Magnesium and strontium isotope signatures were determined during different seasons for the main rivers of the Moselle basin, northeastern France. This small basin is remarkable for its well-constrained and varied lithology on a small distance scale, and this is reflected in river water Sr isotope compositions. Upstream, where the Moselle River drains silicate rocks of the Vosges mountains, waters are characterized by relatively high 87Sr/86Sr ratios (0.7128-0.7174). In contrast, downstream of the city of Epinal where the Moselle River flows through carbonates and evaporites of the Lorraine plateau, 87Sr/86Sr ratios are lower, down to 0.70824.Magnesium in river waters draining silicates is systematically depleted in heavy isotopes (δ26Mg values range from −1.2 to −0.7‰) relative to the value presently estimated for the continental crust and a local diorite (−0.5‰). In comparison, δ26Mg values measured in soil samples are higher (∼0.0‰). This suggests that Mg isotope fractionation occurs during mineral leaching and/or formation of secondary clay minerals. On the Lorraine plateau, tributaries draining marls, carbonates and evaporites are characterized by low Ca/Mg (1.5-3.2) and low Ca/Sr (80-400) when compared to local carbonate rocks (Ca/Mg = 29-59; Ca/Sr = 370-2200), similar to other rivers draining carbonates. The most likely cause of the Mg and Sr excesses in these rivers is early thermodynamic saturation of groundwater with calcite relative to magnesite and strontianite as groundwater chemistry progressively evolves in the aquifer. δ26Mg of the dissolved phases of tributaries draining mainly carbonates and evaporites are relatively low and constant throughout the year (from −1.4‰ to −1.6‰ and from −1.2‰ to −1.4‰, respectively), within the range defined for the underlying rocks. Downstream of Epinal, the compositions of the Moselle River samples in a δ26Mg vs. 87Sr/86Sr diagram can be explained by mixing curves between silicate, carbonate and evaporite waters, with a significant contribution from the Vosgian silicate lithologies (>70%). Temporal co-variation between δ26Mg and 87Sr/86Sr for the Moselle River throughout year is also observed, and is consistent with a higher contribution from the Vosges mountains in winter, in terms of runoff and dissolved element flux. Overall, this study shows that Mg isotopes measured in waters, rocks and soils, coupled with other tracers such as Sr isotopes, could be used to better constrain riverine Mg sources, particularly if analytical uncertainties in Mg isotope measurements can be improved in order to perform more precise quantifications. 相似文献
This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis. 相似文献
Seismic wavefield scattering from a statistically randomly rough interface in a multilayered piecewise homogeneous medium is studied in 3D. The influence of the surface roughness on the scattered wavefield is analysed numerically by using a finite‐difference operator in the acoustic domain. Since interface scattering in the real practical sense is a 3D physical phenomenon, we show in this work that the scattering response of a randomly rough interface is not the same in 3D situations as in the 2D cases described in some earlier works. For a given interface roughness height in 3D, an interface roughness height at least three times greater is required to produce an equivalent phase scattering effect in 2D situations, for a given correlation length of the interface roughness scale. Based on observations from spectral analysis, we show that scattering results principally in de‐phasing and frequency band‐limiting of the incident wavefront, the frequency band‐limiting properties being comparable to cases reported in the literature for absorption and thin‐layer filtering. The interface scattering phenomenon should be critically considered when using amplitude and phase information from seismic signal during inversion processes. 相似文献
Surveys carried out in mountainous areas of northern Vietnam at research sites selected across a gradient of market integration, revealed strong relationships between the location of the village with respect to the national road network and the nature of its land-use systems, its poverty level and more generally its potential for development. We developed and tested in Bac Kan province a method to give an objective and quantitative definition of accessibility over a large geographic area. Accessibility maps integrated in a provincial GIS showed that despite recent improvements to the road network, some remote areas do not benefit from recent development. 相似文献
The withdrawal of the Aral Sea tributaries (Amu and Syr Daria) for cultures has led to significant falls of its level and an important increase in its salinity. During the Holocene, a succession of low and high water inputs occurred. Silty deposits correspond to the high levels and carbonates to the low levels. This study makes a distinction between the Syr Daria and the Amu Daria water inputs during low-level periods by using mineralogical and chemical compositions of the carbonates deposits. Waters from the Syr Daria are more sulphatic and have a low iron content in comparison with that of the Amu Daria. The Syr Daria was the major tributary around 7500, 4956 and 970 yr?BP, whereas around 6200 and 3610 yr?BP, inflow also from the Amu Daria is observed. To cite this article: L. Le Callonnec et al., C. R. Geoscience 337 (2005).相似文献
The turbulent exchange of momentum between a two-dimensional cavity and the overlying boundary layer has been studied experimentally,
using hot-wire anemometry and particle image velocimetry (PIV). Conditions within the boundary layer were varied by changing
the width of the canyons upstream of the test canyon, whilst maintaining the square geometry of the test canyon. The results
show that turbulent transfer is due to the coupling between the instabilities generated in the shear layer above the canyons
and the turbulent structures in the oncoming boundary layer. As a result, there is no single, unique velocity scale that correctly
characterizes all the processes involved in the turbulent exchange of momentum across the boundary layer. Similarly, there
