Hydrochemical characterization of an acid mine drainage-affected reservoir: the Sancho Reservoir,Huelva, southwest Spain

Abstract

The objectives of this study were to discover the relationship between variables in a water reservoir and the hydrochemical variations related to acid mine drainage (AMD), and to describe the horizontal stratification related to vertical salinity and variations in metals present in the region. The information obtained may be used for establishing risk evaluation criteria and to design future remediation strategies, which could be useful for new dams. The hydrochemical characterization was based on a sampling campaign performed in October 2011. A total of 28 samples, at 1-m-deep intervals, were obtained. The hydrogeochemical study of the polluted reservoir shows that the dilution effect is not sufficient to neutralize AMD contributions from mining activity. Sampling carried out from the surface water to the deepest points reveals stratification of the reservoir that allows it to be included in the group of monomictic and holomitic lakes.

Editor D. Koutsoyiannis; Associate editor M.D. Fidelibus     

Exploring the role of topography in small channel erosion

Erosion caused by concentrated flows in agricultural areas is responsible for important soil losses, and rapid sediment transfer through the channel network. The main factors controlling concentrated flow erosion rates include the erodibility of soil materials, soil use and management, climate and watershed topography. In this paper, two topographic indices, closely related to mathematical expressions suggested by different authors, are used to characterize the influence of watershed topography on gully erosion. The AS1 index is defined as the product of the watershed area and the partial area‐weighted average slope. The AS2 index is similar to the AS1 but uses the swale slope as the weighting factor. Formally, AS2 is the product of the watershed area and the length‐weighted average swale slope. From studies made using different ephemeral gully erosion databases, it is shown that a high correlation consistently exists between the topographic indices and the volume of eroded soil. The resulting relationships are therefore useful to assess soil losses from gully erosion, to identify the most susceptible watersheds within large areas, and to compare the susceptibility to gully erosion among different catchments. This information is also important in studying the response of natural drainage network systems to different rainfall inputs. Copyright © 2005 John Wiley & Sons, Ltd.     

Assessing soil erosion rates in cultivated areas of Navarre (Spain)

Although there is much evidence of intense soil erosion in cultivated areas of Navarre (Spain), information on it is currently scarce. Rill and ephemeral gully volumes can be used as a guide to minimum erosion rates. With the main purpose of determining the annual soil loss rates in cultivated areas of central Navarre, a detailed assessment of rainfall and of rill and gully erosion was made in 19 small catchments from October 1999 to September 2001. Seventeen of them were randomly selected, and were cultivated with winter cereals, vineyards or sunflowers. The other two catchments were selected to represent partially uncultivated lands abandoned for ten years. Channel cross‐sections were measured by using a 1‐m‐wide micro‐topographic profile meter, describing 632 cross‐sections and processing information from 31 600 pins. Erosive events happened every year in the three study areas. For cereal catchments, soil losses occurred in only one or two rainfall events each year, usually at the end of autumn and in some summers, with high erosion rates (0·20–11·50 kg m^?2 a^?1). In vineyards, soil losses occurred several times per year, and in any season. This is attributed to the small percentage of surface covered by the crop throughout the year. Again, high erosion rates were found (0·33–16·19 kg m^?2 a^?1), with ephemeral gully erosion causing more loss than rill erosion. No‐till is proposed as an effective conservation measure. From this large data set, it can be stated that rill erosion and ephemeral gully erosion are widespread in Mediterranean regions, and that much more attention should be paid to the problem. Abandoned fields showed very high erosion rates (16·19 kg m^?2 a^?1 on average), suggesting that the abandonment of marginal lands without implementing any erosion control can lead to severe erosion rates. Copyright © 2005 John Wiley & Sons, Ltd.     

Characterization of acid mine drainage sources in the Iberian Pyrite Belt: base methodology for quantifying affected areas and for environmental management

The present work aims to propose a methodology for quantifying the sources of acid mine drainage (AMD) and to characterize the magnitude of the affected areas in the Iberian Pyrite Belt (SW Spain). Such an approach allows the creation of a support tool for managing land and natural resources valorization, which may be easily applied in similar mining regions. The motivation and usefulness of this work can be realized by focusing on two main emerging strategic issues: (1) water resources management, with the example of Alcolea dam that will receive water from affected areas in the Iberian Pyrite Belt; and (2) mineral resources valorization, especially, regarding copper exploration due to increasing market prices. The used methodology included the following general steps: it started with an inventory of the mines in the Iberian Pyrite Belt, followed by field cartography campaigns and finally the quantification of affected areas and contaminant discharges. The results of the present work serve to confirm and quantify the magnitude of the AMD pollution in the Pyrite Belt. A total affected area of about 4,847 ha was estimated. Taking into account this figure and combining it with the annual average precipitation (650 L/m²) results in an estimation of 31,503,680 m³/year of discharging water affected by the presence of sulphides. In this scenario, a total annual contribution of 260,056 tonnes/year was obtained for sulphates, which means more than 712 tonnes a day. In the case of arsenic, a toxic element, the total annual contribution is more than 20 tonnes, or close to 55 kg/day. Regarding copper, this economically interesting metal translates into total contributions of 10,364 tonnes/year in the generating medium. This gave more than 28 tonnes/day, which today sits at 8,200 dollars/tonne. This result suggests that solutions aimed at recovering this resource should be searched. It may represent a financial return at the same time that it would mean overcome environmental liabilities.     

Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments?

Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI₅₅₀) and organic carbon (OC) content and between LOI at 950 °C (LOI₉₅₀) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI₅₅₀ and LOI₉₅₀ show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI₁₀₅) is a good qualitative proxy for the trends in gypsum content.     

The paradigm of Circular Mining in the world: the Iberian Pyrite Belt as a potential scenario of interaction

Water is one of the receptors most affected by the impacts caused, especially in the case of mining sulphides and, to a lesser extent, of coal. Acid Mine Drainage (AMD) is the main problem associated with these mining operations, producing extremely high impacts, and in many cases irreversible impacts, until now. A new concept of mining can make this activity compatible with the environmental preservation and also to the recovery of the environment affected by the old mining operations that today are in the process of reopening. This new concept implicates the paradigm of Circular Mining as a derivative of the concept of Circular Economy, considered as a strategy that aims to reduce both the entry of materials and the production of virgin waste, closing the “loops” or economic and ecological flows of resources. The present work discusses the paradigm of Circular Mining, focused on the Iberian Pyrite Belt, one of the most paradigmatic metallogenetic regions in the world. Based on some examples, expeditious calculations show the possibility of recovering base metals as well as strategic elements from acid mine drainage, thus obtaining important economic assets.     

Long‐term effects of aquifer overdraft and recovery on groundwater quality in a Ramsar wetland: Las Tablas de Daimiel National Park,Spain

Las Tablas de Daimiel National Park is one of Spain's most representative groundwater‐dependent ecosystems. Under natural conditions, water inflows combined brackish surface water from River Gigüela with freshwater inputs from River Guadiana and the underlying aquifer. Since the mid‐1970s, aquifer overexploitation caused the desiccation of the wetlands and neighbouring springs. The National Park remained in precarious hydrological conditions for three decades, with the only exception of rapid floods due to extreme rainfall events and sporadic water transfers from other basins. In the late 2000s, a decrease in groundwater abstraction and an extraordinarily wet period reversed the trend. The aquifer experienced an unexpected recovery of groundwater levels (over 20 m in some areas), thus restoring groundwater discharge to springs and wetlands. The complex historical evolution of the water balance in this site has resulted in substantial changes in surface and groundwater quality. This becomes evident when comparing the pre‐1980 groundwater quality and the hydrochemical status in the wetland in two different periods, under “dry” and “wet” conditions. Although the system is close to full recovery from the groundwater‐level viewpoint, bouncing back in the major hydrochemical constituents has not yet been obtained. These still appear to evolve in response to the previous overexploitation state. Moreover, in some sectors, there are groundwater‐dependent ecosystems that remain different to those found in preoverexploitation times. The experience of Las Tablas de Damiel provides an observatory of long‐term changes in wetland water quality, demonstrating that the effects of aquifer overexploitation on aquatic ecosystems are more than a mere alteration of the water balance and that groundwater quality is the key to aquifer and aquatic ecosystem sustainability.     

Spatial evolution of an AMD stream in the Iberian Pyrite Belt: process characterization and control factors on the hydrochemistry

ABSTRACT

This paper presents hydrochemical data of an AMD stream, Poderosa Creek, in the Iberian Pyrite Belt, obtained between its source, in the Poderosa Mine portal, and its confluence with the Odiel River. The main objective is to establish potential interdependent relationships between sulphate and metal loads and the following physico-chemical variables: pH, electrical conductivity (EC), redox potential (EH) and dissolved oxygen (DO). All the parameters show an overall increasing tendency from the tunnel exit to the confluence at the Odiel River. The TDS and EC are two relevant exceptions. They behave similarly, showing a decreasing trend and a strong inflection that describes a minimum immediately after the discharging point. Spatial analysis combined with statistical tools reveal typical AMD processes and the respective physico-chemical implications. Inputs with distinctive hydrochemical signatures impose relevant modifications in the Poderosa Creek waters. This indicates low hydrochemical inertia and high vulnerability to external stimuli.

Editor D. Koutsoyiannis; Associate editor not assigned     

Assessment of prospective geological hazards in Torrevieja-La Mata coast (western Mediterranean) based on Pleistocene and Holocene events

Natural Hazards - The coastal zone in which the lagoons of La Mata and Torrevieja (Eastern Spain) developed can be described as a compilation of geo-hazards typical of the Mediterranean realm. This...