The Fe-C system at 5 GPa and implications for Earth’s core

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.     

Platinum group element geochemistry of komatiites from the Alexo and Pyke Hill areas, Ontario, Canada

Thirty-three whole-rock drill core samples and thirteen olivine, chromite, and sulfide separates from three differentiated komatiite lava flows at Alexo and Pyke Hill, Canada, were analyzed for PGEs using the Carius tube digestion ID-ICP-MS technique. The emplaced lavas are Al-undepleted komatiites with ∼27% MgO derived by ∼50% partial melting of LILE-depleted Archean mantle. Major and minor element variations during and after emplacement were controlled by 30 to 50% fractionation of olivine Fo_93-94. The emplaced lavas are characterized by (Pd/Ir)_N = 4.0 to 4.6, (Os/Ir)_N = 1.07, and Os abundances of ∼2.3 ppb. Variations in PGE abundances within individual flows indicate that Os and Ir were compatible (bulk D_Os,Ir = 2.4-7.1) and that Pt and Pd were incompatible (bulk D_Pt,Pd < 0.2) during lava differentiation, whereas bulk D_Ru was close to unity. Analyses of cumulus olivine separates indicate that PGEs were incompatible in olivine (D_PGEs^Ol-Liq = 0.04-0.7). The bulk fractionation trends cannot be accounted for by fractionation of olivine alone, and require an unidentified Os-Ir-rich phase. The composition of the mantle source (Os = 3.9 ppb, Ir = 3.6 ppb, Ru = 5.4 ppb, Pt and Pd = 5.7 ppb) was constrained empirically for Ru, Pt, and Pd; the Os/Ir ratio was taken to be identical to that in the emplaced melt, and the Ru/Ir ratio was taken to be chondritic, so that the absolute IPGE abundances of the source were determined by Ru. This is the first estimate of the PGE composition of a mantle source derived from analyses of erupted lavas. The suprachondritic Pd/Ir and Os/Ir of the inferred Abitibi komatiite mantle source are similar to those in off-craton spinel lherzolites, orogenic massif lherzolites, and enstatite chondrites, and are considered to be an intrinsic mantle feature. Bulk partition coefficients for use in komatiite melting models derived from the source and emplaced melt compositions are: D_Os,Ir = 2.3, D_Ru = 1.0, D_Pt,Pd = 0.07. Ruthenium abundances are good indicators of absolute IPGE abundances in the mantle sources of komatiite melts with 26 to 29% MgO, as Ru fractionates very little during both high degrees of partial melting and lava differentiation.     

Highly siderophile element geochemistry of Os-enriched 2.8 Ga Kostomuksha komatiites, Baltic Shield

New analyses of highly siderophile elements (HSE; Re, Os, Ir, Ru, Pt, and Pd) obtained by Carius tube digestion isotope dilution inductively coupled plasma mass-spectrometry (ID-ICPMS) technique are reported for ¹⁸⁷Os-enriched 2.8 Ga komatiites from the Kostomuksha greenstone belt. As a result of a significant improvement in the yield over our previous digestions by the NiS fire-assay technique, these komatiites have now been shown to contain 22 to 25% more Os, Ir, and Pt and 34% more Ru. The emplaced komatiite lavas at Kostomuksha thus had siderophile element abundances comparable to those of the Abitibi belt. The discrepancies observed between the two techniques are interpreted to be the result of incomplete digestion of HSE carriers (particularly chromite) during the NiS fire-assay procedure. Our results for UB-N peridotite reference material agree well with those obtained by the high-pressure ashing digestion ID-ICPMS technique reported in the literature. Two types of komatiite lavas have been distinguished in this study based on the IPGE (Os, Ir, and Ru) behavior during lava differentiation. The Kostomuksha type is unique and is characterized by an incompatible behavior of IPGEs, with bulk solid-liquid partition coefficients for IPGEs being close to those for olivine. Cumulate zones in this type of komatiite lava occupy <20% of the total thickness of the flows. The Munro type exhibits a compatible behavior of IPGEs during lava differentiation. The cumulate zone in this type of komatiite occupies >20% of the total thickness of the flows. The calculated bulk partition coefficients indicate that, as with the other Munro-type komatiite lavas, the bulk cumulate contained an IPGE-rich minor phase(s) in addition to olivine. The non-CI chondritic HSE pattern for the source of the Kostomuksha komatiites calculated here is similar to that of Abitibi komatiites and to average depleted spinel lherzolite (ADSL) and supports the hypothesis of a non-CI chondritic HSE composition of the Earth’s mantle. The absolute HSE abundances in the source of the Kostomuksha komatiite have been demonstrated to be comparable to those of the source of Abitibi komatiites, even though the two komatiites contrast in their Os isotopic compositions. This supports the earlier hypothesis that if core-mantle interaction produced the ¹⁸⁷Os/¹⁸⁸Os radiogenic signature in the Kostomuksha source, it must have occurred in the form of isotope exchange at the core-mantle boundary. Other explanations of the radiogenic Os signature are similarly constrained to conserve the elemental abundance pattern in the mantle source of Kostomuksha komatiites.     

