Variation of δ18O, δD and 3H in karst springs of south Kashmir,western Himalayas (India)

Water samples were collected from cold and warm karst springs for stable isotopes (δ¹⁸O and δD) and ³H from SE of Kashmir valley (western Himalayas) to distinguish the sources of recharge and infer their recharge areas. The spring water samples were most depleted in heavier isotopes in May (average δ¹⁸O: ?8.87‰ and δD: ?50.3‰) and enriched in September (average δ¹⁸O: ?7.58‰ and δD: ?48.1‰). The depleted ¹⁸O and ²H of spring waters bear the signatures of winter precipitation while as the enriched ¹⁸O and ²H of spring waters bear the signature of summer rainfall. D‐excess and ³H corroborate with the stable isotope results that the spring flow in spring season (May) and autumn (September) is dominantly controlled by the melting of winter snowmelt and summer rainfall, respectively. The results showed that unlike δD, the δ¹⁸O value in the karst spring waters decreases in January suggesting δ¹⁸O shift. The spring water samples also fall above the Local Meteoric Water Line and Global Meteoric Water Line indicating the δ¹⁸O shift due to interaction of groundwater with the host carbonate rocks during its traverse. The mean elevation of the recharge areas of the springs using δ¹⁸O and δD tracers was also estimated. Copyright © 2014 John Wiley & Sons, Ltd.     

Sorption of lead by chemically modified rice bran

In this work, the effectiveness of native and chemically modified rice bran to remove heavy metal Pb(II) ions from aqueous solution was examined. Chemical modifications with some simple and low-cost chemicals resulted in enhancement of the adsorption capacities and had faster kinetics than native rice bran. Experiments were conducted in shake flasks to monitor the upshot of parameters over a range of pH, initial Pb(II) concentrations and contact times using a batch model study. The sorption capacities q (mg g^?1) increased in the following order: NaOH (147.78), Ca(OH)₂ (139.08), Al(OH)₃ (127.24), esterification (124.28), NaHCO₃ (118.08), methylation (118.88), Na₂CO₃ (117.12) and native (80.24). The utmost uptake capacity q (mg g^?1) was shown by NaOH-pretreated rice bran. The results showed that, using NaOH-modified rice bran, the chief removal of Pb(II) was 74.54 % at pH 5, primary Pb(II) concentration 100 mg L^?1 and contact time 240 min. Equilibrium isotherms for the Pb(II) adsorption were analyzed by Langmuir and Freundlich isotherm models. The Langmuir isotherm model, showing Pb(II) sorption as accessible through the high value of the correlation coefficient (R ² = 0.993), showed a q _max value of 416.61 mg g^?1. The kinetic model illustrated adsorption rates well, depicted by a second order, which gives an indication concerning the rate-limiting step. Thermodynamic evaluation of the metal ion ?G ^o was carried out and led to the observation that the adsorption reaction is spontaneous and endothermic in nature. NaOH chemically modified rice bran was a superb biosorbent for exclusion of Pb(II) and proved to be excellent for industrial applications.     

Sensitivity studies of high-resolution RegCM3 simulations of precipitation over the European Alps: the effect of lateral boundary conditions and domain size

