Arsenic incorporation in a salt marsh ecosystem

Replicate portions of a Delaware salt marsh were enclosed in cylindrical microcosms and exposed to elevated levels of inorganic arsenic (arsenate). All biotic and abiotic components in dosed cylinders rapidly incorporated arsenic. Spartina blades showed the greatest arsenic enrichment, with dosed plants incorporating arsenic concentrations an order of magnitude higher than controls. Spartina detritus and sediments also exhibited greatly elevated arsenic concentrations. Virtually all of the arsenic was incorporated into plant tissue or strongly sorbed to cell surfaces. Thus, elevated arsenic concentrations in estuarine waters will be reflected in living and non-living components of a salt marsh ecosystem, implying that increased arsenic will be available to organisms within the marsh ecosystem.     

Fourier analysis of the light curves of eclipsing variables. XIII

New expressions for the fractional loss of light _l ⁰ have been derived in the simple forms of rapidly converging expansions to the series of Chebyshev polynomials, Jacobi polynomials, and Kopal'sJ-integrals. In these expansions, which are a supplement to those given by Kopal (1977b), variablesk andh occur in different products that simplify the numerical computation. The treatment follows the new definition of _l ⁰ which has been recently developed by Kopal (1977a).     

Geodynamic significance of granitoid magmatism in the southeast Anatolian orogen: geochemical and geochronogical evidence from Göksun–Afşin (Kahramanmaraş, Turkey) region

In southeast Anatolia, there are number of tectonomagmatic units in the Kahramanmaraş–Malatya–Elazığ region that are important in understanding the geological evolution of the southeast Anatolian orogenic belt during the Late Cretaceous. These are (a) metamorphic massifs, (b) ophiolites, (c) ophiolite-related metamorphics and (d) granitoids. The granitoids (i.e. Göksun–Afşin in Kahramanmaraş, Doğanşehir in Malatya and Baskil in Elazığ) intrude all the former units in a NE–SW trending direction. The granitoid in Göksun–Afşin (Kahramanmaraş) region is mainly composed of granodioritic and granitic in composition. The granodiorite contains a number of amphibole-bearing mafic microgranular enclaves of different sizes, whereas the granite is intruded by numerous aplitic dikes. The granitoid rocks have typical calcalkaline geochemical features. The REE- and Ocean ridge granite-normalized multi-element patterns and tectonomagmatic discrimination diagrams, as well as biotite geochemistry suggest that the granitoids were formed in a volcanic arc setting. The K–Ar geochronology of the granitoid rocks yielded ages ranging from 85.76±3.17 to 77.49±1.91 Ma. The field, geochemical and geochronological data suggest the following Late Cretaceous tectonomagmatic scenario for southeast Anatolia. The ophiolites were formed in a suprasubduction zone tectonic setting whereas the ophiolite-related metamorphic rocks formed either during the initiation of intraoceanic subduction or late-thrusting (∼90 Ma). These units were then overthrust by the Malatya–Keban platform during the progressive elimination of the southern Neotethys. Thrusting of the Malatya–Keban platform over the ophiolites and related metamorphic rocks was followed by the intrusion of the granitoids (88–85 Ma) along the Tauride active continental margin in the southern Neotethys.     

An assessment on size and site selection of emergency assembly points and temporary shelter areas in Düzce

Natural Hazards - Open green spaces contribute to urban/rural life in terms of ecological, recreational, spatial, economic, etc., functions as well as prevention of natural disasters, mitigation of...     

Parametric rolling behaviour of azimuthing propulsion-driven ships

The study investigates the experimental and numerical analysis of the occurrence of auto-parametric rolling for large, high-speed pod-driven ships in waves. Considering unique design and performance targets, the aim here is to exploit susceptibility to auto-parametric rolling behaviour and to identify probable design and operational precautions. In order to achieve this aim, an existing non-linear time-domain software to simulate capsizing and other critical manoeuvring behaviours of slow- to medium-speed conventional and podded ships in waves is being enhanced for fast pod-driven vessels and then compared against the dedicated model test conducted in long-crested regular and random waves for a large, pod-driven containership model. This paper includes the presentation of current numerical modifications for pod-driven ships and the verification analysis.     

