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排序方式: 共有1472条查询结果,搜索用时 15 毫秒
1.
Philippe E. Raison Regis Jardin Daniel Bouëxière Rudy J. M. Konings Thorsten Geisler Claudiu C. Pavel Jean Rebizant Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra. 相似文献
2.
In an earlier paper Arp, Bi, Chu and Zhu investigated various quasar samples and recognized a periodicity of remarkable degree in them. Their conclusion was that the existence of such a periodicity is a counterevidence against the cosmological origin of quasar redshifts. Since this question is of great importance in a cosmological context, here we reanalyze some of the samples together with a galaxy sample of the pencil-beam survey of Broadhurstet al. Our result is that on the plane of cosmological parameters (0, 0) there is a non-negligible region where two quasar samples and the galaxy sample are simultaneously fairly periodic. Pure periodicity is still compatible with cosmological principles, at least on length scales much longer than the period length. So the regularities can fit into a cosmological context. 相似文献
3.
Yves Moëlo Pierre Palvadeau Nicolas Meisser Alain Meerschaut 《Comptes Rendus Geoscience》2002,334(8):529-536
Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å3, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu0.15Pb2(Pb0.53Sb0.47)(Pb0.46Sb0.54)(Sb0.75Pb0.19Bi0.06)S6; the reduced one: Cu0.58Pb12.72(Sb7.04Bi0.24)S24. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536. 相似文献
4.
We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border
group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures
(T
c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling
dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling
was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states
of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from
the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated
using an assumed average permeability of 10-12 cm2 for the pluton, but not completely with a model calculated on the basis of an average permeability of 10-13 cm2, although both values produced shifts of δ18O that are comparable to those observed in the pluton.
Received: 27 February 1995/Accepted: 20 July 1995 相似文献
5.
Delphine Yeghicheyan Cécile Bossy Martine Bouhnik Le Coz Chantal Douchet Guy Granier Alexie Heimburger Francois Lacan Aurélie Lanzanova Tristan C. C. Rousseau Jean‐Luc Seidel Mickaël Tharaud Frédéric Candaudap Jérôme Chmeleff Christophe Cloquet Sophie Delpoux Marie Labatut Rémi Losno Catherine Pradoux Yann Sivry Jeroen E. Sonke 《Geostandards and Geoanalytical Research》2013,37(4):449-467
The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. 相似文献
6.
Nicola Nocilla Aldo Evangelista Anna Scotto di Santolo 《Rock Mechanics and Rock Engineering》2009,42(5):815-833
In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations
and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte
Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic
limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency
towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks
on the cliff faces (V
0) and fallen blocks on the slopes (V
f). It was assumed that the ratio V
f/V
0 decreases with the distance (x
f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated
by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering
perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation
measures. 相似文献
7.
TritonX-100-5-Br-PADAP光度法测定铜和镍 总被引:2,自引:0,他引:2
研究了非离子型表面活性剂Triton X- 100 存在下,用5 - Br - PADAP 光度法测定铜、镍的方法。结果表明:在pH9 .0 的硼砂缓冲介质中,5 - Br - PADAP 与铜和镍生成紫红色络合物,λCum ax = 575 nm ,εCu = 1 .04 ×105 L·mol- 1·cm - 1 ;λNim ax = 575 nm ,εNi = 1 .14 ×105 L·mol- 1·cm - 1 。铜和镍的质量浓度分别在0 ~560 μg/ L和0 ~440 μg/ L符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与5 - Br - PADAP 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍5 次测定的RSD均小于5 % 。 相似文献
8.
Jane Bemigisha John Carranza rew K. Skidmore Mike McCall Chiara Polce Herbert H.T. Prins 《Transactions in GIS》2009,13(3):273-293
In a project to classify livestock grazing intensity using participatory geographic information systems (PGIS), we encountered the problem of how to synthesize PGIS-based maps of livestock grazing intensity that were prepared separately by local experts. We investigated the utility of evidential belief functions (EBFs) and Dempster's rule of combination to represent classification uncertainty and integrate the PGIS-based grazing intensity maps. These maps were used as individual sets of evidence in the application of EBFs to evaluate the proposition that " This area or pixel belongs to the high, medium, or low grazing intensity class because the local expert(s) says (say) so ". The class-area-weighted averages of EBFs based on each of the PGIS-based maps show that the lowest degree of classification uncertainty is associated with maps in which "vegetation species" was used as the mapping criterion. This criterion, together with local landscape attributes of livestock use may be considered as an appropriate standard measure for grazing intensity. The maps of integrated EBFs of grazing intensity show that classification uncertainty is high when the local experts apply at least two mapping criteria together. This study demonstrates the usefulness of EBFs to represent classification uncertainty and the possibility to use the EBF values in identifying and using criteria for PGIS-based mapping of livestock grazing intensity. 相似文献
9.
Summary Properties of the thermoremanent magnetization of various archaeological materials (baked-clay objects, samples from old trees, bones and stones) were investigated with the purpose to assess the possibility of their use for the determination of the earth's magnetic field in the historical past and to apply the data for solving some practical problems. It turns out that most of those materials yield magnetic values that can be used for making the radiocarbon dating method more accurate, for determining the degree of burning and for direct archaeomagnetic dating. The new conclusions also contribute to the knowledge of changes in the earth's magnetic field in the past. 相似文献
10.
河北平原水系密度与隐伏活动构造的关系 总被引:4,自引:1,他引:4
以1926年出版的比例尺为1:5万的顺直地形图作为基础图件,用地理信息系统技术对河北平原作水系密度计量分析,揭示隐伏在第四纪巨厚的沉积物之下活动构造的信息,研究结果证实水系线密度统计图与使用其它地球科学方法获得的成果,例如基底活动断块图,地貌类型图和第四纪厚度图都有很好的对应,特别与布格重力图对应更好,研究结果发现水系密度图与布格重力异常图在总体一致性较好的前提下,多处反向异常区均为近代强震发生的区域,提出这种地表水系密度统计研究的成果不仅可以揭示深部隐伏的活动构造,而且具有较明确的时间含义。 相似文献