Geology and the Allied liberation of Normandy: highlights to help mark the 75th anniversary of D‐Day, 6 June 1944

During the Second World War, the Allied invasion of the French coast of Normandy on D‐Day, 6 June 1944, was the greatest amphibious assault in world history. An article in Geology Today (v.11, for 1995, pp.58–63) marked the 50th anniversary of the end of the war in Europe, on 8 May 1945, by describing how British military geologists had participated in planning for D‐Day and in the NW Europe campaign that followed it. The work of these geologists provides a classic case history, revealing that ‘military geology’ has many potential applications. Geological factors influenced site selection for temporary airfields, predictions of trafficability for the Normandy beaches, the development of potable water supplies, and quarrying for road metal—and more besides. This new article helps to mark the 75th anniversary of D‐Day by further details of how geologists and geology contributed to Allied victory.     

Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

Radar observations of Itokawa in 2004 and improved shape estimation

Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object.     

Modeling X-Ray Photoionized Plasmas Produced at the Sandia Z-Facility

In experiments at the high-power Z-facility at Sandia National Laboratory in Albuquerque, New Mexico, we have been able to produce a low density photoionized laboratory plasma of Fe mixed with NaF. The conditions in the experiment allow a meaningful comparison with X-ray emission from astrophysical sources. The charge state distributions of Fe, Na and F are determined in this plasma using high resolution X-ray spectroscopy. Independent measurements of the density and radiation flux indicate unprecedented values for the ionization parameter ξ = 20–25 erg cm s⁻¹ under nearly steady-state conditions. First comparisons of the measured charge state distributions with X-ray photoionization models show reasonable agreement, although many questions remain.     

Metabolism of perylene by monooxygenases of the skin and liver of Ambystoma tigrinum

The prevalence of dermal neoplasia among neotenic tiger salamanders (Ambystoma tigrinum) collected from the Reese Air Force Base sewage lagoon far exceeded that among salamanders from nearby uncontaminated lagoons. Perylene was the predominant pglycyclic aromatic hydrocarbon contaminant in this lagoon. Perylene was shown to be a substrate for monooxygenases in skin and liver homogenates and formed DNA-binding metabolites. Perylene exposure appeared to augment subsequent perylene metabolism by dermal enzymes but it was not a strong inducer of hepatic monooxygenases. Aroclor 1254 induced benzo(a)pyrene and perylene metabolism by both skin and liver enzymes. However, perylene apparently was not activated by salamander enzymes, as suggested by its lack of in vitro mutagenicity and failure to induce tumors.     

Dark matter particles and the flat rotation curves of spiral galaxies

It is shown that a gas of massive bosonic particles (m 60 eV), e.g. Higgs particles, surrounding disk galaxies is able to generate the flat rotation curves of spiral galaxies without internal difficulties with physical principles. We have analyzed 36 galaxies and find good agreement with the empirical data.     

Laboratory simulation of infrared astrophysical features

Laboratory infrared emission and absorption spectra have been taken of terrestrial silicates, meteorites and lunar soils in the form of micrometer and sub-micrometer grains. The emission spectra were taken in a way that imitates telescopic observations. The purpose was to see which materials best simulate the 10 m astrophysical feature.The emission spectra of dunite, fayalite and Allende give a good fit to the 10 m broadband emission feature of comets Bennett and Kohoutek. A study of the effect of grain size on the presence of the 10 m emission feature of dunite shows that for particles larger than 37 m no feature is seen.The emission spectrum of the Murray meteorite, a Type 2 carbonaceous chondrite, is quite similar to the intermediate resolution spectrum of comet Kohoutek in the 10 m region. Hydrous silicates or amorphous magnesium silicates in combination with high-temperature condensates, such as olivine or anorthite, would yield spectra that match the intermediate resolution spectrum of comet Kohoutek in the 10 m region. Glassy olivine and glassy anorthite in approximately equal proportions would also give a spectrum that is a good fit to the cometary 10 m feature.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6 8 September, 1978.