Quantitative Analysis of Micro-structural Changes in a Bituminous Coal After Exposure to Supercritical CO2 and Water

Natural Resources Research - High-volatile bituminous coal samples were reacted in deionized water with supercritical CO2 (ScCO2–water) under simulated in situ pressure and temperature...     

Mining and spoiled land in Zambia: An example of conflicting land use in the third world

Mining of copper and other metals to a lesser extent is the mainstay of the Zambian economy. Copper is mined in the Copperbelt situated in the northern part of the country. It is not only the the most thickly populated part of the country but also the most urbanized. Urban centers developed with the mines as their nuclei and hence pose spatial problems between the needs of a rapidly increasing population on the one hand and the requirements of the mining industry on the other. The provision of raw material for the extractive industries is a geological one. Economic history shows the realization of these potentials and thirdly, lack of planning has permitted exploitation of minerals and dumping of wastes without much regard to reclamation. Spoilation of land by mining activity is mainly caused by the methods of mining as well as by the dumping of the solid and liquid wastes from the ore crushers and concentrators; while air pollution from sulphurdioxide and dust is from the smelters. Legislation has recently being enacted to regulate the dumping of wastes and for the reclamation of waste dumps. However, this has had only a minimal effect on the problem as yet. The soil from a dump which is ready for reclamation is analysed and methods of revegetating such a dump based on ecological principles is attempted. Finally, the conflict for land between the needs of a growing urban population and the requirements of the mining industry is discussed taking Kitwe, the capital of the Copperbelt as an example.     

What governs the presence of residual vegetation in boreal wildfires?

Wildfires are frequent boreal forest disturbances in Canada, and emulating their patterns with forest harvesting has emerged as a common forest management goal. Wildfires contain many patches of residual vegetation of various size, shape, and composition; understanding their characteristics provides insights for improved emulation criteria. We studied the occurrence of residual vegetation within eleven boreal wildfire events in a natural setting; fires ignited by lightning, no suppression efforts, and no prior anthropogenic disturbances. Relative importance of the measurable geo-environmental factors and their marginal effects on residual presence are studied using Random Forests. These factors included distance from natural firebreaks (wetland, bedrock and non-vegetated areas, and water), land cover, and topographic variables (elevation, slope, and ruggedness index). We present results at spatial resolutions ranging from four to 64 m while emphasizing four and 32 m since they mimic IKONOS- and Landsat-type images. Natural firebreak features, especially the proximity to wetlands, are among the most important variables that explain the likelihood residual occurrence. The majority of residual vegetation areas are concentrated within 100 m of wetlands. Topographic variables, typically important in rugged terrain, are less important in explaining the presence of residuals within our study fires.     

AzTEC millimetre survey of the COSMOS field – I. Data reduction and source catalogue

We present a 1.1 mm wavelength imaging survey covering 0.3 deg² in the COSMOS field. These data, obtained with the AzTEC continuum camera on the James Clerk Maxwell Telescope, were centred on a prominent large-scale structure overdensity which includes a rich X-ray cluster at z ≈ 0.73. A total of 50 mm-galaxy candidates, with a significance ranging from 3.5 to 8.5σ, are extracted from the central 0.15 deg² area which has a uniform sensitivity of ∼1.3 mJy beam⁻¹. 16 sources are detected with S/N ≥ 4.5, where the expected false-detection rate is zero, of which a surprisingly large number (9) have intrinsic (deboosted) fluxes ≥5 mJy at 1.1 mm. Assuming the emission is dominated by radiation from dust, heated by a massive population of young, optically obscured stars, then these bright AzTEC sources have far-infrared luminosities  >6 × 10¹² L_⊙  and star formation rates  >1100 M_⊙ yr⁻¹  . Two of these nine bright AzTEC sources are found towards the extreme peripheral region of the X-ray cluster, whilst the remainder are distributed across the larger scale overdensity. We describe the AzTEC data reduction pipeline, the source-extraction algorithm, and the characterization of the source catalogue, including the completeness, flux deboosting correction, false-detection rate and the source positional uncertainty, through an extensive set of Monte Carlo simulations. We conclude with a preliminary comparison, via a stacked analysis, of the overlapping MIPS 24-μm data and radio data with this AzTEC map of the COSMOS field.     

Shale gas fracturing using foam-based fracturing fluid: a review

World energy resources are depleting at an alarming rate, and natural gas has been identified as an environmentally friendly energy resource, with shale gas being one option. However, the extremely low permeability of shale plays has caused them to fail to produce a commercially viable amount of gas. Therefore, appropriate production enhancement techniques, including hydro-fracturing, are required. This paper reviews the research on shale gas production enhancement using foam-based hydro-fracturing and focuses on research on shale deposit distribution around the world, the importance of shale gas recovery, major shale gas recovery enhancement techniques, the effectiveness of foam-based fracturing depending on the foam type used and the formation properties, advantages and limitations of foam-based fracturing compared to other fluids, and existing experimental and numerical studies and field studies. According to the available experimental and modelling studies on foam fracturing, N₂-based foams are stronger than CO₂-based foams. The effective viscosity that controls the foam rheology decreases with increasing temperature and decreasing pressure and foam quality, and fracture length reduces and fracture width increases with increasing foam quality. Although this technique has been tested in few shale plays worldwide, most studies have been performed in the USA and Canada. Therefore, the foam fracturing technique is still comparatively novel for other countries around the world.     

