Geochemical Evidence for Subduction Fluxes, Mantle Melting and Fractional Crystallization Beneath the South Sandwich Island Arc

The volcanoes of the South Sandwich island arc follow threedistinct series: low-K tholeiitic (followed by Zavodovski, Candlemas,Vindication, Montagu and Bristol), tholeiitic (followed by Visokoi,Saunders and Bellinghausen) and calcalkaline (followed by Leskov,Freehand and part of Cook and Thule). Flux calculations indicatethat the percentage contribution of the subduction componentto the mantle source of all three series varies from undetectable(e.g. Zr) through small (e.g. Nd=20%) and moderate (e.g. La,Ce, Sr=50–80%) to dominant (e.g. Pb, K, Ba, Rb, Cs >90%)with little change along the arc. Isotope systematics (Pb, Nd,Sr) show that this subduction component obtains a greater contributionfrom altered oceanic crust than from pelagic sediment. Elementsfor which the subduction contribution is small show that themantle is already depleted relative to N-MORB mantle (equivalentto loss of an 2•5% melt fraction) before melting beneaththe arc. After addition of the subduction component, dynamicmelting of this depleted mantle then causes the variations inK that distinguish the three series. The estimated degree ofpartial melting (20%) is slightly greater than that beneathocean ridges, though geothermometry suggests that the primarymagma temperature (1225C) is similar to that of primary MORB.About half of the melting may be attributed to volatile addition,and half to decompression. Dynamic melting involving three-dimensional,two-phase flow may be needed to explain fully the inter-islandvariations. KEY WORDS: geochemistry; petrology; fluxes; melting; subduction ^*Corresponding author     

Stable Isotopic Evidence for Fluid-Rock Interactions in the Ivrea Zone, Italy

Stable isotope compositions of Ivrea Zone marbles and associatedlithologies are in general heterogeneous. The oxygen isotopecomposition of quartz in pelites ranges from ¹⁸O +9 to + 17(SMOW) and does not vary systematically with metamorphic grade.Peridotites retain oxygen isotope signatures close to mantlevalues. Marble calcites vary in isotopic composition from ¹³C + 2(PDB),¹⁸0 +24(SMOW)to ¹³C –6(PDB), ¹⁸O + 13 (SMOW).Depletions in ¹⁸O and ¹³C may be explained dominantly by interactionwith fluids derived from within the observed metasedimentarysequence during prograde metamorphism. ¹⁸O and ¹³C show gradients of greater than 5/m across marblemargins and within marbles. The preservation of such isotopicgradients is not consistent with the long-term presence of grain-boundary-scaleinterconnected fluid films in and around marbles. There is ageneral lowering of ¹⁸O within individual marble bodies althoughlarge carbon and oxygen isotopic gradients are present. Calcitein marbles may attain oxygen isotope equilibrium, but rarelycarbon isotope equilibrium, with surrounding metapelites. Infiltrationof marbles must involve a component of channelized fluid flow. The general lack of isotopic equilibration within the sequencerequires channelized fluid flow and limited fluid-rock ratios.Large pervasive mantle to crust fluid fluxes are not consistentwith the observations. ^*Present address: Natural Environment Research Council, Polaris House, North Star Avenue, Swindon SN2 1EU, England     

Public Perceptions of Natural Character in New Zealand: Wild Nature Versus Cultured Nature

Results of empirical research undertaken in New Zealand to determine public perceptions of natural character in the biophysical environment are presented and related to recent theoretical literature. The research comprised two distinct case studies using Q method and photographs, in which participants evaluated natural character in terms of their own landscape experiences by ranking the photographs in order of preference. The results confirm prevailing responses to nature recently specified in North American literature, and have some policy implications for environmental management in New Zealand.     

Stream-driven, high-density gravelly traction carpets: possible deposits in the Trabeg Conglomerate Formation, SW Ireland and some theoretical considerations of their origin

Within high-density flood flows a prominent mechanism of gravel transport and deposition is by stream-driven, high-density traction carpet (with a rheology similar to grain flow). These gravel carpets are envisaged to form the basal portion of a bipartite high-density flood flow, decoupled from an overlying sand- and silt-laden turbulent flow. Several examples already documented in the literature are reviewed and an additional case from the Lower Old Red Sandstone of southwest Ireland is presented. Two mechanisms of traction carpet initiation are discussed: by rapid entrainment of gravel into suspension on rising stage, followed by settling into the gravel traction carpet at peak and falling stage; and by overconcentration of a ‘normal’, low-density bedload. Gravel entrainment, suspension and traction carpet development are significantly easier if the flood water already carries a high concentration of sand and silt in suspension. Theoretical consideration further shows that gravelly traction carpets can be maintained in channels of relatively low gradient by the shear stress exerted by the high-density, sand-bearing turbulent flood flow above. This tangential shear stress is converted to dispersive pressure, which aids buoyancy and quasi-static grain-to-grain contacts in the support of the clasts within the gravel carpet. The carpet is thought to have a quasi-plastic rheology but behave much like a viscous fluid at high shear rates. Stream-driven gravelly traction carpets are expected to produce sheet-like units of clast- to matrix-supported conglomerate, characterized by a parallel or an a(p)a(i) clast fabric. These units may be ungraded, normally or inversely graded, depending on the rate of shear, the viscosity of the flow and the celerity of deposition.     

Garnet-Orthopyroxene Bearing Granulites from Enderby Land, Antarctica: Metamorphic Pressure Temperature-Time Evolution of the Archaean Napier Complex

Garnet-orthopyroxene bearing granulite assemblages from theArchaean Napier Complex, Enderby Land, Antarctica, display avariety of exsolution, recrystallization and corona textureswhich result both from near-isobaric cooling from the peak ofmetamorphism and from later overprinting. Compositional dataon distinct generations of phases and on zoning patterns incoexisting minerals, have been used to estimate (a) peak metamorphicconditions attained between the first and second major deformationphases (Dl and D2); (b) cooling paths from this peak, and (c)ambient metamorphic conditions at the time of a later deformation(D3). Experimentally calibrated geothermobarometers indicateinitial metamorphism at 900–950?C and 7–10 kb duringand subsequent to Dl and D2, at 3100–3000 Ma. The presentlyexposed granulites indicate a regional increase in the pressuresof this metamorphism south-west to the Scott Mountains-CaseyBay region, where minimum crustal thicknesses of 10 kb wereattained at c. 3000 Ma. Subsequently, the Napier Complex granulitesevolved through a prolonged period of near-isobaric coolingprior to further metamorphism at 600–750 and 4–8kb during D3 at c. 2500 Ma. The near-isobaric pressure-temperature-timepath (P-T-t) suggests that the Napier Complex acted as an essentiallystable craton as early as 3000 Ma, and that the major magmaticand tectonic crustal thickening events associated with Dl precededthe thermal peak represented by the earliest recognized metamorphism.     

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.