Suitability assessment of deep groundwater for drinking and irrigation use in the Djeffara aquifers (Northern Gabes,south-eastern Tunisia)

The multilayered Djeffara aquifer system, south-eastern Tunisia, has been intensively used as a primary source to meet the growing needs of the various sectors (drinking, agricultural and industrial purposes). The analysis of groundwater chemical characteristics provides much important information useful in water resources management. Detailed knowledge of the geochemical evolution of groundwater and assessing the water quality status for special use are the main objective of any water monitoring study. An attempt has been made for the first time in this region to characterize aquifer behavior and appreciate the quality and/or the suitability of groundwater for drinking and irrigation purposes. In order to attend this objective, a total of 54 groundwater samples were collected and analyzed during January 2008 for the major cations (sodium, calcium, magnesium and potassium), anions (chloride, sulfate, bicarbonate), trace elements (boron, strontium and fluoride), and physicochemical parameters (temperature, pH, total dissolved salts and electrical conductivity). The evolution of chemical composition of groundwater from recharge areas to discharge areas is characterized by increasing sodium, chloride and sulfate contents as a result of leaching of evaporite rock. In this study, three distinct chemical trends in groundwater were identified. The major reactions responsible for the chemical evolution of groundwater in the investigated area fall into three categories: (1) calcite precipitation, (2) gypsum and halite dissolution, and (3) ion exchange. Based on the physicochemical analyses, irrigation quality parameters such as sodium absorption ratio (SAR), percentage of sodium, residual sodium carbonate, residual sodium bicarbonate, and permeability index (PI) were calculated. In addition, groundwater quality maps were elabortaed using the geographic information system to delineate spatial variation in physico-chemical characteristics of the groundwater samples. The integration of various dataset indicates that the groundwater of the Djeffara aquifers of the northern Gabes is generally very hard, brackish and high to very high saline and alkaline in nature. The water suitability for drinking and irrigation purposes was evaluated by comparing the values of different water quality parameters with World Health Organization (WHO) guideline values for drinking water. Piper trilinear diagram was constructed to identify groundwater groups where the relative major anionic and cationic concentrations are expressed in percentage of the milliequivalent per liter (meq/l), and it was demonstrated that the majority of the samples belongs to SO₄–Cl–Ca–Na, Cl–SO₄–Na–Ca and Na–Cl hydrochemical facies. As a whole, all the analyzed waters from this groundwater have revealed that this water is unsuitable for drinking purposes when comparing to the drinking water standards. Salinity, high electric conductivity, sodium adsorption ratio and sodium percentages indicate that most of the groundwater samples are inappropriate for irrigation. The SAR vary from medium (S2) to very high (S4) sodicity. Therefore, the water of the Djeffara aquifers of the northern Gabes is dominantly of the C4–S2 class representing 61.23 % of the total wells followed by C4–S3 and C4–S4 classes at 27.27 and 11.5 % of the wells, respectively. Based on the US Salinity Classification, most of the groundwater is unsuitable for irrigation due to its high salt content, unless certain measures for salinity control are undertaken.     

The construction of a third-order secular analytical J-S-U-N theory by the Hori-Lie technique

We expand both parts, the principal and indirect, of the Hamiltonian function up to the third order in the masses for the four major planets Jupiter-Saturn-Uranus-Neptune. Accordingly we write down the secular terms ofF ₁,F ₂,F ₃ and the critical terms ofF ₁,F ₂ in terms of the canonical variables of H. Poincaré neglecting powers higher than the second inH, K, P, Q.     

