Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

The early Miocene (~25 Ma) volcanism in the northern Kyushu-Palau Ridge,enriched mantle source injection during rifting prior to the Shikoku backarc basin opening

The northern Kyushu-Palau Ridge (KPR), remnant conjugate arc of the Izu-Ogasawara (Bonin)-Mariana (IBM) active arc, is dominated by basalt-andesite except for the Komahashi-Daini Seamount where acidic plutonic rocks of 38 Ma were recovered. These mafic to intermediate volcanics are produced by the rifting volcanism in the proto-IBM arc associated with spreading of the Shikoku Basin. The HFSE and HREE contents and ratios of these volcanics indicate enriched source mantle composition compared to recent volcanic front. The LILE ratios exhibit similar characteristics to reararc volcanism of the recent Izu arc, and some enriched volcanics exhibit high abundance of sediment melt inputs. Based on these observations and compilations of the published data set, the replacement event of the wedge mantle under the IBM arc occurred two times. The first event occurred between 45 and 38 Ma, with Pacific type mantle being replaced by depleted Indian type mantle. The second event occurred between 36 and 25 Ma, enriched mantle flowed from reararc side. The slab component during the proto-IBM arc rifting was a similar characteristic to recent reararc volcanism of the Izu arc, and sediment melt added in a local area.     

Changes in the abundance and composition of picophytoplankton in relation to the occurrence of a Kyucho and a bottom intrusion in the Bungo Channel,Japan

The Bungo Channel in southwestern Japan receives both warm, called Kyucho, and cold deep-water intrusions (bottom intrusion) from the Pacific Ocean. Abundances of Prochlorococcus, Synechococcus, and eukaryotic picophytoplankton were monitored from 18 July to 17 August 2001 to clarify whether advected picophytoplankton from the Pacific Ocean can grow in the channel or not. Synechococcus cells were further discriminated into low- and high-PUB types according to their fluorescence property in flow cytometry. From 18 to 25 July, the water temperature decreased by 3 °C at a 5-m depth at all stations, indicating the occurrence of a bottom intrusion. From 25 July to 4 August, a Kyucho occurred and the water temperature rapidly increased. From 4 to 17 August, a bottom intrusion and a Kyucho both occurred twice, although the intensities were smaller than those occurring until 4 August. From 18 to 30 July, the abundance of both Prochlorococcus and a high-PUB type of Synechococcus drastically decreased because of a bottom intrusion; however, the abundances rapidly increased due to the advection by a Kyucho. These advected cells increased from 4 to 17 August in the channel and Kitanada Bay. Changes in the abundance of low-PUB type of Synechococcus and eukaryotic picophytoplankton were less noticeable than those in the abundance of Prochlorococcus and high-PUB type. The present study demonstrated that oceanic picophytoplankton advected by the Kyucho could grow in the channel. However, abundances of low-PUB type and eukaryotic picophytoplankton increased higher than those of Prochlorococcus and high-PUB type did. Thus, these oceanic phytoplankters will be excluded when Kyucho does not occur for a long time. The co-occurrence of various types of picophytoplankton found in the channel is probably achieved by both Kyucho event and their growth capability in the channel.     

Latitudinal and local variations of the life history characteristics of the thalassinidean decapod, Upogebia yokoyai: A hypothesis based on trophic conditions

Mean total length of the eldest cohort (MTLe) of the thalassinidean decapod, Upogebia yokoyai sampled at 16 sites showed a latitudinal variation from south-west islands of the Ryukyu Archipelago (24° N) to the Seto-Inland Sea of Japan (34° N). Local variations were however also found from sites in the same latitudes. The level of the organic content in each habitat showed a positive correlation with MTLe. We hypothesized that MTLe is strongly affected by the trophic condition, resulting in the local variations. To test this hypothesis, two estuaries with different organic content were compared; Kodono River (Kochi Prefecture, 33° N) which was relatively oligotrophic and Sakata River (Hiroshima Prefecture, 34° N) which was highly eutrophicated. The Kodono River population showed slow growth after settlement, and growth stopped in May to June. This population survived for only one or two years, resulting in small MTLe. On the other hand, the Sakata River population showed fast growth from August to December. This population survived for three years, resulting in large MTLe. Maturation was estimated to occur two years after settlement in both populations. Low salinities may partially affect MTLe. Habitats in the Seto-Inland Sea (33.5–34.8° N) were eutrophicated, but many habitats in the subtropical islands (24–31° N) were relatively oligotrophic. Latitudinal variation of MTLe was reflected by the geographical difference in trophic condition. A negative relationship between population density and growth was found, which was explained in terms of reduced survival of recruits in the eutrophicated habitats.     