A suite of high-resolution (10 km) simulations were performed with the International Centre for Theoretical Physics (ICTP) Regional Climate Model (RegCM3) to study the effect of various lateral boundary conditions (LBCs), domain size, and intermediate domains on simulated precipitation over the Great Alpine Region. The boundary conditions used were ECMWF ERA-Interim Reanalysis with grid spacing 0.75^°, the ECMWF ERA-40 Reanalysis with grid spacing 1.125 and 2.5^°, and finally the 2.5^° NCEP/DOE AMIP-II Reanalysis. The model was run in one-way nesting mode with direct nesting of the high-resolution RCM (horizontal grid spacing Δx = 10 km) with driving reanalysis, with one intermediate resolution nest (Δx = 30 km) between high-resolution RCM and reanalysis forcings, and also with two intermediate resolution nests (Δx = 90 km and Δx = 30 km) for simulations forced with LBC of resolution 2.5^°. Additionally, the impact of domain size was investigated. The results of multiple simulations were evaluated using different analysis techniques, e.g., Taylor diagram and a newly defined useful statistical parameter, called Skill-Score, for evaluation of daily precipitation simulated by the model. It has been found that domain size has the major impact on the results, while different resolution and versions of LBCs, e.g., 1.125^° ERA40 and 0.7^° ERA-Interim, do not produce significantly different results. It is also noticed that direct nesting with reasonable domain size, seems to be the most adequate method for reproducing precipitation over complex terrain, while introducing intermediate resolution nests seems to deteriorate the results.     

Field testing of robotic technologies to support ground ice prospecting in martian polygonal terrain

Polygonal terrain, a landform commonly associated with the presence of ground ice, is widespread throughout the high latitudes on Mars. In this paper, we present the results of field testing a potential mission concept for the robotic prospecting of ground ice in polygonal terrain. The focus of the paper is on the key robotic technologies that could be used to implement the concept and the engineering lessons we learned (as opposed to the specific scientific findings of our field tests). In particular, we have found that a lander- or rover-mounted lidar and a rover-borne stereo camera/ground-penetrating radar suite are two important scientific tools that may be used to help pin-point ground ice prior to subsurface sampling. We field tested some aspects of this mission concept on a previously - unstudied polygonal terrain site on Devon Island in the Canadian High Arctic (a common Mars/Moon analogue site) during the summer of 2008. This unique collaboration between technological and scientific communities has led to a deeper understanding of how such a science-driven mission could actually be implemented robotically.     

Hydrogeochemical characterization and groundwater quality assessment in Al-Hasa,Saudi Arabia

Fifty groundwater samples were collected from Al-Hasa to analyze the pH, electrical conductivity (EC, dS m^?1), total dissolved solids (TDS), major anions (HCO₃^?, CO₃^2?, Cl^?, SO₄^2?, and NO₃^?), major cations (Ca²⁺, Mg²⁺, Na⁺, and K⁺), and total hardness. The analyzed data plotted in the Piper, Gibbs, and Durov diagrams, and water quality index (WQI) were calculated to evaluate the groundwater geochemistry and its water quality. The results reveal that most of the investigated samples are Ca²⁺, Mg²⁺, SO₄^2?, Cl^? and Na⁺, and HCO₃^? water types using the Piper diagram. Na⁺?>?Ca²⁺?>?Mg²⁺ are the dominant cations, while Cl^??>?HCO₃^??>?SO₄^2??>?CO₃^2? are the dominant anions. Sodium adsorption ratio (SAR) values varied from 0.79 to 10; however, the Kelly ratio (KR) ranged between 0.1 and 2.2. The permeability index (PI) showed that well water is suitable for irrigation purposes with 75% or more of maximum permeability. The US salinity diagram revealed that the water quality classes of studied waters were CIII-SI, CIII-SII, and CIV-SII, representing height hazards of salinity and medium- to low-sodium hazard. The water quality index (WQI) results indicated that total dissolved solids are out of the drinking water standard limits in Saudi Arabia. The WQI revealed that 38% of the studied wells were considered as poor water (class III), 52% are found as very poor water class (IV), and 10% are unsuitable water for drinking class (V).     

