Quantitative Evaluation of Water Deposited By Dew on Monuments

Samples of White and Green Carrara marble, and three types oflimestone and brick exposed in the field vertically and horizontally were used to evaluate condensationon monuments during clear sky nights. Experiments in a simulation chamber under controlledconditions led to a general equation for the actual amount of water deposited on a surface by dew.This is determined by: How much and for how long the surface temperature falls below the dew point,the moisture content in the air and the ventilation. On clear nights, the condensation on buildingstructures facing the sky may reach some 0.2 kg m^-2 (or 0.2 mm), whereas condensation on verticalsurfaces is very small. Computation of the seasonal trend of night-time condensationshowed that the maximum amount of water condensed per night occurs in the autumn, with the moreabundant concentration of moisture in the air. The total amount of water condensed per month isfound to be a maximum in the summer-autumn period. Morning condensationfor the thermal inertia of monuments is also relevant, and has been calculated to reach the same order of magnitude as thenocturnal dew. A detailed analysis of the temperature and mixing ratio profiles near a condensingsurface has shown two different situations. In still air, the two profiles follow an exponentiallaw and the thermal and the concentration layers lie within a few tens of millimetres. Inthe presence of turbulence, the thickness of these two layers is dramatically reduced. In still air, infront of a vertical, chilly surface, the deposition rate of air pollutants by thermophoresis and/orStefan flow is increased by 3 or 4 times in comparison with a horizontal surface. In the presence ofturbulence, the thickness of the thermal and concentration layers was dramatically reduced, makingthese two kinds of deposition much faster.     

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.     

Hyperspectral mapping of alteration assemblages within a hydrothermal vug at the Haughton impact structure,Canada

Meteorite impacts on Earth and Mars can generate hydrothermal systems that alter the primary mineralogies of rocks and provide suitable environments for microbial colonization. We investigate a calcite–marcasite‐bearing vug at the ~23 km diameter Haughton impact structure, Devon Island, Nunavut, Canada, using imaging spectroscopy of the outcrop in the field (0.65–1.1 μm) and samples in the laboratory (0.4–2.5 μm), point spectroscopy (0.35–2.5 μm), major element chemistry, and X‐ray diffraction analyses. The mineral assemblages mapped at the outcrop include marcasite; marcasite with minor gypsum and jarosite; fibroferrite and copiapite with minor gypsum and melanterite; gypsum, Fe³⁺ oxides, and jarosite; and calcite, gypsum, clay, microcline, and quartz. Hyperspectral mapping of alteration phases shows spatial patterns that illuminate changes in alteration conditions and formation of specific mineral phases. Marcasite formed from the postimpact hydrothermal system under reducing conditions, while subsequent weathering oxidized the marcasite at low temperatures and water/rock ratios. The acidic fluids resulting from the oxidation collected on flat‐lying portions of the outcrop, precipitating fibroferrite + copiapite. That assemblage then likely dissolved, and the changing chemistry and pH resulting from interaction with the calcite‐rich host rock formed gypsum‐bearing red coatings. These results have implications for understanding water–rock interactions and habitabilities at this site and on Mars.     

From ERS-1/2 to Sentinel-1: two decades of subsidence monitored through A-DInSAR techniques in the Ravenna area (Italy)

Land subsidence due to underground resources exploitation is a well-known problem that affects many cities in the world, especially the ones located along the coastal areas where the combined effect of subsidence and sea level rise increases the flooding risk. In this study, 25 years of land subsidence affecting the Municipality of Ravenna (Italy) are monitored using Advanced Differential Interferometric Synthetic Aperture Radar (A-DInSAR) techniques. In particular, the exploitation of the new Sentinel-1A SAR data allowed us to extend the monitoring period till 2016, giving a better understanding of the temporal evolution of the phenomenon in the area. Two statistical approaches are applied to fully exploit the informative potential of the A-DInSAR results in a fast and systematic way. Thanks to the applied analyses, we described the behavior of the subsidence during the monitored period along with the relationship between the occurrence of the displacement and its main driving factors.     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

Impacts of maintenance channel dredging in a northern Adriatic coastal lagoon. I: Effects on sediment properties,contamination and toxicity

Conservation and management of coastal lagoons envisage direct human intervention. To prevent siltation and to preserve the hydrodynamics features of the lagoon system, the inner channels undergo regular maintenance dredging.     

Shock effects in plagioclase feldspar from the Mistastin Lake impact structure,Canada

Shock metamorphism, caused by hypervelocity impact, is a poorly understood process in feldspar due to the complexity of the crystal structure, the relative ease of weathering, and chemical variations, making optical studies of shocked feldspars challenging. Understanding shock metamorphism in feldspars, and plagioclase in particular, is vital for understanding the history of Earth's moon, Mars, and many other planetary bodies. We present here a comprehensive study of shock effects in andesine and labradorite from the Mistastin Lake impact structure, Labrador, Canada. Samples from a range of different settings were studied, from in situ central uplift materials to clasts from various breccias and impact melt rocks. Evidence of shock metamorphism includes undulose extinction, offset twins, kinked twins, alternate twin deformation, and partial to complete transformation to diaplectic plagioclase glass. In some cases, isotropization of alternating twin lamellae was observed. Planar deformation features (PDFs) are notably absent in the plagioclase, even when present in neighboring quartz grains. It is notable that various microlites, twin planes, and compositionally different lamellae could easily be mistaken for PDFs and so care must be taken. A pseudomorphous zeolite phase (levyne‐Ca) was identified as a replacement mineral of diaplectic feldspar glass in some samples, which could, in some instances, also be potentially mistaken for PDFs. We suggest that the lack of PDFs in plagioclase could be due to a combination of structural controls relating to the crystal structure of different feldspars and/or the presence of existing planes of weakness in the form of twin and cleavage planes.