Sensitivity analysis in groundwater vulnerability assessment based on GIS in the Mahdia-Ksour Essaf aquifer,Tunisia: a validation study

Abstract

The assessment of groundwater vulnerability to pollution has proved to be an effective tool for water resource management, especially in arid and semi-arid regions like Mahdia and Ksour Essaf. The main objective of this study is to assess the aquifer vulnerability by applying the DRASTIC method as well as using sensitivity analysis to evaluate the effect of each DRASTIC parameter on the final vulnerability map. An additional objective is to demonstrate the role of the GIS techniques in the vulnerability assessment. The DRASTIC method assigns a high vulnerability to the coast of the Mahdia-Ksour Essaf. The lowest values are observed in the southern part of the study area. A sensitivity analysis applied in this study suggests that net recharge, aquifer media and depth of groundwater are the key factors determining vulnerability. The model is validated with groundwater quality data and the results have shown strong relationships between modified DRASTIC Vulnerability Index and nitrate and chloride concentrations.

Citation Saidi, S., Bouri, S. & Ben Dhia, H. (2011) Sensitivity analysis in groundwater vulnerability assessment based on GIS in the Mahdia-Ksour Essaf aquifer, Tunisia: a validation study. Hydrol. Sci. J. 56(2), 288–304.     

Assessing groundwater vulnerability to nitrate pollution using statistical approaches: a case study of Sidi Bouzid shallow aquifer,Central Tunisia

The study region comprises the Sidi Bouzid shallow aquifer, which is located in the western part of Central Tunisia. It is mainly occupied by agricultural land with intensive use of chemical fertilizers especially nitrates. For this reason, nitrate measurement was performed in 38 water samples to evaluate and calibrate the obtained models. Several environmental parameters were analyzed using groundwater nitrate concentrations, and different statistical approaches were applied to assess and validate the groundwater vulnerability to nitrate pollution in the Sidi Bouzid shallow aquifer. Multiple linear regression (MLR), analyses of covariance (ANCOVA), and logistic regression (LR) were carried out for studying the nitrate effects on groundwater pollution. Statistical analyses were used to identify major environmental factors that control the groundwater nitrate concentration in this region. Correlation and statistical analyses were conducted to examine the relationship between the nitrate (dependent variable) and various environmental variables (independent variables). All methods show that “groundwater depth” and “land use” parameters are statistically significant at 95% level of confidence. Groundwater vulnerability map was obtained by overlaying these two thematic layers which were obtained in the GIS environment. It shows that the high vulnerability area coincides with the likelihood that nitrate concentration exceeds 24.5 mg/l in groundwater. The relationship between the groundwater vulnerability classes and the nitrate concentrations provides satisfactory results; it showed an Eta-squared correlation coefficient of 64%. So, the groundwater vulnerability map can be used as a synthetic document for realistic management of groundwater quality.     

The construction of a third order secular

In this part we find out the 24 equations of secular perturbation equations for the subsystem J-S-U-N. The solution of these equations by the Lagrange-Laplace procedure and the Eigen value Eigen vector is analysed. Also we refer to Hurwitz theorem to test stability.     

Groundwater vulnerability and risk mapping of the Hajeb-jelma aquifer (Central Tunisia) using a GIS-based DRASTIC model

The aim of this study is to elaborate a synthetic document for the assessment of groundwater vulnerability to pollution in the Hajeb-Jelma aquifer. The specific object is to incorporate the Geographical Information System (GIS) to generate groundwater vulnerability and risk maps with DRASTIC model. Indeed, GIS could help to make the results of a complicated model more clear through visual representation, providing an applicable tool for decision makers. The vulnerability map of Hajeb-Jelma watershed shows three classes: moderate, high and very high depending on the intrinsic properties. The risk map shows a very high risk dependant on hydrogeological characteristics, land use and human impacts in major part of the Hajeb-Jelma region. These maps could serve as a scientific basis for sustainable land use planning and groundwater management in the Hajeb-Jelma region.     