Quantification of groundwater–surface water interactions using environmental isotopes: A case study of Bringi Watershed,Kashmir Himalayas,India

Environmental isotopes including \({\updelta }^{18}\)O, \({\updelta }^{2}\)H and \(^{3}\)H of precipitation, streams and springs were determined in the mountainous Bringi catchment of Kashmir Himalaya, dominated by carbonate lithology. The isotopic signature of winter precipitation is reflected in stream and spring water in late spring and is, therefore, representative of snow melting. The spring waters in September bear the enriched isotopic signatures of summer rainfall. The strong correlation (\(r^{2} = 0.97\)) between the isotopic composition of streams and springs indicates the streams and springs either share similar catchments or the springs are recharged by the streams. Chloride mass balance and isotopic mass balance studies suggest that the surface recharge component averages 337.35 m\(^{3}\)/s, which is about 75% of total stream discharge during the high flow period. Similarly, the contribution of surface water to groundwater recharge during the low flow period averages 7.5 m\(^{3}\)/s, which is about 18.6% of total stream flow. Furthermore, the mean residence time of the springs calculated from the tritium decay equation is very short (<1 year). The residence time is longer for Kongamnag and short for Achabalnag, which is further supported by dye testing.     

Assessment of MTBE biodegradation in contaminated groundwater using C and C analysis: Field and laboratory microcosm studies

Radiolabelled assays and compound-specific stable isotope analysis (CSIA) were used to assess methyl tert-butyl ether (MTBE) biodegradation in an unleaded fuel plume in a UK chalk aquifer, both in the field and in laboratory microcosm experiments. The ¹⁴C-MTBE radiorespirometry studies demonstrated widespread potential for aerobic and anaerobic MTBE biodegradation in the aquifer. However, δ¹³C compositions of MTBE in groundwater samples from the plume showed no significant ¹³C enrichment that would indicate MTBE biodegradation at the field scale. Carbon isotope enrichment during MTBE biodegradation was assessed in the microcosms when dissolved O₂ was not limiting, compared with low in situ concentrations (2 mg/L) in the aquifer, and in the absence of O₂. The microcosm experiments showed ubiquitous potential for aerobic MTBE biodegradation in the aquifer within hundreds of days. Aerobic MTBE biodegradation in the microcosms produced an enrichment of 7‰ in the MTBE δ¹³C composition and an isotope enrichment factor (ε) of −1.53‰ when dissolved O₂ was not limiting. However, for the low dissolved O₂ concentration of up to 2 mg/L that characterizes most of the MTBE plume fringe, aerobic MTBE biodegradation produced an enrichment of 0.5-0.7‰, corresponding to an ε value of −0.22‰ to −0.24‰. No anaerobic MTBE biodegradation occurred under these experimental conditions. These results suggest the existence of a complex MTBE-biodegrading community in the aquifer, which may consist of different aerobic species competing for MTBE and dissolved O₂. Under low O₂ conditions, the lower fractionating species have been shown to govern overall MTBE C-isotope fractionation during biodegradation, confirming the results of previous laboratory experiments mixing pure cultures. This implies that significant aerobic MTBE biodegradation could occur under the low dissolved O₂ concentration that typifies the reactive fringe zone of MTBE plumes, without producing detectable changes in the MTBE δ¹³C composition. This observed insensitivity of C isotope enrichment to MTBE biodegradation could lead to significant underestimation of aerobic MTBE biodegradation at field scale, with an unnecessarily pessimistic performance assessment for natural attenuation. Site-specific C isotope enrichment factors are, therefore, required to reliably quantify MTBE biodegradation, which may limit CSIA as a tool for the in situ assessment of MTBE biodegradation in groundwater using only C isotopes.     

Extraction and validation of cartosat-1 DEM

CARTOSAT-1 satellite, launched in May, 2005 is a dedicated along track stereo mission providing high quality data for topographic and cartographic applications. The present paper describes the evaluation of the Cartosat-1 stereo data, mainly through the generation and validation of DEM for moderately undulating and hilly areas. Photogrammetric techniques have been used for generation of DEM and Orthoimage for two cases i.e. 1) using RPCs (Rational Polynomial Coefficients) and 2) using RPCs along with ground control points. Root Mean Square Error (RMSE) in elevation values for the moderately undulating (Dehradun) and hilly area (Shimla), are found to be 4.38 and 3.69m respectively.