Collisional excitation of interstellar cyclopropenylidene

Theoretical rotational excitation rates were computed for C3H2 in collisions with He atoms at temperatures from 30 to 120 K. The intermolecular forces were obtained from accurate self-consistent field and perturbation theory calculations, and collision dynamics were treated within the infinite-order sudden approximation. The accuracy of the latter was examined by comparing with the more exact coupled states approximation.     

Deducing the spatial variability of exchange within a longitudinal channel water balance

Developing an appropriate data collection scheme to infer stream–subsurface interactions is not trivial due to the spatial and temporal variability of exchange flowpaths. Within the context of a case study, this paper presents the results from a number of common data collection techniques ranging from point to reach scales used in combination to better understand the spatial complexity of subsurface exchanges, infer the hydrologic conditions where individual influences of hyporheic and groundwater exchange components on stream water can be characterized, and determine where gaps in information arise. We start with a tracer‐based, longitudinal channel water balance to quantify hydrologic gains and losses at a sub‐reach scale nested within two consecutive reaches. Next, we look at groundwater and stream water surface levels, shallow streambed vertical head gradients, streambed and aquifer hydraulic conductivities, water chemistry, and vertical flux rates estimated from streambed temperatures to provide more spatially explicit information. As a result, a clearer spatial understanding of gains and losses was provided, but some limitations in interpreting results were identified even when combining information collected over various scales. Due to spatial variability of exchanges and areas of mixing, each technique frequently captured a combination of groundwater and hyporheic exchange components. Ultimately, this study provides information regarding technique selection, emphasizes that care must be taken when interpreting results, and identifies the need to apply or develop more advanced methods for understanding subsurface exchanges. Copyright © 2013 John Wiley & Sons, Ltd.     

What is the source of baseflow in agriculturally fragmented catchments? Complex groundwater/surface‐water interactions in three tributary catchments of the Wabash River,Indiana, USA

Some conceptual models suggest that baseflow in agriculturally fragmented watersheds may contain little, if any, groundwater. This has critical implications for stream quality and ecosystem functioning. Here, we (a) identify the sources and flowpaths contributing to baseflow using ²²²Rn and ⁸⁷Sr/⁸⁶Sr and (b) quantify mean apparent ages of groundwater and baseflow using multiple isotopic tracers (CFC, SF₆, ³⁶Cl, and ³H) in 4 small (0.08 to 0.64 km²) tributary catchments to the Wabash River in Indiana, USA. ²²²Rn activities and ⁸⁷Sr/⁸⁶Sr ratios indicate that baseflow in 3 catchments is sourced primarily from groundwater; baseflow in the fourth is dominated by a source similar to agricultural run‐off. CFC‐12 data indicate that springs in 1 catchment are discharging significant proportions of water that recharged between 1974 (42 ± 2 years) and 1961 (55 ± 2 years). Those same springs have ³⁶Cl/Cl ratios between 1,381.08 ± 29.37 (×10^?15) and 1,530.64 ± 27.65 (×10^?15) indicating that a substantial proportion of the discharge likely recharged between 1975 (41 years) and 1950 (66 years). Groundwater samples collected from streambed mini‐piezometers in a separate catchment have CFC‐12 concentrations indicating that a large proportion of the recharge occurred between 1948 (68 ± 2 years) and 1950 (66 ± 2 years). Repeat sampling conducted in September 2015 after above‐average summer rainfall did not show significant decreases in mean apparent age. The relatively old ages observed in 3 of the catchments can be explained by geological complexities that are likely present in all 4 catchments, but overwhelmed by flow from the shallow phreatic aquifer in the fourth catchment.     

