Present environment and historic changes from the record of lake sediments, Dhaka City, Bangladesh

Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe₂O₃ and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe₂O₃ and Pb–Fe₂O₃ relations. Zn–Fe₂O₃ ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe₂O₃ ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe₂O₃ trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages.     

Geochemical study of arsenic and other trace elements in groundwater and sediments of the Old Brahmaputra River Plain,Bangladesh

The geochemical study of groundwaters and core sediments from the Old Brahmaputra plain of Bangladesh was conducted to investigate the distribution of arsenic and related trace elements. Groundwaters from tube wells are characterized by pH of 6.4–7.4, dissolved oxygen (DO) of 0.8–1.8 mg/l, Ca contents of 5–50 mg/l, and Fe contents of 0.2–12.9 mg/l. Arsenic concentrations ranged from 8 to 251 μg/l, with an average value of 63 μg/l. A strong positive correlation exists between As and Fe (r ² = 0.802; p = 0.001) concentrations in groundwater. The stratigraphic sequences in the cores consist of yellowish silty clays at top, passing downward into grayish to yellowish clays and sands. The uppermost 3 m and lower parts (from 13 to 31 m) of the core sediments are oxidized (average oxidation reduction potential (ORP) +170 and +220 mV, respectively), and the ORP values gradually become negative from 3 to 13 m depths (−35 to −180 mV), indicating that anoxic conditions prevail in the shallow aquifers of the Brahmaputra plain. Age determinations suggest that clay horizons at ~10 m depth were deposited at around 2,000 and 5,000 years BP (¹⁴C ages) during the transgressive phase of sea-level change. Elevated concentrations of As, Pb, Zn, Cu, Ni, Cr, and V are present in the silts and clays, probably due to adsorption onto clay particles. Significant concentrations of As occur in black peat and peaty sediments at depths between 9 and 13 m. A strong positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed onto Fe oxides in aquifer sediments.     

A comparative analysis of pre- and post-industrial spatiotemporal drought trends and patterns of Tibet Plateau using Sen slope estimator and steady-state probabilities of Markov Chain

Natural Hazards - The increase of frequency and severity of extreme weather events due to climate change gives evidence of severe challenges faced by infrastructure systems. Among them, the...     

Non-vacuum static cylindrically symmetric solution and energy distribution in f(R) gravity

In this paper, we investigate static cylindrically symmetric solution in metric f(R) gravity by taking matter in the form of dust. The assumption of constant Ricci scalar curvature is taken to find the solution. The energy distribution of this solution is explored by applying Landau-Lifshitz energy-momentum complex. In addition, we explore the stability as well as constant scalar curvature conditions for some viable f(R) models along with their energy distribution. It is interesting to mention here that these models satisfy the above mentioned conditions.     

Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

Present environment of Dam Lake Sambe,southwestern Japan: a geochemical study of bottom sediments

Geochemical analyses of lakebed and core sediments from Lake Sambe on the outskirts of Oda City in Shimane prefecture in southwestern Japan were carried out in order to assess the water quality and the concentration and distribution patterns of sixteen elements. The lake water showed a stratified condition with respect to dissolved O₂, and As, Fe, and Mn concentrations in the bottom layers which increased in the summer. The chemical composition of the sediments, as measured by X-ray fluorescence, included major and trace elements (P, Ca, Sc, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Sr, Zr, Pb, and Th), and total sulfur (TS). Elevated values of As, Zn, V, Fe, P, and TS were present in several layers of the upper cores (from 0 to 5 cm) and other surface sediments. Increases in the abundances of these metals in lake sediments are probably related to the reducing condition of the sediments, fine-grained organic rich sediments, and post-depositional diagenetic remobilization. Moreover, correlations between the concentrations of trace metals and iron in the sediments suggest their adsorption onto Fe (oxy)hydroxides, whereas correlations with sulfur indicate that they were precipitated as Fe-sulfides. The average abundances of As, Pb, Zn, and Cu exceeded the lowest effect level and Interim Sediment Quality Guideline values that the New York State Department of Environmental Conservation and the Canadian Council of Ministers of the Environment determined to have moderate impact on aquatic organisms. In addition, concentrations of As and Zn exceeded the Coastal Ocean Sediment Database threshold value, indicating potentially toxic levels. Therefore, the presence of trace metals in the lake sediments may result in adverse effects on biota health.     

Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh

Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments.     

Regional-scale airborne electromagnetic surveying of the Yucatan karst aquifer (Mexico): geological and hydrogeological interpretation

Geometry and connectivity of high-permeability zones determine groundwater flow in karst aquifers. Efficient management of karst aquifers requires regional mapping of preferential flow paths. Remote-sensing technology provides tools to efficiently map the subsurface at such scales. Multi-spectral remote sensing imagery, shuttle radar topography data and frequency-domain airborne electromagnetic (AEM) survey data were used to map karst-aquifer structure on the Yucatan Peninsula, Mexico. Anomalous AEM responses correlated with topographic features and anomalous spectral reflectance of the terrain. One known preferential flow path, the Holbox fracture zone, showed lower bulk electrical resistivity than its surroundings in the AEM surveys. Anomalous structures delineated inland were sealed above by a low-resistivity layer (resistivity: 1–5 Ωm, thickness: 5–6?m). This layer was interpreted as ejecta from the Chicxulub impact (Cretaceous/Paleogene boundary), based on similar resistivity signatures found in borehole logs. Due to limited sensitivity of the AEM survey, the subsurface configuration beneath the low-resistivity layer could not be unambiguously determined. AEM measurements combined with remote-sensing data analysis provide a potentially powerful multi-scale methodology for structural mapping in karst aquifers on the Yucatan Peninsula and beyond.     

Modelling the vulnerability of groundwater to contamination in an unconfined alluvial aquifer in Pakistan

The area of Thal Doab is located in the Indus Basin and is underlain by a thick alluvial aquifer called the Thal Doab aquifer (TDA). The TDA is undergone intense hydrological stress owing to rapid population growth and excessive groundwater use for livestock and irrigated agricultural land uses. The potential impact of these land uses on groundwater quality was assessed using a DRASTIC model in a Geographic Information System environment. Seven DRASTIC thematic maps were developed at fixed scale and then combined into a groundwater vulnerability map. The resultant vulnerability index values were grouped into four zones as low, moderate, high and very high. The study has established that 76% of the land area that is underlain by the TDA has a high to very high vulnerability to groundwater contamination mainly because of a thin soil profile, a shallow water table and the presence of soils and sediments with high hydraulic conductivity values. In addition, only 2 and 22% of the total area lie in low and moderate vulnerability zones, respectively. The outcomes of this study can be used to improve the sustainability of the groundwater resource through proper land-use management.