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1.
The dissolution of opaline silica of diatom tests in sea water 总被引:3,自引:0,他引:3
Two different series of measurements have been made of the solubilities and rates of solution in sea water of acid-washed siliceous tests of the diatomsThalassiosira decipiens andRhizosolenia hebetata. The kinetic approach was carried out on the assumption that the tests behave as identical solid spheres. If the tests were present in considerable excess over that required for saturation of the water with respect to silica, the dissolution obeyed first order reaction kinetics and its rate was proportional to the surface area of the exposed tests. When the tests were not in excess the kinetics of dissolution appeared to be more complex. This was considered to be due to a decrease in specific surface area as dissolution proceeded. An expression developed to allow for the change of surface area as a sphere dissolves offers a partial explanation of the kinetics when the tests are not present in excess. 相似文献
2.
Syed Bukhari Nick Eyles Shane Sookhan Riley Mulligan Roger Paulen Maarten Krabbendam Niko Putkinen 《Boreas: An International Journal of Quaternary Research》2021,50(3):781-805
Three-dimensional surface visualization models derived from high-resolution LiDAR data provide new information about the type and scale of erosional processes below Late Wisconsin palaeo-ice streams traversing the boundary between Canadian Shield crystalline rocks with offlapping Palaeozoic limestones in central Ontario. The hard bed is directly analogous to that found below ice streams in East Antarctica and East Greenland and provides insight into the effects of abrupt changes in substrate type on subglacial processes. Erosion of hard crystalline Canadian Shield rock was largely ineffectual consisting of areal abrasion of rounded whalebacks and local lee side plucking. In contrast, fast flow over the strike of gently dipping well-bedded and jointed Palaeozoic limestones cut large flow-parallel grooves and ridges akin to mega-scale glacial lineations reflecting intense abrasion below narrow streams of subglacial debris dominated by hard crystalline Shield clasts (erodents). Regionally extensive plucking of structurally weak, well-jointed and bedded limestone produced large volumes of rubbly carbonate debris leaving a 25-km-wide belt of uncontrolled hummocky rubble terrain (long known as the Dummer Moraine in Southern Ontario) some 350 km long and locally as much as 10 m thick. Subglacial plucking and abrasion under fast flowing ice were highly effective in stripping limestone cover rocks from Precambrian basement, and over many glacial cycles, may have played a role in the location and excavation of numerous large and deep lake basins around the Shield–Palaeozoic boundary zone in North America. 相似文献
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The late Chadian Foel Formation, previously thought to be confined to the Dyserth area of North Wales, forms a poorly exposed but persistent basal unit to much of the Dinantian crop east of the Clwydian Range, necessitating a revision of the local lithostratigraphy. The formation comprises a peritidal heterolith which, together with the lowest few metres of the overlying Llanarmon Limestone, yields microfossil assemblages diagnostic of the Eoparastaffella Cf4α Subzone. Succeeding strata, containing the lowest archaediscid foraminifera, provide the first record of Cf4β assemblages from North Wales and establish an early Arundian age for these beds. The Foel Formation was deposited as an aggradational sequence on the northern flank of St. George's Land during a pulsed transgression which began in late Chadian times. The widely recognized basal Arundian transgression is represented by the contact between the Foel Formation and overlying platform carbonates. The latter overlap the Foel Formation in the southernmost part of the Clwydian crop demonstrating, for the first time, southwards onlap on the northern side of the Bala–Bryneglwys Fault System. 相似文献
5.
Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most
rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable
excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this
type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive
decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed
by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had
dissolved. 相似文献
6.
The oceanographic conditions of the Mackenzie River plume in the Arctic Ocean were examined during a 12-day period in August 2007. Field observations in the river channel and the delta region (2–6 m depth), ship-based observations on the shelf and satellite observations of sea surface temperatures indicate that movements of plume density fronts cause changes in water temperatures of over 10 C over a few days. We used a 1D model to compare the strength of stratification versus surface wind stress, and a 3D numerical model to simulate the plume motions under forcing from the river flows, local wind and water level variations from tides and wind-driven surge. The results indicate that the coastal region is stratified with a ∼2 m thick surface plume even in water depths of 3–4 m, resulting in strong vertical variation of horizontal currents. Moderate easterly winds of 5–10 m/s are sufficient to induce offshore transport of the surface plume and onshore transport of the deeper shelf water, leading to large fluctuations in temperature and salinity in the coastal region. This study examined a period of offshore transport and mean water level set-down, and indicates the rapid response of the plume to wind over the shallow delta. 相似文献
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9.
The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as: where βHSO4 and βHF are the relevant association constants and ST and FT are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (KW) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units): where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers. 相似文献
10.
Timothy Garn David A. Green Julia M. Riley Paul Alexander 《Monthly notices of the Royal Astronomical Society》2009,397(2):1101-1112
We probe the relationship between star formation rate (SFR) and radio synchrotron luminosity in galaxies at 0 < z < 2 within the northern Spitzer Wide-area Infrared Extragalactic survey (SWIRE) fields, in order to investigate some of the assumptions that go into calculating the star formation history of the Universe from deep radio observations. We present new 610-MHz Giant Metrewave Radio Telescope (GMRT) observations of the European Large-Area ISO Survey-North 2 (ELAIS-N2) field, and using this data, along with previous GMRT surveys carried out in the ELAIS-N1 (North 1) and Lockman Hole regions, we construct a sample of galaxies which have redshift and SFR information available from the SWIRE survey. We test whether the local relationship between SFR and radio luminosity is applicable to z = 2 galaxies, and look for evolution in this relationship with both redshift and SFR in order to examine whether the physical processes which lead to synchrotron radiation have remained the same since the peak of star formation in the Universe. We find that the local calibration between radio luminosity and star formation can be successfully applied to radio-selected high-redshift, high-SFR galaxies, although we identify a small number of sources where this may not be the case; these sources show evidence for inaccurate estimations of their SFR, but there may also be some contribution from physical effects such as the recent onset of starburst activity, or suppression of the radio luminosity within these galaxies. 相似文献