Strain-related differences in the crystal growth of white mica and chlorite: a TEM and XRD study of the development of metapelitic microfabrics in the Southern Uplands thrust terrane, Scotland

Abstract TEM and XRD techniques were used to study crystal growth characteristics of the fabric-forming phyllosilicates which developed in response to low-grade metamorphism and tectonic imbrication in part of the Southern Uplands thrust terrane. Prograde regional metamorphism, ranging from late diagenesis through the anchizone to the epizone, was accompanied by the development of a slaty cleavage which is commonly bedding-parallel. TEM-measured mean thicknesses of white mica and chlorite crystallite populations increase with advancing grade and correlate with XRD-measured crystallinity indices. Analytical TEM data show that prograde changes in composition lead to a net loss of Si, Ca and minor Fe from the fabric-forming phyllosilicates. White micas are paragonite-poor phengites with a mean b lattice parameter of 9.037 Å, and indicate an intermediate pressure series of metamorphism with a field gradient of <25° C km^-1. Chlorite compositions evolved from diabantite (with intergrown corrensite) to ripidolite over an estimated temperature range of 150–320° C. Field gradient and temperature estimates suggest that crystal growth and fabric development occurred at burial depths ranging from 6 km to at least 13 km in the thrust terrane. During late diagenesis, crystal growth of white mica and chlorite was predominantly a consequence of polytypic and phase transitions, and resulted in similar size distributions which resemble typical Ostwald ripening curves. Under anchizonal and epizonal conditions, white mica grew more rapidly than chlorite because of its greater ability to store strain energy and recover from subgrain development; as a result crystal thickness distributions are not typical of Ostwald ripening. In contrast, chlorite crystals which grew under these conditions developed subgrain boundaries at high strain rates which were only partially recovered at low strain rates; these retained dislocations reduce the crystallite thicknesses detected by TEM and XRD, compared with those of white mica. These differences in strain-induced crystal growth indicate that white mica (illite) and chlorite crystallinity indices are likely to show significant differences where low-grade metamorphism is closely associated with tectonic fabric development.     

Interlobate ice-sheet dynamics during the Last Glacial Maximum at Whitburn Bay, County Durham, England

This research reconstructs ice-sheet processes operating during the Late Devensian in northeast England. The article assesses the lithostratigraphy of the Devensian glacial tills of Whitburn Bay, eastern County Durham, and presents the first detailed analysis of petrological, geochemical and biostratigraphical data to reconstruct lithostratigraphy, provenance and iceflow pathways. Two Devensian tractions tills (the Blackhall and Horden tills) are separated by a boulder pavement, pointing to a switch in ice-bed conditions and the production of a melt-out lag prior to deposition of the upper traction till, the Horden Till. The Blackhall Till contains Magnesian Limestone, Carboniferous Limestone, Whin Sill dolerite and Old Red Sandstone, suggesting a northwesterly source, probably from the Midland Valley and the Southern Uplands. The Horden Till contains erratics and heavy minerals derived from crystalline bedrock sources in the Cheviot Hills and northeast Scotland. Within the Horden Till are numerous sand, clay and gravel-filled canals incised downwards into the diamicton which are attributed to a low-energy, distributed, subglacial canal drainage system. Coupled with hydro-fractures and the boulder pavement, this suggests that a partially decoupled, fast-flowing ice stream deposited the Horden Till. The uphill, landward direction of ice movement indicates that the ice stream was confined in the North Sea Basin, possibly by the presence of Scandinavian Ice.     

ESTABLISHING LICHENOMETRIC AGES FOR NINETEENTH- AND TWENTIETH-CENTURY GLACIER FLUCTUATIONS ON SOUTH GEORGIA (SOUTH ATLANTIC)

