Removal of Organochlorine Pesticides from Aqueous Solution by Using Neutralized Red Mud

This work describes the potential usability of neutralized red mud for the removal of organochlorine pesticides (OCPs) from aqueous solutions. After examination on the adsorption capability of neutralized red mud for all studied OCPs, the experiments were performed by employing aldrin as a model compound. The effect of several parameters, such as contact time, pH of the solution, initial aldrin concentration, and dosage of the adsorbent was evaluated by batch experiments. The determination of OCPs was carried out using traditional liquid–liquid extraction followed by a GC coupled with µ‐electron capture detector (GC‐µECD). The results showed that adsorption equilibrium time depended upon the initial aldrin concentration and adsorption followed the second‐order kinetic model. Kinetic study also indicated that the film diffusion mechanism was a main rate control mechanism. The removal was explained by considering the electrostatic interactions between metal oxides surface of the neutralized red mud and inductively charged centers (negative charge (d?) of chlorine atoms and positive charge (d+) of π‐cloud aromatic ring) of the aldrin molecules. In comparison to the Langmuir isotherm model, the Freundlich model better represented the adsorption data. The neutralized red mud was also succesfully employed for the removal of OCPs from real water samples, including tap water and surface (lake) water, fortified with studied OCPs.     

Performance assessment of a concept propulsor: the thrust-balanced propeller

This paper presents the results of a numerical performance analysis to demonstrate the worthiness of a recently patented new concept propulsor, the so-called “thrust-balanced propeller (TBP)”. The main advantage of this unconventional propulsor is its inherent ability to reduce the unsteady effect of blade forces and moments when it is operating in a non-uniform wake flow. The propulsor comprises a pair of diametrically opposed blades that are connected to one another and mounted so as to be rotatable together through a limited angle about their spindle axis. A quasi-hydrodynamic approach is described and applied to perform the numerical analysis using a state-of-the-art lifting surface procedure for conventional propellers. Performance comparisons with a conventional fixed-pitch propeller are made for the blade forces and moments, efficiency, cavitation extents and fluctuating hull pressures. Bearing in mind the quasi-static nature of the analyses, the results present favourable performance characteristics for the thrust-balanced propeller and support the worthiness of the concept. However, the concept needs to be proved through physical model tests, which are planned to take in a cavitation tunnel.     

Triple diagram method for the prediction of wave height and period

Many formulations have been developed so far to predict the wave height and period from fetch length and wind blowing duration for a constant wind speed. This study aimed to predict wave parameters from fetch length and meteorological factors by using triple diagram methodology based on Kriging principles. Proposed model results were compared with Joint North Sea Wave Project (JONSWAP) model which is used so commonly in the ocean and coastal engineering studies. For the implementation of the methodology hourly wave and wind data were obtained from a buoy located in Lake Ontario. Numerical and graphical comparisons demonstrated that the proposed method outperforms the classical formulation.     

Late Oligocene–Early Miocene palaeoecology based on pollen data from the Kalkım-Gönen Basin (Northwest Turkey)

Radiometric and palynological data of the Upper Oligocene–Lower Miocene Soma Formation from the Kalk?m-Gönen Basin yield new results related to age and palynological contents. In this study, Upper Oligocene strata from the Dani?ment and Linfa areas and Lower Miocene strata from the Bengiler area were sampled palynologically and for radiometric dating. The Dani?ment assemblage, which is older than the Linfa assemblages, mainly contains coniferous and evergreen to deciduous mixed mesophytic forest elements. Relatively high quantities of the altitudinal plants Picea and Abies, indicate a cooler palaeoclimate. The Linfa associations mainly include coniferous and riparian elements. Pollen of the riparian plant Alnus and Taxodiaceae indicative for the swamp forest community was predominant, probably as a result of a high lake level. There is a hiatus during the Oligocene–Miocene transition, probably showing a non-depositional phase and sea-level fall indicating the Mi-1 glaciation event. Higher in the sequence, the Aquitanian Bengiler sediments include high amounts of coniferous forest elements as well as components indicative for the evergreen and deciduous mesophytic forest and also riparian forest and swamp forest. Due to presence of thermophilous taxa Reveesia, Mastixiaceae and Arecaceae, a warm and humid palaeoclimate is inferred according to quantitative analyses using the Coexistence Approach.     