Geochemical and isotopic evolution of groundwater in the Wadi Watir watershed,Sinai Peninsula,Egypt

The Wadi Watir delta in the Wadi Watir watershed is a tourist area in the arid southeastern part of the Sinai Peninsula, Egypt, where development and growth of the community on the delta are constrained by the amount of groundwater that can be withdrawn sustainably. To effectively manage groundwater resources in the Wadi Watir delta, the origin of groundwater recharge, groundwater age, and changes in groundwater chemistry in the watershed needs to be understood. Mineral identification, rock chemistry, water chemistry, and the isotopes of hydrogen, oxygen, and carbon in groundwater were used to identify the sources, mixing, and ages of groundwater in the watershed and the chemical evolution of groundwater as it flows from the upland areas in the watershed to the developed areas at the Wadi Watir delta. Groundwater in the Wadi Watir watershed is primarily from recent recharge while groundwater salinity is controlled by mixing of chemically different waters and dissolution of minerals and salts in the aquifers. The El Shiekh Attia and Wadi El Ain areas in the upper Wadi Watir watershed have different recharge sources, either from recharge from other areas or from different storm events. The downgradient Main Channel area receives groundwater flow primarily from the El Shiekh Attia area. Groundwater in the Main Channel area is the primary source of groundwater supplying the aquifers of the Wadi Watir delta.     

Geology and geochemistry of Kurkur bentonites,southern Egypt: provenance,depositional environment,and compositional implication of Paleocene–Eocene thermal maximum

A large lower Eocene bentonite deposit at the top of Sinn El-Kaddab plateau, southern Egypt, is investigated. It forms isolated anticlinal hills as mesa and cuesta geomorphic units. The Sinn El-Kaddab plateau (497 m above sea level) with Gebel Abyad in northern Sudan represent the most southern margin of Tethys realm in East Africa. Clay and silt fractions constitute up to 95 % of the bentonite and calcium montmorillonite is the predominant phase (70–87 %). These sediments were deposited during the Paleocene–Eocene Thermal Maximum (PETM) event. Grain-size distribution in conjunction with their geologic setting argues in favor of a low energy deep hemipelagic, restricted basin within the outer shelf zone. They suggest sporadic deposition in a basin characterized by relief oscillation, in response to continuous tectonic uplifting. The sediments of the peripheral parts of the basin are more calcareous and were deposited in an arid climatic condition. Calcium montmorillonite was deposited in subtropical warm climate, with alternating wet and dry seasons. Compositionally, the bentonite shales are basic to intermediate and exhibit a rather limited range of K₂O/Na₂O and SiO₂/Al₂O₃ ratios. They suggest mature polycyclic siliciclastics as the main provenance and within-plate alkali basalts as a main igneous precursor. They are the product of intensive physical weathering process in response to combined effects of both tectonic disturbance and prevailed climatic conditions during the PETM event. Geochemically, they are interpreted in terms of mixing of two end-members: pure clastic terrigenous component (inherited from the source area) and carbonate-rich matrix.     

Groundwater resource sustainability in the Wadi Watir delta, Gulf of Aqaba, Sinai, Egypt

The Wadi Watir delta, in the arid Sinai Peninsula, Egypt, contains an alluvial aquifer underlain by impermeable Precambrian basement rock. The scarcity of rainfall during the last decade, combined with high pumping rates, resulted in degradation of water quality in the main supply wells along the mountain front, which has resulted in reduced groundwater pumping. Additionally, seawater intrusion along the coast has increased salinity in some wells. A three-dimensional (3D) groundwater flow model (MODFLOW) was calibrated using groundwater-level changes and pumping rates from 1982 to 2009; the groundwater recharge rate was estimated to be 1.58?×?10⁶ m³/year. A variable-density flow model (SEAWAT) was used to evaluate seawater intrusion for different pumping rates and well-field locations. Water chemistry and stable isotope data were used to calculate seawater mixing with groundwater along the coast. Geochemical modeling (NETPATH) determined the sources and mixing of different groundwaters from the mountainous recharge areas and within the delta aquifers; results showed that the groundwater salinity is controlled by dissolution of minerals and salts in the aquifers along flow paths and mixing of chemically different waters, including upwelling of saline groundwater and seawater intrusion. Future groundwater pumping must be closely monitored to limit these effects.