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1.
原生有机质及沥青的有机地球化学研究结果表明矿区存在微弱的热异常,地层中原生有机质含量极低,沥青是成矿过程中由含矿热液他地带来的迁移型流体烃,流体迁烃在迁移时发生轻烃组分的分馏。在成矿部位,含有硫酸盐,铅锌和流体烃的深湖热液与携带硫酸盐还原细菌的大气降水汇合,流体烃发生生物降解和水洗溶解并引起硫酸盐的生物还原,生成硫化氢,导致铅锌硫化物沉淀,形成矿床。 相似文献
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在岩溶及其伴生的成矿作用发生的同时,来自溶解岩石中被分离出的有机质、地表水携带的陆生植物及由含矿卤水自深部或它地搬运的有机化合物与其它岩溶液填物一起沉积于岩溶洞穴中.根据它们的不同来源及受到岩溶成矿的影响程度,可区别出改造型、继承型、搬迁型、原生型有机质.由于有机质的热稳定性低,因此能较好地反映岩溶的性质、演变过程及其中成矿的特点.研究岩溶型铅锌矿床中有机质的类型、变化、分布规律,有助于矿床成因研究,指导找矿. 相似文献
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Ho KT Burgess RM Pelletier MC Serbst JR Ryba SA Cantwell MG Kuhn A Raczelowski P 《Marine pollution bulletin》2002,44(4):286-293
The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected. 相似文献
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McKay CP Grunthaner FJ Lane AL Herring M Bartman RK Ksendzov A Manning CM Lamb JL Williams RM Ricco AJ Butler MA Murray BC Quinn RC Zent AP Klein HP Levin GV 《Planetary and Space Science》1998,46(6-7):769-777
The MOx instrument was developed to characterize the reactive nature of the martian soil. The objectives of MOx were: (1) to measure the rate of degradation of organics in the martian environment; (2) to determine if the reactions seen by the Viking biology experiments were caused by a soil oxidant and measure the reactivity of the soil and atmosphere: (3) to monitor the degradation, when exposed to the martian environment, of materials of potential use in future missions; and, finally, (4) to develop technologies and approaches that can be part of future soil analysis instrumentation. The basic approach taken in the MOx instrument was to place a variety of materials composed as thin films in contact with the soil and monitor the physical and chemical changes that result. The optical reflectance of the thin films was the primary sensing-mode. Thin films of organic materials, metals, and semiconductors were prepared. Laboratory simulations demonstrated the response of thin films to active oxidants. 相似文献
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80年代以来,土壤地球化学已经被 在西澳在利亚Kalgoorlie北西约50km的黑旗地区进行金矿勘查的一种有效的技术。1991-1995年间,澳大利亚矿业公司在一片大约400km^2的租地区实施了一项系统的土壤地球化学计划;该地区的大部分此前曾经由许多不同的勘查小组用多种地球化学技术进行勘查。一个包含近40000个样品的GIS数据库被集成起来,这些数据部分来自MCA的工作,也适当地使用了无前勘查 相似文献