Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.     

A 20 cm2 CCD mosaic camera for a dark matter search part I : Mechanics,optics and cryogeny

A 20cm ² CCD mosaic camera has been especially built to search for dark galactic halo objects by the gravitational microlensing effect. The sensitive area is made of 16 edge-buttable CCDs developped by Thomson-CTS, with 23×23 µm ² pixels. The 35 kg camera housing and mechanical equipment is presented. The associated electronics and data acquisition system are described in a separate paper. The camera resides at the focal plane of a 40 cm, f/10, Ferson reflector. The instrument has been in operation since December 1991 at the La Silla Observatory (ESO).     

New seismic data in the Mozambique Channel

This paper presents seismic reflection and refraction data from the Mozambique Channel, collected between 1971 and 1973. A deep sedimentary basin (up to 5 km of sediments) opens southwards to the Mozambique Basin, and is bounded to the east by the Davie Ridge and beyond by the marginal plateau of Malagasy. A continuous reflector (C), possibly of Cretaceous age, is identified between layers having seismic interval velocities of 2.4–2.8 km/s and 3.1–3.4 km/s. The deepest sediments have velocities of 4.5–4.9 km/s and overlie a layer with velocity 5.5 km/s, which may be volcanic in the north-east of the Channel.The crust occupying most of the Channel is probably pre-Cretaceous in age, and may be largely continental in nature. This is supported by subdued magnetic anomalies and the possibility of a continuous Karroo sedimentary section across the northern Channel. The oceanic crust of the Mozambique Basin may extend as far north as 24°S, into the western Channel only. The problem of the origin of the Mozambique Channel remains unresolved, although a long sedimentary history indicates that Malagasy may have separated from Mainland Africa prior to Karroo times. The Davie Ridge may possibly represent a relict strike-slip fault, which permitted movement along a north-south line.     

Transverse vibrations of a rectangular cantilever plate with thickness varying in a discontinuous fashion

A numerical solution is obtained for the title problem by means of the popular finite element method. An experimental investigation of the problem is also presented for plates of square planform. The agreement between theoretical and experimental values is very good in the case of the fundamental frequency, and reasonably good when the second and third normal modes of transverse vibration are considered. It is concluded that beneficial effects are obtained in the sense that one generates a lighter structural element with higher fundamental frequency of transverse vibration. Hence, dynamic stiffening is achieved.     

Ability of indigenous Bacillus licheniformis and Bacillus subtilis in microbial enhanced oil recovery

Microbially produced lipopeptide have been isolated and studied for microbial enhanced oil recovery. About 60 gram positive bacteria isolated from soil contaminated with crude oil, near the crude oil storage tank in Tehran Refinery, Tehran, Iran. However, most of these studies have produced lipopeptide by one of the pure-culture microbes isolated in a laboratory. Among the isolates, heamolytic tests revealed two biosurfactant producers. The isolated strains were designated as C2, E1. By using morphological, biochemical and molecular biology tests (16 SrRNA), the strains identified as Bacillus licheniformis and Bacillus subtitlis, respectively. Emulsification activity and measurement of surface tension indicated that, the isolates were high producers of biosurfactant. The product of C2 and E1 is mainly lipopeptide. This product reduce surface tension from 65 to 30 mN/m. Emulsified activity of crude oil was 92% for C2 and 90 % in case of E1. This is the first report of indigenous Bacillus licheniformis and Bacillus subtilis from a soil contaminated with oil in an Iranian refinery with ability to produce biosurfactant.     

Comparison between a radiative wind model for be stars and high angular resolution data from the GI2T interferometer

I present theoretical line profiles and intensity maps from an axi-symmetric radiative wind model from a rapidly rotating Be star. The introduction of a viscosity parameter in the latitude-dependent hydrodynamic code enables us to consider the effects of the viscous force in the azimuthal component of momentum equations (Araújo et al. 1994). Both velocity field and density law derived from the hydrodynamic equations have been used for solving the statistical equilibrium equations. By adopting the Sobolev approximation, we could easily obtain a good estimate of both electronic density and hydrogen level populations throughout the envelope. The numerical calculation was performed for parameters characterisic of the Be star Cassiopeiae.     

Structure of the αFexAl1:xOOH solid solution

The three-dimensional local organisation around Fe atoms in a natural diaspore (Al_0.9955Fe_0.0045OOH) has been investigated by angular measurements of X-ray absorption spectra. It is demonstrated that in a single crystal of diaspore, the absorption cross-section exhibits the special case of trichroism where three independent measurements are needed to determine the absorption cross-section for any direction of polarization. Extended X-ray absorption fine structure (EXAFS) spectra were thus recorded at the following orientations of the polarization vector: , , and . The incoming white beam was monochromatized using two Si(331) crystals, which deliver at the Fe K-edge a completely linearly polarized X-ray beam. The reliability of our measurements was checked by comparing the isotropic EXAFS spectrum calculated from the three orthogonal measurements to the one of the diaspore powder recorded at the magic angle. It is shown that Fe³⁺ ions are not randomly distributed within the diaspore framework. Furthermore, only part of the Fe³⁺ ions substitutes Al, the others being located in the channels of the structure. The 3D local structure of the Fe domains has been modeled assuming hematite-like clusters of three Fe octahedra topotactically grafted to aluminous chains. These Fe clusters are thought to represent ancient multinuclear Fe surface complexes having formed at the time of the diaspore growth, and being sealed in its bulk structure. The whole crystal of diaspore is then thought to have kept the memory of the heterogeneous nucleation mechanism of these hematite nuclei. In addition to the well-known examples of atom segregations, ion vacancies, and intergrowths of discrete phases, this new type of crystal defect represents another evidence of non-equilibrium crystallization process under the thermodynamic and kinetic conditions that prevail at the earth's surface.     

