PCBs in Central Vietnam coastal lagoons: levels and trends in dynamic environments

PCBs were analysed in surficial sediments and selected sediment cores collected between 2002 and 2008 in Central Vietnam coastal lagoons. The aim was to determine contamination levels and trends, and to evaluate the effects of anthropogenic pressures and natural events. Samples were mostly fine-grained with low total PCB concentrations (0.367-44.7 μg kg⁻¹). Atmospheric transport and post depositional processes modify to some degree the fingerprint of PCB inputs to the environment favouring the predominance of 3, 4 and 5 chlorinated congeners. The similarity of congener distributions in contemporary surficial samples also suggests the presence of a unique source over the entire study area, probably connected to mobilisation and long range transports from land-based stocks. The removal of consistent sediment layers is hypothesised based on repeated samplings of the same area. Natural meteorological events (such as typhoons) are suspected to be responsible for these sediment losses.     

Chemical and textural equilibration of garnet during amphibolite facies metamorphism: The influence of coupled dissolution–reprecipitation

Metamorphic equilibration requires chemical communication between minerals and may be inhibited through sluggish volume diffusion and or slow rates of dissolution in a fluid phase. Relatively slow diffusion and the perceived robust nature of chemical growth zoning may preclude garnet porphyroblasts from readily participating in low‐temperature amphibolite facies metamorphic reactions. Garnet is widely assumed to be a reactant in staurolite‐isograd reactions, and the evidence for this has been assessed in the Late Proterozoic Dalradian pelitic schists of the Scottish Highlands. The 3D imaging of garnet porphyroblasts in staurolite‐bearing schists reveals a good crystal shape and little evidence of marginal dissolution; however, there is also lack of evidence for the involvement of either chlorite or chloritoid in the reaction. Staurolite forms directly adjacent to the garnet, and its nucleation is strongly associated with deformation of the muscovite‐rich fabrics around the porphyroblasts. “Cloudy” fluid inclusion‐rich garnet forms in both marginal and internal parts of the garnet porphyroblast and is linked both to the production of staurolite and to the introduction of abundant quartz inclusions within the garnet. Such cloudy garnet typically has a Mg‐rich, Mn‐poor composition and is interpreted to have formed during a coupled dissolution–reprecipitation process, triggered by a local influx of fluid. All garnet in the muscovite‐bearing schists present in this area is potentially reactive, irrespective of the garnet composition, but very few of the schists contain staurolite. The staurolite‐producing reaction appears to be substantially overstepped during the relatively high‐pressure Barrovian regional metamorphism reflecting the limited permeability of the schists in peak metamorphic conditions. Fluid influx and hence reaction progress appear to be strongly controlled by subtle differences in deformation history. The remaining garnet fails to achieve chemical equilibrium during the reaction creating distinctive patchy compositional zoning. Such zoning in metamorphic garnet created during coupled dissolution–reprecipitation reactions may be difficult to recognize in higher grade pelites due to subsequent diffusive re‐equilibration. Fundamental assumptions about metamorphic processes are questioned by the lack of chemical equilibrium during this reaction and the restricted permeability of the regional metamorphic pelitic schists. In addition, the partial loss of prograde chemical and textural information from the garnet porphyroblasts cautions against their routine use as a reliable monitor of metamorphic history. However, the partial re‐equilibration of the porphyroblasts during coupled dissolution–reprecipitation opens possibilities of mapping reaction progress in garnet as a means of assessing fluid access during peak metamorphic conditions.     

D-region recombination coefficients and the short wavelength X-ray flux during a solar flare

VLF phase and amplitude measurements were made on five different frequencies at São Paulo, Brazil during a solar flare which occurred on 22nd January 1972. The phase and amplitude measurements during the decay phase of the flare were combined with the full wave solutions of Wait and Spies (1964) to calculate the recombination coefficient in the lower ionosphere. The values thus obtained are lower than those reported by Reid (1970), but are compatible with those reported by Montbriand et al. (1972) during Solar X-ray events. The effective loss rates have been utilized to calculate the ion-production at the maximum of the flare, which in turn has been utilized to calculate the incident X-ray flux as a function of wavelength at the maximum of the flare. Extensions to the calculations are discussed.     

PCBs and PAHs in sea-surface microlayer and sub-surface water samples of the Venice Lagoon (Italy)

Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) are two classes of micropollutants intensively monitored and regulated due to their toxicity, persistency and wide diffusion. Their concentrations have been investigated in sea-microlayer (SML) and sub-surface water (SSW) samples collected at two sites of the Venice Lagoon, a fragile ecosystem highly influenced by industrial and anthropogenic emissions. The total sigmaPCB concentration varies from 0.45 ng/l to 2.1 ng/l in SSW while a clear enrichment is observed in the SML, where it ranges from 1.2 ng/l to 10.5 ng/l. The total sigmaPAH concentration shows marked differences between the two stations and varies from 12.4 ng/l to 266.8 ng/l in SSW; in SML it is more uniform and ranges from 19.6 ng/l to 178.9 ng/l. The enrichment factors are not larger than 1 for both pollutants in the 'dissolved' phase, while they are most significant for the 'particulate' phase (sigmaPCB: 5-9; sigmaPAH: 4-14).     

