Crustal xenoliths from Calbuco Volcano,Andean Southern Volcanic Zone: implications for crustal composition and magma-crust interaction

Crustal xenoliths in the 1961 andesite flow of Calbuco Volcano, in the southern Southern Volcanic Zone (SSVZ) of the Andes, consist predominantly of pyroxene granulites and hornblende gabbronorites. The granulites contain plagioclase+pyroxene+magnetite±amphibole, and have pronounced granoblastic textures. Small amounts of relict amphibole surrounded by pyroxene-plagioclase-magnetite-glass symplectites are found in some specimens. These and similar textures in the gabbronorites are interpreted as evidence of dehydration melting. Mineral and bulk rock geochemical data indicate that the granulites are derived from an incompatible trace element depleted basaltic protolith that underwent two stages of metamorphism: a moderate pressure, high temperature stage accompanied by melting and melt extraction from some samples, followed by thermal metamorphism after entrainment in the Calbuco andesite lavas. High _Nd ^T values (+4.0 to +8.6), Nd-isotope model ages of 1.7–2.0 Ga, and trace element characteristics like chondrite normalized La/Yb< and La/Nb1 indicate that the protoliths were oceanic basalts. Similar oceanic metabasalts of greenschist to amphibolite facies are found in the Paleozoic metamorphic belt that underlies the Chilean coastal ranges. Mineral and bulk rock compositions of the gabbronorite xenoliths indicate that they are cognate, crystallizing from the basaltic andesite magma at Calbuco. Crystallization pressures for the gabbros based on total Al contents in amphibole are 6–8 kbar. These pressures point to middle to lower crustal storage of the Calbuco magma. Neither granulite nor gabbro xenoliths have the appropriate geochemical characteristics to be contaminants of Calbuco andesites, although an ancient sedimentary contaminant is indicated by the lava compositions. The presence of oceanic metabasaltic xenoliths, together with the sedimentary isotopic imprint, suggests that the lower crust beneath the volcano is analogous to the coastal metamorphic belt, which is an accretionary complex of intercalated basalts and sediments that formed along the Paleozoic Gondwanan margin. If this is the case, the geochemical composition of the lower and middle crust beneath the SSVZ is significantly different from that of most recent SSVZ volcanic rocks.     

EXPERIMENTAL AND FIELD STUDY ON MINING-PIT MIGRATION

1 INTRODUCTION Because of the large quantity of sand and gravel in their beds, rivers have always been considered as a major source of sand and gravel for civil works. Acceptable quality, ease of extraction and economy are some of the reasons could be mentioned. Unfortunately, specific laws and regulations regarding the safe in-stream mining have not been provided for users and officials. What should be taken into account are the effects of over-mining of sand and gravel, which can cause …     

铀在近代海洋生物中的积聚

本文研究的目的是确定软体动物对于铀在海洋生态系统中的分布所起的地球化学作用。对取自里海、日本海、马尔马拉海、爱琴海、黑海、地中海、波罗的海和印度洋的近代软体动物贝壳进行了生物地球化学研究,这些贝壳的物理、化学、地理和地球化学特征各不相同。本次研究中,分析了9个腹足类和54个双壳类不同种的贝壳以记录铀在不同季节层中的变化。季节层是由软体动物在整个生命过程中季节性的碳酸盐—有机相生成的。研究中使用的贝壳主要分3层:上(外)棱柱层,中棱柱层,内(珠母)层。此外,条件许可时,将贝壳性的头部、中部和下部分别进行分析,并且还计算出相对     

Analysis of parameters of ground vibration produced from bench blasting at a limestone quarry

The aim of this study is to predict peak particle velocity level at a limestone quarry located in Istanbul, Turkey. The ground vibration components were measured for 73 blast events during the bench blast optimization studies during a long period. In blasting operations; ANFO (blasting agent), gelatine dynamite (priming) and NONEL detonators (firing) were used as explosives at this site. Parameters of scaled distance (charge quantity per delay and the distance between the source and the station) were recorded carefully and the ground vibration components were measured by means of vibration monitors for every event. Then, the data pairs of scaled distance and particle velocity were analyzed. The equation of scaled distance extensively used in the literature was taken into consideration for the prediction of peak particle velocity. At the end of statistical evaluations, an empirical relationship with good correlation was established between peak particle velocity and scale distance for this site. The established relationship and the results of the study are presented.     