is no single velocity scale that can characterize the different properties of the turbulent flow within the canyon, which
depends strongly on the way in which turbulence from the outer flow is entrained into the cavity and carried round by the
mean flow. The results from this study will be useful in developing simple parametrizations for momentum exchange in the urban
canopy, in situations where the street geometry consists principally of relatively long, uniform streets arranged in grid-like
patterns; they are unlikely to be applicable to sparse geometries composed of isolated three-dimensional obstacles. 相似文献
The ODP leg 161 Site 976 (Alboran Sea) is a deep-sea section sampled at a water depth of 1108 m in the Western Mediterranean Sea. Pollen analysis provides a vegetation and climate record of the Mid Pleistocene Transition (MPT), roughly one million years ago. The age-model tied to biostratigraphic events was revised by aligning the pollen climate index (PCI) to Mediterranean (KC01b) and global (LR04) oxygen isotope records. The studied time slice spans the interval ~1.09 Ma (MIS 31) to ~0.90 Ma (MIS 23).Across this interval, past phytogeography of nowadays extinct taxa, which were rare, allows a successful application of the modern analogues technique (MAT) to quantitative climate reconstructions for the MPT. Five, long-term, obliquity-related vegetation successions (O1 to O5), and eight short-term, precession-related vegetation successions (P1 to P8) are observed within the studied interval. These vegetation successions, regardless of their duration, show the same pattern: the progressive replacement of temperate trees by mountainous taxa, and then by herbs and steppe maxima. Precession-related successions correspond, therefore, to as dramatic vegetation changes as those driven by obliquity, including a final steppe phase under deteriorated climate conditions.Wavelet analysis of the PCI record shows that the Western Mediterranean experienced a shift at 1.01 Ma from precession-dominated frequencies (1.05–1.01 Ma) to obliquity-dominated frequencies (1.01–0.9 Ma). There is, therefore, an apparent discrepancy between wavelet analysis results and vegetation dynamic analysis (which suggests that obliquity and precession are recorded throughout the entire studied interval). This discrepancy could result from the fact that the PCI record sums, somehow, similar vegetation changes (wet to dry) occurring at different periodicities. Such a complex vegetation dynamics is mathematically rendered through a single parameter (i.e. principal component), which does not successfully catch the subtle combinations of variability occurring at two close periodicities. Furthermore, the pollen-inferred Early Pleistocene vegetation dynamic (and climate) of the Western Mediterranean region does not show a decrease of the obliquity response relative to the precession response at the onset of the MPT. 相似文献
In this paper, we develop and apply a multi-dimensional vulnerability assessment framework for understanding the impacts of climate change-induced hazards in Sub-Saharan African cities. The research was carried out within the European/African FP7 project CLimate change and Urban Vulnerability in Africa, which investigated climate change-induced risks, assessed vulnerability and proposed policy initiatives in five African cities. Dar es Salaam (Tanzania) was used as a main case with a particular focus on urban flooding. The multi-dimensional assessment covered the physical, institutional, attitudinal and asset factors influencing urban vulnerability. Multiple methods were applied to cover the full range of vulnerabilities and to identify potential response strategies, including: model-based forecasts, spatial analyses, document studies, interviews and stakeholder workshops. We demonstrate the potential of the approach to assessing several dimensions of vulnerability and illustrate the complexity of urban vulnerability at different scales: households (e.g., lacking assets); communities (e.g., situated in low-lying areas, lacking urban services and green areas); and entire cities (e.g., facing encroachment on green and flood-prone land). Scenario modeling suggests that vulnerability will continue to increase strongly due to the expected loss of agricultural land at the urban fringes and loss of green space within the city. However, weak institutional commitment and capacity limit the potential for strategic coordination and action. To better adapt to urban flooding and thereby reduce vulnerability and build resilience, we suggest working across dimensions and scales, integrating climate change issues in city-level plans and strategies and enabling local actions to initiate a ‘learning-by-doing’ process of adaptation. 相似文献
Pre-compacted MX80 bentonite/Callovo-Oxfordian (COx) claystone mixture has been proposed to backfill and seal the underground galleries for radioactive waste disposal in France. While emplacing these pre-compacted blocks, technological voids are created between the blocks and the host rock and among the blocks themselves. It is expected that homogenization process will take place over time for the structure constructed with pre-compacted blocks upon hydration. This study investigated the boundary friction effect on such a process. Results showed that after the filling of technological voids, the soil far from the technological voids would swell further, while those near the voids would be compressed under the welling pressure generated by the soil behind, resulting in an increase in homogeneity in terms of dry density distribution. However, this homogenization process would stop after a certain time. Further examination showed that the homogenization process ended when the maximum boundary friction force became equal to or higher than the vector sum of swelling forces in the radial direction. Based on the force equilibrium and the mass conservation, the final dry density distribution was estimated. Comparison between the estimation and the measurement showed a good agreement, indicating the relevance of the identified mechanism related to boundary friction.