A review of coal properties pertinent to carbon dioxide sequestration in coal seams: with special reference to Victorian brown coals

This paper presents reviews of studies on properties of coal pertinent to carbon dioxide (CO₂) sequestration in coal with specific reference to Victorian brown coals. The coal basins in Victoria, Australia have been identified as one of the largest brown coal resources in the world and so far few studies have been conducted on CO₂ sequestration in this particular type of coals. The feasibility of CO₂ sequestration depends on three main factors: (1) coal mass properties (chemical, physical and microscopic properties), (2) seam permeability, and (3) gas sorption properties of the coal. Firstly, the coal mass properties of Victorian brown coal are presented, and then the general variations of the coal mass properties with rank, for all types of coal, are discussed. Subsequently, coal gas permeability and gas sorption are considered, and the physical factors which affect them are examined. In addition, existing models for coal gas permeability and gas sorption in coal are reviewed and the possibilities of further development of these models are discussed. According to the previous studies, coal mass properties and permeability and gas sorption characteristics of coals are different for different ranks: lignite to medium volatile bituminous coals and medium volatile bituminous to anthracite coals. This is important for the development of mathematical models for gas permeability and sorption behavior. Furthermore, the models have to take into account volume effect which can be significant under high pressure and temperature conditions. Also, the viscosity and density of supercritical CO₂ close to the critical point can undergo large and rapid changes. To date, few studies have been conducted on CO₂ sequestration in Victorian brown coal, and for all types of coal, very few studies have been conducted on CO₂ sequestration under high pressure and temperature conditions.     

Status of two <Emphasis Type="Italic">Coreius</Emphasis> species in the Three Gorges Reservoir,China

Dam construction alters natural flow regimes which, in turn, cause significant changes in fish communities during and after impoundment. The construction of the Three Gorges Reservoir, from impoundment of the Changjiang (Yangtze) River, China, may have affected native fish species. Thus, the status of two lotic freshwater fish species, Coreius heterodon and C. guichenoti, were monitored in the Three Gorges Reservoir, including fish abundance, individual composition, growth, condition, and mortality. Data on both species were gathered from upstream, midstream and downstream areas of the reservoir and, where available, from studies published before and after dam construction. Lower abundance, slower growth, a less diversified age structure, poorer fish condition (indicated by hepatosomatic index) and higher mortalities were recorded in sites nearest the dam compared with upstream areas. Furthermore, after final impoundment, individual Coreius species inhabiting the area changed, with young individuals becoming more abundant, while upstream of the reservoir the two Coreius species became smaller at a given age. The results show that the status of the two Coreius species was subject to dramatic changes after impoundment.     

Artificial Fracture Stimulation of Rock Subjected to Large Isotropic Confining Stresses in Saline Environments: Application in Deep-Sea Gas Hydrate Recovery

Natural Resources Research - The low permeability of gas hydrate deposits leads to poor extraction rates. Artificial fracture stimulation could significantly improve the recovery rate of an...     

The effect of truck traffic and road water content on sediment delivery from unpaved forest roads

A study investigated the effect of truck‐traffic intensity and road water‐content on the quality of runoff water from unsealed forest roads. Three sections of a gravel‐surfaced forest road were instrumented and exposed to low and high levels of truck traffic during wet winter conditions and dry summer conditions between July 2001 and December 2002. Rainfall, runoff, road moisture, and traffic were measured continuously, and suspended and bedload sediments were integrated measurements over 2‐week site‐service intervals. The median suspended sediment concentration from the three road segments under low truck‐traffic conditions (less than nine return truck passes prior to a storm) was 269 mg l^?1, increasing 2·7‐fold to a median of 725 mg l^?1 under high truck‐traffic conditions (greater than or equal to nine return truck passes prior to a storm). These concentrations, and increases due to traffic, are substantially less than most previously reported values. When these data are expressed as modified universal soil loss equation (MUSLE) erodibility values K, accounting for differences in rainfall energy, site characteristics and runoff, high traffic resulted in a road surface that was four times more erodible than the same road under low traffic conditions. Using multiple regression, traffic explained 36% of the variation in MUSLE erodibility, whereas road water content was not significant in the model. There was little difference in the erodibility of the road when trafficked in low water‐content compared with high water‐content conditions (MUSLE K values of 0·0084 versus 0·0080 respectively). This study shows that, for a good quality well‐maintained gravel forest road, the level of truck traffic affects the sediment concentration of water discharging from the road, whereas the water content of the road at the time of that traffic does not (note that traffic is not allowed during runoff events in Victoria). These conclusions are conditional upon the road being adequately maintained so that trafficking does not compromise the lateral drainage of the road profile. Copyright © 2005 John Wiley & Sons, Ltd.     

The AzTEC mm-wavelength camera

AzTEC is a mm-wavelength bolometric camera utilizing 144 silicon nitride micromesh detectors. Here, we describe the AzTEC instrument architecture and its use as an astronomical instrument. We report on several performance metrics measured during a three-month observing campaign at the James Clerk Maxwell Telescope and conclude with our plans for AzTEC as a facility instrument on the Large Millimetre Telescope.