High-pressure metallization and electronic-magnetic propertiesof hexagonal cubanite (CuFe2S3)

^?57Fe Mössbauer studies at room temperature and temperature-dependent resistance studies have been performed on a natural specimen of cubanite (CuFe₂S₃) in a diamond-anvil cell at pressures up to ～10 GPa. An insulator-metal phase transition occurs in the range 3.4–5.8 GPa coinciding with a previously observed structural transition from an orthorhombic to a hexagonal NiAs (B8) structure. The room temperature data shows that the metallization process concurs with a gradual transition from a magnetically ordered phase at low pressure to a nonmagnetic or paramagnetic phase at high-pressure. The change in magnetic behaviour at the structural transition may be attributed to a reduction of the Fe-S-Fe superexchange angle formed by edge-sharing octahedra occurring in the high-pressure phase. The non-magnetic or paramagnetic metallic phase at high pressure is retained upon decompression to ambient pressure-temperature conditions, indicative of substantial hysteresis associated with the pressure driven orthorhombic→hexagonal structural transition. The pressure evolution of both the ⁵⁷Fe Mössbauer hyperfine interaction parameters and resistance behaviour is consistent with the transition from mixed-valence character in the low pressure orthorhombic structure to that of extended-electron delocalization in the hexagonal phase at high-pressure.     

Funding low-carbon investments in the absence of a carbon tax

Introducing a carbon tax is difficult, partly because it suggests that current generations have to make sacrifices for the benefit of future generations. However, the climate change externality could be corrected without such a sacrifice. It is possible to set a carbon value, and use it to create ‘carbon certificates’ that can be accepted as part of commercial banks’ legal reserves. These certificates can be distributed to low-carbon projects, and be exchanged by investors against concessional loans, reducing capital costs for low-carbon projects. As the issuance of carbon certificates would increase the quantity of money, it will either lead to accelerated inflation or induce the Central Bank to raise interest rates. Low-carbon projects will thus have access to cheaper loans at the expense of either ‘regular’ investors (in case of higher interest rates) or of lenders and depositors (in case of accelerated inflation). Within this scheme, mitigation expenditures are compensated by a reduction in regular investments, so that immediate consumption is maintained. It uses future generation wealth to pay for a hedge against climate change. This framework is not as efficient as a carbon tax but is politically easier to implement and represents an interesting step in the trajectory towards a low-carbon economy.     

Geographical factors of the abundance of flora in Russian cities

Doklady Earth Sciences - An analysis of data on the species abundance of flora in 89 cities (urban flora) of the Russian Federation facilitated determination of its main factors. It has been...     

Building SSPs for climate policy analysis: a scenario elicitation methodology to map the space of possible future challenges to mitigation and adaptation

The scientific community is now developing a new set of scenarios, referred to as Shared Socio-economic Pathways (SSPs) that will be contrasted along two axes: challenges to mitigation, and challenges to adaptation. This paper proposes a methodology to develop SSPs with a “backwards” approach based on (i) an a priori identification of potential drivers of mitigation and adaptation challenges; (ii) a modelling exercise to transform these drivers into a large set of scenarios; (iii) an a posteriori selection of a few SSPs among these scenarios using statistical cluster-finding algorithms. This backwards approach could help inform the development of SSPs to ensure the storylines focus on the driving forces most relevant to distinguishing between the SSPs. In this illustrative analysis, we find that energy sobriety, equity and convergence prove most important towards explaining future difference in challenges to adaptation and mitigation. The results also demonstrate the difficulty in finding explanatory drivers for a middle scenario (SSP2). We argue that methodologies such as that used here are useful for broad questions such as the definition of SSPs, and could also be applied to any specific decisions faced by decision-makers in the field of climate change.