Diffusion induced Li isotopic fractionation during the cooling of magmatic rocks: The case of pyroxene phenocrysts from nakhlite meteorites

Ion-microprobe was used to measure Li abundances and isotopic compositions in pyroxenes from three Martian meteorites belonging to the nakhlite family. The profiles performed across augite crystals from Northwest Africa 817 show a large isotopic zoning from crystal cores (δ⁷Li ∼ 0‰) to rims (δ⁷Li ∼ +20‰) while Li abundances are almost constant (∼9.2 μg/g). Unlike NWA 817, the pyroxene studied in the Miller Range 03346 nakhlite shows a zoning in Li abundance, with concentrations increasing from ∼2.5 μg/g in the core to ∼9 μg/g in the rim. The augite rim (δ⁷Li = +7‰) is slightly enriched in ⁷Li with regard to the core (δ⁷Li = +4‰), but most of the isotopic variations observed occur at an intermediate position along the profile, where δ⁷Li falls down to ∼−11‰. In the case of Nakhla, Li concentrations in augite increase from cores (∼3.5 μg/g) to rims (∼6.5 μg/g), while the δ⁷Li variation is restricted (i.e., between δ⁷Li = +6.0 and +12.6‰). For the three meteorites the Li abundances were also measured in the groundmass, which was found to be enriched in lithium (∼10 μg/g). Conventional magmatic and post-magmatic processes such as alteration and fractional crystallization, fail to explain the dataset obtained on nakhlites. Degassing processes, which were previously proposed to explain the Li distribution in shergottite crystals, cannot result in the strong decoupling between Li abundances and isotopic composition observed in nakhlites. We suggest that the original magmatic Li distributions (concentrations and isotopic compositions) in nakhlites have been modified by diffusion of Li from the Li-rich groundmass towards the pyroxene crystals during sub-solidus cooling. Diffusion appears to have been efficient for NWA 817 and MIL 03346 but, apparently, did not produce a significant migration of Li in Nakhla, possibly because of the lower abundance of groundmass in the latter. Diffusion induced Li redistributions may also affect terrestrial porphyric rocks but very specific cooling rates are required to quench the diffusion profiles as observed in two of the present nakhlites.     

Assessment of the mycoflora of commercial poultry feeds sold in the humid tropical environment of Imo State, Nigeria

This study was carried out to identify the common moulds growing in selected commercial poultry feed sold in Owerri, Imo State, Nigeria. Forty-eight bulk samples derived froml92 bags of feeds were collected from broiler starter (BS), broiler finishers (BF), grower mash (GM) and layer mash (LM) across 4 different brands of ommercial poultry feeds, which included Livestock (LF), Top (TF) Guinea (GF) and Vital (VF) feeds. The feed samples were collected during the rainy season months of June, July and August. The common moulds isolated from these feeds were Aspergillus sp., Peicillium sp.,Mucor sp., Yeast sp., Rhizopus sp., Epicoecum sp., Gymnoaseus sp., Cladosporium sp., Mortierella sp. as well as Bacteria. Generally, more organisms were isolated in June than the other months with Mortierella sp. being the only one not isolated in that month. Vital feed with 8 different isolates had the highest diversity of fungal species while the others had between 4 and 5 species. Prevalence rates across the feed types, generally ranged from 18.76% in layer mash to 30.03% in broiler finisher. The four Aspergillus sp. isolated came from GM and BF. This study highlights the need for constant monitoring of moulds in commercial feedstuff produced in the humid tropical environments such as Imo state, Nigeria. There is also the need to routinely include fungal growth nhibitors in commercial feeds since moulds are capable of reducing the nutritional values of feedstuff as well as elaborating pathogenic toxins.     

Total organic carbon in soils and its relation with manganese concentrations in soils and vegetation close to an abandoned manganese mine

This study aimed at quantifying the total organic carbon (TOC) present in soils within the proximity of the Kgwakgwe Mn oxide ore abandoned mine, Botswana, and establish its relationship with Mn concentrations in soils and vegetation based on multivariate and Geographical Information Systems (GIS) analytical techniques. Four hundred soil samples and 200 vegetation set samples were obtained from a 4 km² area close to the abandoned mine. The TOC in soil samples were determined using a carbon/hydrogen/moisture determinator, and Mn concentrations in soils and vegetation by atomic absorption spectrophotometry. Results were processed using the statistical package for social science (SPSS), GIS, and Remote Sensing (RS) techniques with the Integrated Land and Water Information System (ILWIS), Geosoft Oasis Montaj and ArcGIS software packages. The values for TOC in the soil samples from the study area ranged from 0 wt % to 7.91 wt %, with a mean of 1.90 wt %, and at the control area, from 4.07 wt % to 4.86 wt %. The range of concentrations of Mn in soils was from 36 mg/g to 24908 mg/g and for Mn concentrations in the vegetation samples from 26 mg/g to 3611 mg/g with a mean of 598 mg/g. Results of correlation coefficients depicted very weak negative association except Mn in soils/Mn in leaves which was weak but positive. The statistical data yielded four clusters as follows: cluster one consisted mainly of Mn in leaves, cluster two was constituted of Mn in soils, and cluster four had TOC. Cluster three was dominated by the three parameters but with negative t statistic. The spatial presentation of data presented revealed little or no vegetation in the south eastern area and those close to the mine workings, and some significant vegetation in the north western part of the study area. The low TOC in the soils is associated to low vegetation cover which is considered to have been influenced by the soil clay fraction mineralogy and high concentrations of Mn.