Seasonal and vertical distribution of Aurelia aurita polyps on a pylon in the innermost part of Tokyo Bay

Natural aggregations of Aurelia aurita polyps were found by direct observation during SCUBA diving on the surface of a pylon in the innermost part of Tokyo Bay, Japan, and changes in polyp abundance with depth were examined from November 2000 to December 2001. Most polyps were observed on substrates in the layer within 1 m from the bottom. Substrates in the upper layer were mainly occupied by other sessile organisms such as the blue mussel Mytilus galloprovincialis, implying that A. aurita polyps may be exposed to interspecific competition for space with other organisms, especially during spring and summer. The bottom layer, especially within 1 m from the bottom, was characterized by summer hypoxia and low recruitment and growth of other sessile organisms such as mussels, resulting in abundant settlement and high survival of A. aurita polyps, which are tolerant of near-hypoxic conditions. It is considered that the occurrence of hypoxic waters due to eutrophication contributes directly to the recruitment of polyps and the consequent production of A. aurita medusae in the following year.     

Seasonal and interannual variability of oceanic carbon cycling in the western and central tropical-subtropical pacific: A physical-biogeochemical modeling study

The oceanic carbon cycle in the tropical-subtropical Pacific is strongly affected by various physical processes with different temporal and spatial scales, yet the mechanisms that regulate air-sea CO₂ flux are not fully understood due to the paucity of both measurement and modeling. Using a 3-D physical-biogeochemical model, we simulate the partial pressure of CO₂ in surface water (pCO_2sea) and air-sea CO₂ flux in the tropical and subtropical regions from 1990 to 2004. The model reproduces well the observed spatial differences in physical and biogeochemical processes, such as: (1) relatively higher sea surface temperature (SST), and lower dissolved inorganic carbon (DIC) and pCO_2sea in the western than in the central tropical-subtropical Pacific, and (2) predominantly seasonal and interannual variations in the subtropical and tropical Pacific, respectively. Our model results suggest a non-negligible contribution of the wind variability to that of the air-sea CO₂ flux in the central tropical Pacific, but the modeled contribution of 7% is much less than that from a previous modeling study (30%; McKinley et al., 2004). While DIC increases in the entire region SST increases in the subtropical and western tropical Pacific but decreases in the central tropical Pacific from 1990 to 2004. As a result, the interannual pCO_2sea variability is different in different regions. The pCO_2sea temporal variation is found to be primarily controlled by SST and DIC, although the role of salinity and total alkalinity, both of which also control pCO_2sea, need to be elucidated by long-term observations and eddy-permitting models for better estimation of the interannual variability of air-sea CO₂ flux.     

Observation of the bottom boundary layer off the Soya Warm Current

A mooring observation of current velocity, temperature and bottom pressure was carried out approximately 30 km off the coast of Monbetsu, between August 7 and September 2, 2005, to investigate the characteristics of bottom boundary layer (BBL) off the Soya Warm Current (SWC). We succeeded in measuring the Ekman veering and bottom Ekman transport in the BBL. On comparing the observed current velocity with that represented by the classical theoretical equation, the observed alongshore current velocity in BBL disagreed with that represented by the classical theoretical equation, but the cross-shore one agreed well. However after applying a linear extrapolation for the alongshore current velocity to estimate the alongshore geostrophic current velocity above the bottom, we could explain the alongshore current velocity by that represented in the classical theoretical equation. Consequently, our observations strongly support one of the proposed formation mechanisms of the cold-water belt observed off the SWC, that is, the convergence of bottom Ekman transport. The volume transport of vertical pumping velocity was estimated to be (0.12–0.25) Sv. In addition, the vertical profile of average temperature in all observation periods shows that slightly warmer water lies beneath the homogenous temperature layer, in the BBL. The result is considered to imply that the down-slope advection due to bottom Ekman transport supplies the SWC water in BBL and the eddy diffusivity of order of 10⁻³ m²s⁻¹ maintains the oceanic structure in the bottom mixed layer.