Period formulas of shear wall buildings with flexible bases

The evaluation of the fundamental period of shear wall buildings considering the flexibility of the base is investigated in this paper. This research is motivated by the discrepancy reported between the formulas used in different building codes and the measurement of real buildings. Both experimental and analytical approaches are used to assess the effect of the base flexibility on the fundamental period of shear wall structures. In total, twenty buildings built on different types of soil are tested under ambient vibration. The fundamental period is identified using a non‐parametric linear model in the frequency domain. The results show that fundamental period formulas used by UBC‐97 and NBCC‐95 are inadequate since they do not include the effect of the foundation stiffness. To improve the estimation of the fundamental period of shear wall buildings, an analytical approach is presented. The structure and the foundation are represented by a continuous‐discrete system. The stiffnesses of the base are represented by translational and rotational discrete springs. The rigidities of these springs are evaluated from the elastic uniform compression of the soil mass and the size of the foundation. The analytical predictions improve the estimation of the fundamental period and keep the computation simple. The error between the measured period and the analytical results is, on average, less than 10%. Copyright © 2003 John Wiley & Sons, Ltd.     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

Green synthesis of magnetic mesoporous silica nanocomposite and its adsorptive performance against organochlorine pesticides

Green synthesis of nanomaterials has received increasing attention as an eco-friendly technology in materials science. Here, we have used two types of extractions from green tea leaf (i.e., total extraction and tannin extraction) as reducing agents for a rapid, simple and one-step synthesis method of mesoporous silica nanoparticles/iron oxide nanocomposite based on deposition of iron oxide onto mesoporous silica nanoparticles. Mesoporous silica nanoparticles/iron oxide nanocomposite were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, N₂ adsorption and high-resolution transmission electron microscopy. Mesoporous silica nanoparticles/iron oxide nanocomposite was used as a solid adsorbent for removal of lindane pesticide from aqueous solutions. The developed system possesses the advantages of silica as core that include large surface area and advantages of iron oxide (shell) that include the capability to interact with chlorinated compounds and ability to release by using external magnetic field. UV-Vis technique was used as a simple and easy method for monitoring the removal of lindane. Effects of pH and temperature on the removal efficiency of the developed mesoporous silica nanoparticles/iron oxide nanocomposite toward lindane pesticide were also investigated. Fourier transform infrared spectroscopy, high-performance liquid chromatography and gas chromatography techniques were used to confirm the high ability of mesoporous silica nanoparticles/iron oxide nanocomposite for sensing and the capture of lindane molecules with high sorption capacity (about 99%) that could develop a new eco-friendly strategy for detection and removal of pesticide and as a promising material for water treatment.     

2004年春季沙尘天气对和田市空气质量的影响

利用沙尘暴监测网数据、常规气象资料以及MICAPS系统环流形势资料,对和田市2004年春季沙尘天气产生的污染进行了详细的对比分析。研究结果表明：和田市春季污染相当严重,主要以沙尘污染为主。整个春季79％时间API（环境污染指数）指数均达到500,且45％时间可吸入颗粒物PM10在TSP巾的浓度比例达50％。不同天气系统对和田市空气的污染贡献不同。从东路影响和田市的天气系统、高压底部型地面系统和浮尘天气所造成空气污染相当严重。其余天气系统和天气现象所产生的污染较小。     

A study of aerosol properties over Lahore (Pakistan) by using AERONET data

It is well established that aerosols affect the climate in a variety of ways. In order to understand these effects, we require an insight into the properties of aerosols. In this paper we present a study of aerosol properties such as aerosol optical depth (AOD), single scattering albedo (SSA) and aerosol radiative forcing (ARF) over mega city of Lahore (Pakistan). The data from Aerosol Robotic Network (AERONET) have been used for the period December 2009 to October 2011. The seasonal average values of AOD, asymmetry parameter (ASY) and volume size distribution in coarse mode were observed to be highest in summer. On the other hand, the average values of Angstrom exponent (AE) and imaginary part of refractive index (RI) were found to be maximum in winter. The average value of real part of RI was found to be higher in spring than in all other seasons. The SSA exhibited an increasing trend with wavelength in the range 440 nm–1020 nm in spring, summer and fall indicating the dominance of coarse particles (usually dust). However, a decreasing trend was found in winter in the range 675 nm–1020 nm pointing towards the dominance of biomass and urban/industrial aerosols. As far as aerosol radiative forcing (ARF) is concerned, we have found that during the spring season ARF was lowest at the surface of Earth and highest at top of the atmosphere (TOA). This indicates that the atmosphere was warmer in spring than in all the remaining seasons.     

Estimation of the Land Surface Emissivity in the Hinterland of Taklimakan Desert

An accurate accounting of land surface emissivity(ε) is important both for the retrieval of surface temperatures and the calculation of the longwave surface energy budgets.Since ε is one of the important parameterizations in land surface models(LSMs),accurate accounting also improves the accuracy of surface temperatures and sensible heat fluxes simulated by LSMs.In order to obtain an accurate emissivity,this paper focuses on estimating ε from data collected in the hinterland of Taklimakan Desert by two different methods.In the first method,ε was derived from the surface broadband emissivity in the 8–14 μm thermal infrared atmospheric window,which was determined from spectral radiances observed by field measurements using a portable Fourier transform infrared spectrometer,the mean ε being 0.9051.The second method compared the observed and calculated heat fluxes under nearneutral atmospheric stability and estimated ε indirectly by minimizing the root-mean-square difference between them.The result of the second method found a mean value of 0.9042,which is consistent with the result by the first method.Although the two methods recover ε from different field experiments and data,the difference of meanvalues is 0.0009.The first method is superior to the indirect method,and is also more convenient.