On the relation of SPA measured at VLF to solar microwave burst energies

A surprisingly good correlation has been found for SPA measured at VLF propagation () and 7 GHz solar microwave burst energies (E ). The data are correlated in the form = a log E + b and include all kind of solar events, irrespectively from type, complexity or duration. Soft X-ray peak fluxes (I _x) have a known similar correlation to SPA, and a functional relationship of the form 479-01 can be established. As one practical application, the energies from solar events can be reasonably well inferred from SPA data, which are quite reliable and easily obtainable.     

4.7s nearly periodic oscillations superimposed on the solar microwave great burst of 28 March 1976

An unusual fast oscillation was found superimposed on the solar great burst of 28 March 1976, as measured at 7 GHz. The period of the osculation was 4.7 ± 0.9s, defined over the entire duration of the event. The amplitude of the oscillation was proportional to the flux density, in the range 50 < S < 3000 solar flux units. The degree of circular polarization has not shown any fast periodic time structures.Presently merged with CNP, Observatório Nacional.     

Possible low ionosphere response to very hard X-rays from Cygnus X-3 bursts in september 1972

Coincidence of VLF propagation anomalies in the low terrestrial ionosphere with the flaring period of Cyg X-3 tentatively suggest that this source has shown an output in very hard X-rays. difficulties in interpretation are discussed.     

Nekton community response to a large-scale Mississippi River discharge: Examining spatial and temporal response to river management

Freshwater flow is generally held to be one of the most influential factors affecting community structure and production in estuaries. In coastal Louisiana, the Caernarvon Freshwater Diversion (CFD) is managed to control freshwater discharge from the Mississippi River into Breton Sound basin. Operational since 1991, CFD has undergone several changes in management strategy including pulsed spring flooding, which was introduced in 2001. We used a 20-yr time series of fisheries-independent data to investigate how variation in freshwater inflow (i.e., pre- and post-CFD, and pre and post spring pulsing management) influences the downstream nekton community (abundance, diversity, and assemblage). Analyses of long-term data demonstrated that while there were effects from the CFD, they largely involved subtle changes in community structure. Spatially, effects were largely limited to the sites immediately downstream of the diversion and extended only occasionally to more down-estuary sites. Temporally, effects were 1) immediate (detected during spring diversion events) or 2) delayed (detected several months post-diversion). Analysis of river management found that pulsed spring-time inflow resulted in more significant changes in nekton assemblages, likely due to higher discharge rates that 1) increased marsh flooding, thus increasing marsh habitat accessibility for small resident marsh species, and 2) reduced salinity, possibly causing displacement of marine pelagic species down estuary.     

Turbidites facies response to the morphological confinement of a foredeep (Cervarola Sandstones Formation,Miocene, northern Apennines,Italy)

The Cervarola Sandstones Formation, Aquitanian–Burdigalian in age, was deposited in an elongate, north‐west stretched foredeep basin formed in front of the growing northern Apennines orogenic wedge. As other Apennine foredeep deposits, such as the Marnoso‐arenacea Formation, the stratigraphic succession of the Cervarola Sandstones Formation records the progressive closure of the basin due to the propagation of thrust fronts towards the north‐east, i.e. towards the outer and shallower foreland ramp. This process produces a complex foredeep that is characterized by syn‐sedimentary structural highs and depocentres that strongly influence lateral and vertical turbidite facies distribution. This work describes and discusses this influence, providing a high‐resolution physical stratigraphy with ‘bed by bed’ correlations of an interval ca 1000 m thick, parallel and perpendicular to the palaeocurrents and to the main structural alignments, on an area of ca 30 km that covers the proximal portion of the Cervarola basin in the northern Apennines. The main aim is to show, for the first time ever, a detailed facies analysis of the Cervarola Sandstones Formation, based on a series of bed types that have proven fundamental to understand the morphology of the basin. The knowledge of the vertical and lateral distribution of these bed types, such as contained‐reflected and slurry (i.e. hybrid) beds, together with other important sedimentary structures, i.e. cross‐bedded bypass facies and delamination structures, is the basis for better understanding of facies processes, as well as for proposing an evolutionary model of the foredeep in relation to the syn‐sedimentary growth of the main tectonic structures. This makes the Cervarola Sandstones, like the Marnoso‐arenacea Formation, a typical example of foredeep evolution.