Radioactive elements in collisional and within-plate Sodic-Potassic Granitoids: Accumulation levels and metallogenic significance

New data are reported on the content of radioactive elements in the Precambrian Na-K granitoids from the southwestern margin of the Siberian Craton, Aldan and Ukrainian shields, and Kursk-Voronezh Massif. Analytical data on other regions were generalized for comparison. Two global epochs of Na-K granitoid magmatism bearing elevated contents of radioactive elements (U, Th, K) were distinguished in the Early Precambrian (in Ga): Neoarchean (2.8-2.6) and Late Paleoproterozoic (1.9-1.75). Mesoarchean (3.1-2.8 Ga) epoch of Na-K granite formation has been additionally distinguished at the Australian, South African, and Canadian shields. These epochs of granitization provided high maturity of the crust: geochemical differentiation of the oldest continental blocks and their geochemical and metallogenic specialization for trace elements and RAE. In the southern margin of the Siberian Craton, the most intense granite formation occurred in the Late Paleoproterozoic. The extended South Siberian belt of collisional and within-plate Na-K granitoids is characterized by intense influx of RAE and other trace elements in the upper crustal shell. The southwestern margin of the craton (Yenisei Range) was spanned by repeated Late Neoproterozoic Na-K granite formation, with wide development of collisional and within-plate Na-K granites having elevated Th content and [Th]/[U] ratio. The higher RAE concentrations are typical of within-plate Paleo and Neoproterozoic granitoids. The highest uranium content was found in the postcollisional and within-plate Na-K granites and subalkaline leucogranites. Uranium ore concentrations were formed at the riftogenic stages of evolution of these crustal blocks, when within-plate subalkaline acid magmatism and accompanying hydrothermal metamorphism overprinted granitized crystalline massifs, including high-U sedimentary and volcanic complexes. Areas with the most favorable geological-geochemical environments for the formation of uranium mineralization were distinguished in the southern margin of the Siberian Craton and its nearest folded framing.     

Mercury Emanations from the Baikal Rift: Evidence from the Study of Annual Tree Rings (an Example of the Tunka Depression)

Doklady Earth Sciences - The phenomenon of natural degassing of mercury in the Baikal Rift Zone is considered on the basis of study of the annual rings of poplar (Populus suaveolens Fisch.) and...     

Anomalous gold contents in brown coals and peat in the south-eastern region of the Western-Siberian platform

One hundred twenty-two samples of Jurassic and Paleogene brown coals and 1254 peat samples from the south-eastern region of the Western-Siberian platform were analyzed for gold by the neutron-activation method. Mean content of Au in Jurassic coals is 30 ± 8 ppb, in Paleogene coals is 10.6 ± 4.8 ppb, and in peat is 6 ± 1.4 ppb. Concentrations of gold as high as 4.4 ppm were found in coal ash and 0.48 ppm in the peat ash. Coal beds with anomalous gold contents were found at Western-Siberian platform for the first time.Negative correlation between gold and ash yield in coals and peat and highest gold concentrations were found in low-ash and ultra-low-ash coals and peat. Primarily this is due to gold's association with organic matter.For the investigation of mode of occurrence of Au in peat the bitumen, water-soluble and high-hydrolyzed substances, humic acids, cellulose and lignin were extracted from it. It was determined that in peat about 95% of gold is combined with organic matter. Forty to sixty percent of Au is contained in humic acids and the same content is in lignin. Bitumens, water-soluble and high-hydrolyzed substances contain no more than 1% of general gold quantity in peat.The conditions of accumulation of high gold concentrations were considered. The authors suggest that Au accumulation in peat and brown coals and the connection between anomalous gold concentrations and organic matter in low-ash coals and peat can explain a biogenic–sorption mechanism of Au accumulation. The sources of formation of Au high concentration were various Au–Sb, Au–Ag Au–As–Sb deposits that are abundant in the Southern and South-Eastern peripheries of the coal basin.