Groundwater recharge in arid areas induced by tropical cyclones: lessons learned from Gonu 2007 in Sultanate of Oman

Younger groundwater found in some Omani aquifers is a result of recent recharge from cyclonic and storm events [Weyhenmeyer et al. (Science 287:842–845, 2000); Young et al. (J Appl Geophys 57:43–61, 2004)]. The analysis of the meteorological data in Oman indicates an anomalous rainfall on a decadal interval whereas cyclones frequency is expected to increase due to global climatic changes. The cyclone Gonu has severely struck the eastern Omani coasts in 2007 resulting in devastating floods. Huge volume of water (3,672 mm³) spread over the coastal plain calling for an assessment of potential groundwater recharge subsequent to this event. The present study evaluates groundwater recharge with respect to Gonu 2007 to assess the potential of recharge induced by such cyclones in the arid zones. The hydrographs of several piezometers sited along the coastal plain in Muscat Province have been studied and variation in water table rise has been analyzed. Significant water table rise is indicated for areas with geological and structural settings favoring rapid infiltration of water yielding considerable groundwater mound, whereas piezometers located in less favorable zones show minimum rise of water table. However, soon after the floods the aquifer hydrodynamics has readjusted to attain equilibrium and the groundwater mound dissipated. The cumulative rise of the water table on an areal extent does not exceed a few centimeters indicating lesser volume of recharge. Comparatively, recharge from frequent precipitation along favorable zones produces more significant recharge compared with cyclonic events where surface water residence time is shorter to allow for efficient infiltration.     

High-resolution facies and porosity models of the upper Jurassic Arab-D carbonate reservoir using an outcrop analogue, central Saudi Arabia

Subsurface models of hydrocarbon reservoirs are coarse and of low resolution when compared with the actual geologic characteristics. Therefore, the understanding of the three-dimensional architecture of reservoir units is often incomplete. Outcrop analogues are commonly used to understand the spatial continuity of reservoir units. In this study, a Late Jurassic outcrop analogue for the Arab-D reservoir of central Saudi Arabia was used to build a high-resolution model that captures fine geologic details. Subsurface reservoir lithofacies were matched with those from the studied outcrop, and porosity values derived from published core and well log data from the Ain Dar, Uthmanyah, and Shudgum areas of the Ghawar Field, eastern Saudi Arabia, were then applied to the equivalent lithofacies in the outcrop. Maximum, minimum, and average subsurface porosity for each lithofacies were distributed in the facies model using a geostatistical algorithm to produce nine porosity models for the field data. Several realisations were run to visualise the variability in each model and to quantitatively measure the uncertainty associated with the models. The results indicated that potential reservoir zones were associated with grainstone, packstone, and some wackestone layers. Semivariogram analysis of the lithofacies showed good continuity in the N-S direction and less continuity in the E-W direction. The high-resolution lithofacies models detected permeability barriers and isolated low porosity bodies within the potential reservoir zones. This model revealed the porosity distribution in areas smaller than one cell in the subsurface model and highlighted the uncertainty associated with several aspects of the model.     

Geochemistry of Pliocene/Pleistocene basalts along the Central Anatolian Fault Zone (CAFZ), Turkey

Abstract

Pliocene-Pleistocene volcanism accompanied strike-slip-related transtensional deformation along the K?z?l?rmak fault segment of the Central Anatolian fault zone (CAFZ) in the west of ?ark??la (Sivas-central Turkey). These volcanic rocks are represented by alkali olivine basalts. They can be divided into four different sub-groups on the basis of their Zr, Nb, TiO₂ contents. A primitive mantle-normalized incompatible trace element diagram for four subgroups shows close similarity to typical OIB pattern. Some of the incompatible trace element ratios (Ce/Y, Zr/Nb, La/Ba, La/Nb) are also akin to OIB values. Highly fractionated REE patterns (La/Yb_N=24.7–9.2) with no Eu anomaly are the main features of the alkali basalts and are comparable to alkaline volcanism in continental rift zones. On the basis of Al₂O₃/TiO₂, Nb/Y, Zr/Y Zr/Nb ratios, the geochemical differences among four sub-groups can be explained by variable degrees of partial melting of compositionally similar mantle source. Th/Nb, Th/Y, Nb/Y ratios and the primitive mantle-normalized trace element diagram suggests significant amount of crustal involvement for most of the alkali olivine basalts erupted along the CAFZ. Rupture of the continental lithosphere by strike-slip-related transtensional deformation might have caused decompressional partial melting of the asthenospheric mantle and generating alkali olivine basalts in this region. © 2001 Éditions scientifiques et médicales Elsevier SAS.