polyurethane foam/organobentonite/iron oxide nanocomposite adsorbent was successfully prepared via in situ polymerization of toluene diisocyanate and polyol in presence of 5 wt% organobentonite/iron oxide. The obtained nanocomposite was characterized in detail, and the results revealed that the clay layers are exfoliated and/or intercalated in the polymer matrix forming a nanocomposite structure. The application of the prepared nanocomposite for adsorption of cadmium ions from aqueous solution was tested as a function of various experimental parameters using batch procedures. Adsorptive removal of Cd(II) onto the nanocomposite attained maximum at adsorbent content 1.5 g/L, pH 6, and the equilibrium was established within 60 min. Kinetic studies showed that the experimental data fit very well to pseudo-second-order model, and the adsorption process proceeds through three steps. It was found that external liquid film and intraparticle diffusion steps deeply affect the rate of Cd²⁺ ions adsorption onto the synthesized nanocomposite. Langmuir isotherm model fitted the adsorption data better than Freundlich with a maximum adsorption capacity (q _m) for Cd(II) equal to 78 mg/g under the specified experimental conditions. The synthesized nanocomposite afforded effective extraction for Cd²⁺ ions from natural water samples and excellent reusability feature. This study declares the potential efficiency of a new clay/polymer nanocomposite as alternative for wastewater remediation.     

Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Strong ground motion record selection for the reliable prediction of the mean seismic collapse capacity of a structure group

How to select a limited number of strong ground motion records (SGMRs) is an important challenge for the seismic collapse capacity assessment of structures. The collapse capacity is considered as the ground motion intensity measure corresponding to the drift‐related dynamic instability in the structural system. The goal of this paper is to select, from a general set of SGMRs, a small number of subsets such that each can be used for the reliable prediction of the mean collapse capacity of a particular group of structures, i.e. of single degree‐of‐freedom systems with a typical behaviour range. In order to achieve this goal, multivariate statistical analysis is first applied, to determine what degree of similarity exists between each selected small subset and the general set of SGMRs. Principal Component analysis is applied to identify the best way to group structures, resulting in a minimum number of SGMRs in a proposed subset. The structures were classified into six groups, and for each group a subset of eight SGMRs has been proposed. The methodology has been validated by analysing a first‐mode‐dominated three‐storey‐reinforced concrete structure by means of the proposed subsets, as well as the general set of SGMRs. The results of this analysis show that the mean seismic collapse capacity can be predicted by the proposed subsets with less dispersion than by the recently developed improved approach, which is based on scaling the response spectra of the records to match the conditional mean spectrum. Copyright © 2010 John Wiley & Sons, Ltd.     

The Effect of Moisture on the Kinetic Energy Budget of a Mediterranean Cyclone

Summary  A diagnostic energetics analysis is used to study the effects of moisture-related processes on a developing cyclone over the Mediterranean. This is done by using the moist wind component to calculate the energy budget and then the effect due to wind field changes on the kinetic energy budget is illustrated. The horizontal flux convergence serves as a major energy budget source in both cases (actual and moist wind), although the magnitude values of this term are small in the case of the moist wind. Generation of kinetic energy, is generally (in the case of moist wind), a prominent sink during the life cycle of the cyclone, and its values are greater than the corresponding ones for the actual wind field except at the decay period. Subgrid-scale sources of kinetic energy provide a substantial energy gain throughout the life cycle of the cyclone. The values of the dissipation term differ from using the actual or moist components where its values are influenced by the values of the other terms in the budget. The baroclinic generation due to the divergent moist wind component offsets by 80.8% and 12.1% for the barotropic destruction of kinetic energy by the rotational moist wind component. The divergent moist wind component was found to be very important in the synoptic-scale environments of the cyclogenesis. Both demonstrate that the divergent moist wind component is as important as the rotational moist wind component in producing generation and horizontal flux divergence of kinetic energy. Generation of kinetic energy by the divergent moist wind component seems to be a major factor leading to the creation of upper-level wind maxima north of the storm areas. Thus, these diagnostic findings suggest possible modifications to the wind field by investigating the role of the divergent moist wind component and may also be fruitful in exploring the effects of cyclogensis on the large-scale environment. Received April 27, 1998/Revised April 23, 1999     

Rock slope stability evaluation using kinematic and kinetic methods along the Kamyaran-Marivan road,west of Iran

Interest in rock slope stability in mountainous regions has increased greatly in recent years.This issue has become a topic of major interest for geoscientists and engineering professionals,as well as for private citizens and local administrators,in many parts of the world.This paper evaluates the stability of seven rock slopes along the KamyaranMarivan tourist road,Kurdistan province,Iran,using various methods.The two main reasons for performing this research were to determine whether different methods of stability analysis provide the same results,and to determine how different factors such as the presence of water,tension cracks,and seismic forces affect the stability of these rock slopes.Firstly,field investigations were performed to obtain the engineering characteristics of the rock masses,discontinuities,and intact rocks of the slopes.Secondly,laboratory tests were carried out on rock samples obtained from the slopes,to determine the engineering properties of the intact rocks.Then for each rock slope,the contour diagram of discontinuities and slope face was drawn in the Dips v.5.1 software environment,and the failure mechanism was determined based on the kinematic or stereographic method.Next,the factors of safety of the rock slopes were calculated using the limit equilibrium method,based on the failure mechanisms resulting from the kinematic method.The accuracy of the results obtained by these two methods was investigated using SWedge v.4.0 software.The results indicated that four rock slopes have a potential for plane,wedge,and toppling failure,and three others are stable.Also,it was found that the stability of the studied rock slopes decreases greatly in the presence of water,tension cracks,and seismic forces.