Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

Nonlinear effects of the distribution of amplitudes of sea waves

The effect of nonlinearities, such as wave-breaking and vertical asymmetry associated with sea waves, on the distribution of wave amplitudes is explored. Semiclosed theoretical expressions are derived to describe the distributions of breaking-limited crest and trough amplitudes for Stokes-type nonlinear sea waves. These are compared with the conventional Rayleigh distribution appropriate to linear wave amplitudes. The construction of nonlinear wave envelopes with the fast Fourier transform technique is described. The technique can be utilized to enlarge the data base in empirical analyses of field records which typically contain limited information on amplitude characteristics. The theoretical distributions and the proposed data enlargement technique are demonstrated with the analysis of a nonlinear wave record.     

Effects of spectrum band width on the distribution of wave heights and periods

The statistical distribution of the crest-to-trough heights of narrowband nonlinear sea waves is derived in a semi-closed form. A quantitative comparison of the resulting density and exceedance probability distributions with those of the linear theory is given. It is shown that the nonlinearity of waves, even with steepnesses typical of extreme sea states, has an insignificant influence on the distribution of crest-to-trough heights.     

Statistics of nonlinear wave crests and groups

Groups of large nonlinear waves with sharper higher crests can pose hazards to ships, induce harbor resonance and cause wave-overtopping of fixed and floating structures. Past interest in wave groups has mostly been focused on the statistics and modeling of linear wave groups. Studies on nonlinear wave groups are surprisingly few, and address deep water waves only. Here, statistics of nonlinear wave crests and wave-crest groups in deep and transitional water depths are considered, using an appropriate second-order representation for crest heights and the continuous wave-envelope approach. In particular, theoretical expressions describing the statistics of nonlinear wave crests and their groups are posed in the form of a simple second-order transformation of well-known results on linear waves. Predictions from the transformation so posed compare well with nonlinear wave data gathered in the North Sea, and demonstrate that nonlinearities do affect the statistics of large wave crests and their groups significantly.     

Depositional environments and facies of the Late Triassic Abu Ruweis Formation, Jordan

The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture, gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite, which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O¹⁸ content ranges from 1.45 to 8.38% PDB and the C¹³ content ranges from −1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted conditions were provided by the development of beach barriers.     

The best fitting distribution of annual maximum rainfall in Peninsular Malaysia based on methods of L-moment and LQ-moment

This paper discusses patterns of annual and monthly precipitation variability at seven weather stations in east central Europe (1851–2007). Precipitation patterns were compared to three simple regional indices of atmospheric circulation, i.e., western circulation, southern circulation and the cyclonicity (C) index and a relationship between precipitation and the North Atlantic Oscillation index was identified. Correlations of the monthly records and multiple regression, using a principal components’ analysis, helped determine the statistical significance of the dependence of precipitation on the circulation indices. The Mann–Kendall test revealed no trend to change in any of the precipitation series, but a certain spatial regularity could be discerned in the phase of the annual periodic component. A common feature of the variability in central European annual precipitation is the dry period identified in the 1980s and the first half of the 1990s. In the northern part of the region, above-average precipitation was noted from the 1960s through to the mid-1970s as a result of the frequent prevalence of depressions. South of the divide, the wettest period was recorded at the turn of 1930s/1940s. After a number of very wet years in the last decade of the twentieth century and the beginning of the twenty-first century, precipitation began to fall at all of the region’s weather stations. The C index is the strongest circulation-linked factor influencing precipitation in central Europe and it accounts for more than 40% of the variance in spatially averaged wintertime precipitation.     

中国夏季气候对植被覆盖的影响:1982～2001(英文)

In this paper, we apply lagged correlation analysis to study the effects of vegetation cover on the summer climate in different zones of China, using NOAA/AVHRR normalized difference vegetation index (NDVI) data during the time period from 1982 to 2001 and climate data of 365 meteorological stations across China (precipitation from 1982 to 2001 and temperature from 1982 to 1998). The results show that there are positive correlations between spring NDVI and summer climate (temperature and precipitation) in m...     

Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

Study of horizontal drain effect on slope stability

Slope failure usually occurs when soil particles are unable to build a strong bond with each other and become loose because of the presence of water. Water pressure weakens the ties between the particles and they tend to slip. Therefore, this study focused on the use of horizontal drains to reduce water entry and control the ground water level as a method of slope stabilization. Several previous studies have shown that the use of horizontal drains to lower the water level in soil is one of the fastest and cheapest slope stabilization methods. The main objective of this study is to analyze the effect of horizontal drains on slope stability. Information on slope condition during the landslides which happened at Precinct 9, Putrajaya, Malaysia was used for analytical simulation. Seep/W and Slope/W analyses were carried out with GeoStudio version 2007 software. Slopes with and without horizontal drains were then compared in terms of groundwater level and factor of safety (FOS) values. Scenarios were created for seven types of soil namely: residual, clay, silt, loam, sandy loam, sandy clay loam, and silt clay loam for a case wise analysis. The effect of daily steady rainfall and realcondition rainfall was studied. These cases were studied to find the effectiveness of horizontal drains as a slope stabilization tool. The results revealed that when a drain was installed on a slope, the groundwater level dropped immediately and the safety factor of the slope increased. Sandy loam (sL) soil was identified as the best candidate for a horizontal drain. Its highly saturated hydraulic conductivity Ks facilitated groundwater drain through the horizontal drain effectively. Silt clay loam (scL) soil was identified as the least effective candidate.