Glaciers in small mountain cirques on South Georgia respond rapidly and sensitively to changes in South Atlantic climate. The timing and rate of their deglaciation can be used to examine the impact that nineteenth- and twentieth-century climate change has had on the glacial dynamics and terrestrial ecosystems of South Georgia. As part of a reconnaissance study in Prince Olav Harbour (POH), South Georgia, we measured the size of lichens ( Rhizocarpon Ram. em Th. Fr. subgenus. Rhizocarpon group) on ice-free moraine ridges around two small mountain cirques. Our aims were twofold: first, to provide age estimates for lichen colonization, and hence, deglaciation of the moraine ridges, and second, to examine the potential of applying lichenometry more widely to provide deglacial age constraints on South Georgia. In the absence of lichen age-size (dating) curves for South Georgia, we use long-term Rhizocarpon lichen growth-rates from recent studies on sub-Antarctic Islands and the western Antarctic Peninsula to calculate likely age estimates. These data suggest ice retreat from the two outermost moraines occurred between the end of the 'Little Ice Age' (post c. 1870) and the early twentieth century on South Georgia. Lichen colonization of the innermost moraines is probably related to glacier retreat during the second half of the twentieth century, which has been linked to a well-defined warming trend since c. 1950. Patterns of possible nineteenth- and twentieth-century glacial retreat identified in POH need to be tested further by establishing species- and site-specific lichen age-size (dating) curves for South Georgia, and by applying lichenometry to other mountain cirques across South Georgia.     

A comparison of scavenging and deposition processes in global models: results from the WCRP Cambridge Workshop of 1995

We report on results from a World Climate Research Program workshop on representations of scavenging and deposition processes in global transport models of the atmosphere. 15 models were evaluated by comparing simulations of radon, lead, sulfur dioxide, and sulfate against each other, and against observations of these constituents. This paper provides a survey on the simulation differences between models. It identifies circumstances where models are consistent with observations or with each other, and where they differ from observations or with each other. The comparison shows that most models are able to simulate seasonal species concentrations near the surface over continental sites to within a factor of 2 over many regions of the globe. Models tend to agree more closely over source (continental) regions than for remote (polar and oceanic) regions. Model simulations differ most strongly in the upper troposphere for species undergoing wet scavenging processes. There are not a sufficient number of observations to characterize the climatology (long‐term average) of species undergoing wet scavenging in the upper troposphere. This highlights the need for either a different strategy for model evaluation (e.g., comparisons on an event by event basis) or many more observations of a few carefully chosen constituents.     

Paper I – Optically stimulated luminescence (OSL) dating of perennially frozen deposits in north‐central Siberia: OSL characteristics of quartz grains and methodological considerations regarding their suitability for dating

Arnold, L. J. & Roberts, R. G. 2011: Paper I – Optically stimulated luminescence (OSL) dating of perennially frozen deposits in north?central Siberia: OSL characteristics of quartz grains and methodological considerations regarding their suitability for dating. Boreas, Vol. 40, pp. 389–416. 10.1111/j.1502‐3885.2011.00209.x. ISSN 0300?9483. Optically stimulated luminescence (OSL) dating of coarse‐grained quartz is increasingly being used as the main chronological tool in late Quaternary palaeoenvironmental reconstructions of Siberia. However, relatively little information has been published on the suitability of OSL dating for the various types of perennially frozen sediments found in this region. Here we provide a systematic examination of the quartz luminescence characteristics of 21 perennially frozen samples from the Taimyr Peninsula and adjacent coastal lowlands of north‐central Siberia, and discuss their implications for the reliability of single‐grain and multi‐grain OSL chronologies in such contexts. The results of this study suggest that the quartz luminescence characteristics of these samples are, in principle, favourable for OSL dating but, in practice, require that a series of validation checks are made of the chosen experimental conditions. If these tests are satisfied, then reliable OSL chronologies should be obtained for sedimentary deposits in this region. Importantly, however, the single‐grain and multi‐grain aliquot equivalent dose (D_e) distribution characteristics for our samples reveal that there are advantages in targeting certain types of depositional settings for OSL dating studies of Siberian sediments. We also show that samples from the same depositional settings, and even from the same sites, do not necessarily display similar D_e distribution characteristics. The latter complication favours the use of single‐grain analysis to unravel the bleaching and burial histories of young (mid‐ to late Holocene) sediments in these Arctic environments.     

