Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

Tectonic relation between northeastern China and the Korean peninsula revealed by interpretation of GRACE satellite gravity data

The major continental blocks in northeastern Asia are the North China block and the South China block, which have collided starting from the Korean peninsula. Geologic and geophysical interpretations reveal a well defined suture zone in northeastern China from Qinling through Dabie to Jiaodong. The discovery of high-pressure metamorphic rocks in the Hongseong area of the Korean peninsula, prominent evidence for the collision zone, indicates extension of the collision zone in northeastern China into the Korean peninsula. Interpretation of the GRACE satellite gravity dataset shows two prominent structural boundaries in the Yellow Sea. One extends from the Jiaodong Belt in eastern China to the Imjingang Belt in the Korean peninsula. The other extends from near Nanjing, eastern China, to Hongseong. Tectonic movement in or near the suture zone may be responsible for seismic activity in the western Korean peninsula and the development of the Yellow Sea sedimentary basin.     

Development of statistical seasonal prediction models of Arctic Sea Ice concentration using CERES absorbed solar radiation

Statistical seasonal prediction models for the Arctic sea ice concentration (SIC) were developed for the late summer (August-October) when the downward trend is dramatic. The absorbed solar radiation (ASR) at the top of the atmosphere in June has a significant seasonal leading role on the SIC. Based on the lagged ASR-SIC relationship, two simple statistical models were established: the Markovian stochastic and the linear regression models. Crossvalidated hindcasts of SIC from 1979 to 2014 by the two models were compared with each other and observation. The hindcasts showed general agreement between the models as they share a common predictor, ASR in June and the observed SIC was well reproduced, especially over the relatively thin-ice regions (of one- or multi-year sea ice). The robust predictability confirms the functional role of ASR in the prediction of SIC. In particular, the SIC prediction in October was quite promising probably due to the pronounced icealbedo feedback. The temporal correlation coefficients between the predicted SIC and the observed SIC were 0.79 and 0.82 by the Markovian and regression models, respectively. Small differences were observed between the two models; the regression model performed slightly better in August and September in terms of temporal correlation coefficients. Meanwhile, the prediction skills of the Markovian model in October were higher in the north of Chukchi, the East Siberian, and the Laptev Seas. A strong non-linear relationship between ASR in June and SIC in October in these areas would have increased the predictability of the Markovian model.     

Regional Distribution of Perceived Temperatures Estimated by the Human Heat Budget Model （the Klima-Michel Model） in South Korea

The regional distribution of perceived temperatures (PT) for 28 major weather stations in South Korea during the past 22 years (1983–2004) was investigated by employing a human heat budget model, the Klima-Michel model. The frequencies of a cold stress and a heat load by each region were compared. The sensitivity of PT in terms of the input of synoptic meteorological variables were successfully tested. Seogwipo in Jeju Island appears to be the most comfortable city in Korea. Busan also shows a high frequenc...     

Field Evaluation of the Vertical Bearing Capacity of a Screw Pretensioned Spun High-Strength Concrete Pile

This study has evaluated the vertical bearing capacity by conducting static load tests for noise-free and vibration-free screw pretensioned spun high-strength concrete (PHC) piles installed using two different methods (end-squirting shoe and pre-boring methods). Vertical bearing capacity differences seem to occur due to the displacement of soils near the external circumference of a pile, depending on the installation method. A method by which to evaluate the bearing capacity of screw concrete piles is suggested by considering the equations that already have been used to calculate the bearing capacity of piles. Based on static load tests and analysis, the pile installed using the end-squirting shoe method was assumed to be a bored pile and it was reasonable to use the equation proposed by the Japanese Geotechnical Society. At the same time, the pile installed using the pre-boring method was deemed a low soil displacement pile and so it was reasonable to apply the equations proposed for calculating the bearing capacity of the driven pile suggested by the Architectural Institute of Japan.     

Effects of particle shape on the cushioning mechanics of rock-filled gabions

Acta Geotechnica - Rock-filled gabions are commonly installed in front of reinforced concrete structures to reduce concentrated impact loads induced by rock fall and boulders entrained in debris...     

Quantitative Analysis of Micro-structural Changes in a Bituminous Coal After Exposure to Supercritical CO2 and Water

Natural Resources Research - High-volatile bituminous coal samples were reacted in deionized water with supercritical CO2 (ScCO2–water) under simulated in situ pressure and temperature...     

Comparison of radiocarbon and OSL dating methods for a Late Quaternary sediment core from Lake Ulaan,Mongolia

Both radiocarbon and optically stimulated luminescence (OSL) dating methods were applied to test their suitability for establishing a chronology of arid-zone lacustrine sediments using a 5.88-m-long core drilled from Lake Ulaan, southern Mongolia. Although the radiocarbon and OSL ages agree in some samples, the radiocarbon ages are older than the corresponding OSL ages at the 550-cm depth horizon (late Pleistocene) and in the 100–300-cm interval (early to late Holocene). In the early to late Holocene, radiocarbon ages are consistently older than OSL ages by 4,100–5,800 years, and in the late Pleistocene by 2,700–3,000 years. Grain-size analysis of early to late Holocene sediments and one late Pleistocene sediment sample (550-cm depth) indicates that eolian processes were the dominant sediment-transport mechanism. Also, two late Pleistocene sediments samples (from 400- to 500-cm depths) are interpreted to have been deposited by both eolian and glaciofluvial processes. Accordingly, the radiocarbon ages that were older than the corresponding OSL ages during the Holocene seem to have been a consequence of the influx of ¹⁴C-deficient carbon delivered from adjacent soils and Paleozoic carbonate rocks by the westerly winds, a process that is also active today. In addition to the input of old reworked carbon by eolian processes, the late Pleistocene sediments were also influenced by old carbon delivered by deglacial meltwater. The results of this study suggest that when eolian sediment transport is suspected, especially in lakes of arid environments, the OSL dating method is superior to the radiocarbon dating method, as it eliminates a common ‘old-carbon’ error problem.