The impact of biofuel-induced food-price inflation on dietary energy demand and dietary greenhouse gas emissions

Dramatic increases in liquid biofuel production have led to concerns about associated impacts on food prices, with many modeling studies showing significant biofuel-related price inflation. In turn, by changing patterns of food demand, biofuel production may indirectly influence greenhouse gas emissions. We estimated changes to dietary energy (calorie) demand and greenhouse gas emissions embodied in average diets under different biofuel-related food-price scenarios for Brazil, China and the United States, using food-price projections and food-price elasticities. Average energy demand decreased in all countries, from about 40 kcal per person per day in Brazil under a moderate price inflation scenario – a reduction of 1% relative to the (2009) reference scenario – to nearly 300 per day in the United States with high price inflation – almost 8% of reference levels. However, emissions per calorie increased slightly in all three countries. In terms of total greenhouse gas emissions, the results are suggestive of overall reductions only in the United States, where average reductions ranged from about 40 to 110 kg of carbon dioxide equivalent emissions per person per year. In China, the direction of impact is unclear, but the net change is likely to be small. Brazilian results were sensitive to parameter values and the direction and magnitude of impact is therefore uncertain. Despite the uncertainty, even small changes (positive or negative) in individual dietary emissions can produce large changes at the population level, arguing for the inclusion of the dietary pathway in greenhouse gas accounting of liquid biofuels.     

Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting

The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess ²³⁰Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation.     

All-sky ultraviolet surveys: the needs and the means

This is a crucial time in the history of astronomy with major all-sky surveying work being carried out in all spectral bands, as well as in astrometry. The results of this activity are advancing all fields of astrophysical research, from the investigation of exo-planetary systems to the study of the chemical evolution of the Universe. Full sky surveys are available from the radio domain to X-ray wavelengths but not in the ultraviolet range (UV). While large UV missions are currently under discussion within the astrophysical community and at the major Space Agencies, the efficient use of resources requires preparatory work that can fill the UV surveying gap. This article summarizes the research and on-going activities in this field.     

A damped train of regular metre-wave pulses from the sun

The metre-wave observations presented here of a damped train of regular pulses from the Sun appear much simpler than other similar events previously described. The interpretations so far proposed for such phenomena do not adequately explain the asymmetry observed in this case.Radiophysics Publication RPP 1645, March, 1973.     

Spectroscopic Study of a Large Sample of Galaxies Discovered in the Second Byurakan Survey Fields

The Second Byurakan Survey (SBS) is a well known combined survey, which uses the presence of UV-excess radiation in the continuum, or the presence of emission-lines in the spectra for the identification of active and star-forming galaxies. This paper reports on a comparative study of 77 galaxies identified with UV-excess, and 34 galaxies identified via emission-line techniques in the fields of the SBS. The spectroscopic parameters used for the comparison are the [OII]3727/H and [OIII]5007/H emission-lines ratios, the equivalent widths of [OII]3727, [OIII]5007 and H emission-lines, and the C _[OII]-C _H index. Spectroscopic parameters as well as new redshifts were determined from the spectra obtained with the 6m telescope of the Special Astrophysical Observatory (Russia). The main results are: 1) Galaxies discovered via UV-excess technique are preferably more active. 2) Galaxies discovered via emission-line technique are preferably high-excitation low-luminosity star-forming galaxies. 3) UV-excess galaxies with faintest UV-excess radiation are likely candidates to be LINER or Sy2 type objects.     

Changes in an urban water resource,an example from Sydney,Australia

This paper examines present and future resource utilization in the tidal section of the Georges River in the southern part of Sydney. Over the last 30 years, the physical characteristics of the river have changed as a result of urbanization, changed hydrologic regime and sand dredging. Urbanization has resulted in an increase in population from 190,000 in 1947 to 550,000. This has resulted in an increase in runoff, sediment input to the river and waste disposal. The change in hydrologic regime has resulted in a substantial increase in the magnitude and frequency of flooding which has increased erosion. Sand dredging has increased the channel capacity, enlarged the tidal prism and increased water turbidity. It has also resulted in extensive bank erosion in the upper part of the river and extensive deposition lower down as tailings are deposited. Although most of these changes have resulted in the deterioration of environmental quality, use of the river for recreation and as an urban amenity has increased.