Estimation of the local financial costs of flood damage with different methodologies in Unye (Ordu), Turkey

The aim of this study was to conduct flood analysis with digital modeling systems and estimate the total flood damage in a built-up area. The Ceviz Stream basin, which is located in Unye (Ordu) district in the Eastern Black Sea region of Turkey, was selected as the study area. A 1D/2D coupled flood modeling software MIKE FLOOD was used in flood analysis. According to the modeling results, water depth and velocity maps are produced for maximum Q₅₀, Q₁₀₀, Q₅₀₀ and Q₁₀₀₀ discharge scenarios in the most downstream section of the Ceviz Stream. At the projected Q_50, Q₁₀₀, Q₅₀₀ and Q₁₀₀₀ maximum flow rates, approximately 9.75%, 23.0%, 30.0% and 32.25% of that section of the study area were estimated to be negatively affected by floodwaters. In order to examine the financial magnitude of the effects of flooding, the Huizinga, van Eck and Kok, ICBR and Pistrika and Jonkman damage estimation methodologies were applied, with the highest financial costs estimated with the Pistrika and Jonkman method.

     

Hydrochemical characterisation of ground and surface water at Dörtyol/Hatay/Turkey

The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.     

Climate change in Turkey for the last half century

Climate change and its urban-induced bias in selected Turkish cities is studied with a quality controlled temperature and precipitation data of Turkish stations in the period of 1950–2004. These stations are classified into two groups according to their populations; S1, including rural and suburban stations and S2, including large urban stations. Moving average signals, 365-day, and their digital low pass filtered versions are produced to eliminate the short term fluctuations and examine the possible trends or anomalies in climate data. Furthermore, ‘relative difference’ signals are introduced and applied to temperature and precipitation series to observe the actual local changes in the climate data independent from large-scale effects. Mann–Kendall test statistics are calculated for maximum, minimum, mean temperature and precipitation series and plotted on maps to determine any spatial trend patterns. Signal analysis show a cool period extending from early 1960s till 1993, generally with the lowest temperature values on 1992–1993 owing to the eruption of Mount Pinatubo. A last decade significant warming trend is observed in both of the series, S1 and S2, leading to 2000–2002 temperatures to be recorded as maximums in record history. The variability of urban precipitation series is generally larger than the rural ones, suggesting that urban stations can experience more frequent and severe droughts and floods. Though not significant, an increase in the urban precipitation compared to the rural one is also found. Spatial analysis resulted in significant warming in southern and southeastern parts of the country. Particularly, minimum temperature series show significant warming in almost all of the regions indicating the effect of urbanization. Significant decreases of precipitation amounts in the western parts of Turkey, such as Aegean and Trachea regions, are found. On the other hand, some Turkish northern stations show increases in precipitation of which some are significant.     

Estimation of relative humidity based on artificial neural network approach in the Aegean Region of Turkey

The aim of this study is to estimate the monthly mean relative humidity (MRH) values in the Aegean Region of Turkey with the help of the topographical and meteorological parameters based on artificial neural network (ANN) approach. The monthly MRH values were calculated from the measurement in the meteorological observing stations established in Izmir, Mugla, Aydin, Denizli, Usak, Manisa, Kutahya and Afyonkarahisar provinces between 2000 and 2006. Latitude, longitude, altitude, precipitation and months of the year were used in the input layer of the ANN network, while the MRH was used in output layer of the network. The ANN model was developed using MATLAB software, and then actual values were compared with those obtained by ANN and multi-linear regression methods. It seemed that the obtained values were in the acceptable error limits. It is concluded that the determination of relative humidity values is possible at any target point of the region where the measurement cannot be performed.     

Quantification of the urban heat island under a changing climate over Anatolian Peninsula

The Anatolian Peninsula is located at the confluence of Europe, Asia, and Africa and houses 81 cities of which 79 of them have population over 100,000. We employed some criteria to select the cities from the 81 cities. After accomplishing all the criteria, eight cities were remaining for the study. Nonparametric Mann–Kendall test procedure was employed for the urban and rural stations of these cities to detect the long-term change in temperature trends. Statistical analysis of daily minimum temperatures for the period between 1965 and 2006 suggest that there is no statistically significant increase in rural areas. In contrast to the findings of the previous studies, however, all the urban sites and difference between urban and rural pairs show significant increase in temperatures, a strong indication for the existence of urban heat island (UHI) affect over the region. Regional Climate Model was also utilized to assess the changes in temperature by the end of century for the region. The findings suggest that an increase of up to 5°C is possible. Climate change effects enforced with UHI have the potential to cause serious problems for the entire region and hence needs to be studied thoroughly.