Compositions of group IVB iron meteorites and their parent melt

The concentrations of P, V, Cr, Fe, Co, Ni, Cu, Ga, Ge, As, Mo, Ru, Rh, Pd, W, Re, Os, Ir, Pt, and Au in the group IVB iron meteorites Cape of Good Hope, Hoba, Skookum, Santa Clara, Tawallah Valley, Tlacotepec, and Warburton Range have been measured by laser ablation inductively coupled plasma mass spectrometry. The data were fitted to a model of fractional crystallization of the IVB parent body core, from which the composition of the parent melt and metal/melt distribution coefficients for each element in the system were determined, for a chosen value of D(Ni). Relative to Ni and chondritic abundances, the parent melt was enriched in refractory siderophiles, with greatest enrichment of 5× chondritic in the most refractory elements, and was strongly volatile-depleted, down to 0.00014× chondritic in Ge. Comparison to an equilibrium condensation sequence from a gas of solar composition indicates that no single temperature satisfactorily explains the volatility trend in the IVB parent melt; a small (<1%) complement of ultrarefractory components added to metal that is volatile-depleted but otherwise has nearly chondritic abundances (for Fe, Co and Ni) best explains the volatility trend. In addition to this volatility processing, which probably occurred in a nebular setting, there was substantial oxidation of the metal in the IVB parent body, leading to loss of Fe and other moderately siderophile elements such as Cr, Ga, and W, and producing the high Ni contents that are observed in the IVB irons. By assuming that the entire IVB parent body underwent a similar chemical history as its core, the composition of the silicate that is complementary to the IVB parent melt was also estimated, and appears to be similar to that of the angrite parent.     

An analysis of climatic and human induced determinants of agricultural land use changes in Shupiyan area of Jammu and Kashmir state,India

The economy of the Jammu and Kashmir state depends mostly on traditional forms of occupation. Unaffected and unaltered by modern day industrial developments and changing times, the indigenous traditional occupations of farming, animal husbandry and horticulture forms the backbone of the state economy. But in the last few decades, Agriculture in the state as well as the study area is receiving a set back and Horticulture is flourishing leaps and bounds. The present study aims to analyze various determinants responsible for this change. Climatic as well as field data was thoroughly analyzed to comprehend the situation. A Mann–Kendall test was done on the climatic data to support the hypotheses. It was observed that initially changing climatic trends proved to be the triggering factor supporting this change, but in due course of time, the determinants took an economic and psychological turn. The perusal of Indian Meteorological Data reveals an increasing trend of annual mean maximum temperature from 16.78 °C in 1985 to 17.58 °C in 1995 and an increase from 5.30 °C to 7.00 °C in the annual mean minimum temperature, and as such acting as a triggering factor for the land use conversion. Further, the mean annual rainfall shows a decrease from 100.75 mm in 1981 to 79.43 mm in 1991. The greater economic returns from horticulture as well as the changing behavioral patterns of people over the time further cemented its growth. The farmers have since persisted with the horticulture activity as it has proven to be an economically a much better lucrative enterprise.     

Evaluation of long term trends in apple cultivation and its productivity in Jammu and Kashmir from 1975 to 2015

GeoJournal - Horticulture plays a pivotal role in the economy of Jammu and Kashmir. Owing to favourable agro-climatic conditions, temperate horticulture is fast expanding in the state which is...     

Unique achondrite Northwest Africa 11042: Exploring the melting and breakup of the L chondrite parent body

Northwest Africa (NWA) 11042 is a heavily shocked achondrite with medium‐grained cumulate textures. Its olivine and pyroxene compositions, oxygen isotopic composition, and chromium isotopic composition are consistent with L chondrites. Sm‐Nd dating of its primary phases shows a crystallization age of 4100 ± 160 Ma. Ar‐Ar dating of its shocked mineral maskelynite reveals an age of 484.0 ± 1.5 Ma. This age coincides roughly with the breakup event of the L chondrite parent body evident in the shock ages of many L chondrites and the terrestrial record of fossil L chondritic chromite. NWA 11042 shows large depletions in siderophile elements (<0.01×CI) suggestive of a complex igneous history involving extraction of a Fe‐Ni‐S liquid on the L chondrite parent body. Due to its relatively young crystallization age, the heat source for such an igneous process is most likely impact. Because its mineralogy, petrology, and O isotopes are similar to the ungrouped achondrite NWA 4284 (this work), the two meteorites are likely paired and derived from the same parent body.     

Snow cover area change and its relations with climatic variability in Kashmir Himalayas,India

Snowmelt makes an essential component of the hydrological system of Kashmir Himalayas. The present study was carried out to examine the status of Snow Cover Area (SCA) using Moderate Resolution Imaging Spectroradiometer (MODIS) 8-day Snow Cover Product between 2000 and 2016. The intra- and inter-annual variability in SCA and in meteorological parameters was observed and various statistical tests were used to study the interrelationship. Results of statistical analysis indicate decrease in maximum temperature (?0.05 °C/year) and minimum temperatures (?0.02 °C/year) while rise in precipitation (19.13 mm/year). It also showed an increase in annual mean SCA (43.5 sq km) during the study period. The analysis was also carried out on a seasonal basis. The results revealed that in Kashmir Himalayas, climate plays a dominating role in controlling the SCA. The results depict the short-term fluctuations in SCA and show the magnitude of change between two successive values being very large in SCA.     

ANALYSIS OF SURFACE AIR TEMPERATURE RECORDED IN LAHORE AND MIANWALI OVER THE PAST THREE DECADES

Surface air temperatures recorded over the past three decades at the weather stations located in Lahore (anindustrialized and densely populated city) and Mianwali (a small and sparsely populated city) were analyzed in order tostudy their climatic trend.Lahore,where meteorological data are recorded at two weather stations (city station and air-port station) indicates a cooling trend,of about 0.5℃ per record period of 1953—1992,for the airport station (31°31′N,74°24′E) and a slight warming trend,of about 0.2℃,for the city station (31°33′N,74°20′E) for the record period of 1950—1992.The Mianwali weather station (32°33′N,71°31′E) also shows a slight cooling trend,of about 0.4℃ per recordperiod of 1959—1992.The climatic variability at these stations was studied by computing seasonal and annual tempera-ture anomalies.The results are explained in terms of the local environmental conditions.