Paper II – Dirt,dates and DNA: OSL and radiocarbon chronologies of perennially frozen sediments in Siberia,and their implications for sedimentary ancient DNA studies

Arnold, L. J., Roberts, R. G., MacPhee, R. D. E., Haile, J. S., Brock, F., Möller, P., Froese, D. G., Tikhonov, A. N., Chivas, A. R., Gilbert, M. T. P. & Willerslev, E. 2010: Paper II – Dirt, dates and DNA: OSL and radiocarbon chronologies of perennially frozen sediments in Siberia, and their implications for sedimentary ancient DNA studies. Boreas, Vol. 40, pp. 417–445. 10.1111/j.1502‐3885.2010.00181.x. ISSN 0300‐9483 The sedimentary ancient DNA (sedaDNA) technique offers a potentially invaluable means of investigating species evolution and extinction dynamics in high‐latitude environments. An implicit assumption of the sedaDNA approach is that the extracted DNA is autochthonous with the host deposit and that it has not been physically transported from older source deposits or reworked within the sedimentary profile by postdepositional mixing. In this paper we investigate whether these fundamental conditions are upheld at seven perennially frozen wetland sites across the Taimyr Peninsula and coastal lowlands of north‐central Siberia. Optically stimulated luminescence (OSL) and radiocarbon (¹⁴C) dating are used to constrain the ages of both the inorganic and organic fractions of perennially frozen deposits from which sedaDNA of extinct and extant species have been recovered. OSL and ¹⁴C age/depth profiles, as well as single‐grain equivalent dose (D_e) distribution characteristics, are used to assess the stratigraphic integrity of these sedaDNA sequences by (i) identifying the presence of primary or reworked organic and inorganic material, and (ii) examining the types of depositional and postdepositional processes that have affected specific sedimentary facies. The results of this study demonstrate that even though DNA preservation and stratigraphic integrity are commonly superior in perennially frozen settings, this does not, in itself, guarantee the suitability of the sedaDNA approach. The combined OSL and ¹⁴C chronologies reveal that certain perennially frozen sites may be poorly suited for sedaDNA analysis, and that careful site selection is paramount to ensuring the accuracy of any sedaDNA study – particularly for ‘latest appearance date’ estimates of extinct taxa.     

Multi-textured garnets from a single growth event: an example from northern Norway

Abstract Textural relationships between porphyroblasts of biotite and garnet in metasediments in the Nordkinn Peninsula area of the Finnmarkian Caledonides of North Norway are apparently complex. There is evidence for two textural zones in both mineral phases and superficially the development of these appears to have overlapped, at least in part, in time and space. This apparently complex porphyroblast growth history can be considerably simplified if only one period of garnet growth occurred and if different inclusion fabrics developed where garnet replaced biotite porphyroblasts and where it overgrew the matrix foliation. The possibility that porphyroblasts with textural evidence for multiphase growth histories actually grew during a single crystallization event is of importance in the interpretation and elucidation of tectonometamorphic relationships.     

MIGRATION OF MIXED-MODE VSP WAVEFIELDS1

Two-dimensional VSP surveys are often conducted to provide structural illumination of the subsurface away from the borehole. The illumination is achieved through offsetting the source with respect to the downhole geophone. This inevitably gives rise to mode-conversions in both downgoing and upgoing wavefields. Migration of mixed-mode wavefields is complex because the velocity profile used for wavefield extrapolation is valid only for a particular propagation mode; the other mode always propagates at a different velocity. It is therefore advisable to separate the wave-types (P-wave and SV-wave) prior to migration. This may be achieved through wavemode filtering, a multichannel process which exploits the relation between propagation velocity, slowness of events at the recording array and particle motion. The necessary information about particle motion is available only if the VSP data are acquired with a three-component downhole geophone assembly. The wavemode filter partitions wave-types at the recording array; it provides no information about the various changes of propagation mode experienced by the energy as it travels from source to geophone. For the purpose of migration, the intermediate modes of propagation must be deduced. Much of the energy arriving at the receivers is P-wave which has followed the P-wave velocity profile from the source. It can therefore be imaged by conventional (Kirchhoff) migration. As an example of SV-wave imaging, a common mode-code is P-wave from source to reflector and SV-wave from reflector to geophone. Migration of such data calls for back-propagation of the geophone array wavefield, at SV-wave velocity, to the point in the subsurface where it is time-coincident with the forward propagated downwave, at P-wave velocity.