Late Glacial and Holocene environmental history of the Pirin Mountains (SW Bulgaria): a paleolimnological study of Lake Dalgoto (2310 m)

Diatoms, Cladocera, and chironomids preserved in the sediments of Lake Dalgoto were studied to reconstruct the history of the lake ecosystem in the context of the vegetation history as represented by the pollen stratigraphy. Younger Dryas silty sediments at the base of the core are characterized by low diversity of aquatic organisms. The transition to the Holocene is indicated by a sharp change from silt to clay-gyttja. The migration and expansion of trees at lower elevations between 10200 and 8500 ¹⁴C-yr BP, along with higher diversities and concentrations of aquatic organisms and the decreased proportion of north-alpine diatoms, point to rapidly rising summer temperatures. After 6500 ¹⁴C-yr BP the expansion of Pinus mugo in the catchment coincides with signs of natural eutrophication as recorded by an increase of planktonic diatoms. In the late Holocene (4000–0 ¹⁴C-yr BP) Pinus peuce and Abies are reduced and Picea expands. Cereal grains and disturbance indicators suggest late-Holocene human modification of the vegetation.     

Addressing Hurricane Intensity through Angular Momentum and Scale Energetics Approaches

This paper addresses two avenues for gaining insight into the hurricane intensity issue—the angular momentum approach and the scale interaction approach. In the angular momentum framework, the torques acting on a parcel's angular momentum are considered along an inflowing trajectory in order to construct the angular momentum budget. These torques are separable into three components: The pressure torque, the surface friction torque, and the cloud torque. All torques are found to diminish the angular momentum of an inflowing parcel, with the cloud torques having the most important role. In the scale interaction approach, energy exchanges among different scales within a hurricane are considered as a means of understanding hurricane intensity. It is found that the majority of kinetic energy contribution to the hurricane scales originates from potential-to-kinetic in-scale energy conversions. The contribution of mean-wave interactions in the kinetic energy varies with distance from the center and with the life stage of a storm. In the early stages, as the disorganized convection becomes organized on the hurricane scales, upscale energy transfers (i.e., from small to large scale) are found to take place in the outer radii of the storm. In a mature storm, the kinetic energy transfers are downscale, except for the inner radii.     

Trace elements in the Goze Delchev coal deposit, Bulgaria

The geochemistry of trace elements in the underground and open-pit mine of the Goze Delchev subbituminous coal deposit have been studied. The coals in both mines are highly enriched in W, Ge and Be, and at less extent in As, Mn and Y as compared with the world-wide Clarkes for subbituminous coals. Ni and Ti are also enhanced in the underground coals, and Zr, Cr and Mo in the open-pit mine coals.Characteristic for the trace element contents in the deposit is a regular variation with depth. The following patterns were distinguished for profile I: a — the element content decreases from the bottom to the top of the bed paralleling ash distribution (Fe, Co, As, Sb, V, Y, Mo, Cs, REE, Hf, Ta, Th, P and Au); b — Ge and W are enriched in the near-bottom and near-top coals; c — in the middle part of the bed the content of K and Rb is maximal, while that of U is slightly enriched; d — Ba content decreases from the top to the bottom of the bed. In profile II, W and Be contents decrease from the bottom to the top. The near-bottom, and especially the near-roof samples of profile IV are highly enriched in Ge, while for W the highest is the content of the near-bottom sample.Ge, Be, As, Mn, Cl and Br are mainly organically associated. The organic affiliation is still strong for Co, B, Sr, Ba, Sb, U, Th, Mo, La, Ce, Sm, Tb and Yb in the underground coals, and Fe, Co, Na, W, Sr, Y and Ag in the coals from the open-pit mine. K, Rb, Ti, Zr, Hf and Ta are of dominant inorganic affinity. The chalcophile and siderophile elements correlate positively with Fe and each other and may be bound partly with pyrite or other sulphides and iron containing minerals.Compared statistically by the t-criteria, the elements Na, Li, Cu, Zn, Pb, Cr, Ni, Co, Mo, Fe and Be are of higher content in the open-pit mine. Tungsten is the only element of higher concentration in the underground mine. The contents of Ge, As, Sr, V, Mn, Y, Zr and P are not statistically different in both mines.It was supposed that there were multiple sources of the trace elements in the deposit. The source of the highly enriched elements (W, Ge, Be, and As) most probably were the thermal waters in the source area. The contemporary mineral springs are of high content of these elements. Another source were the hosting Mesta volcanic rocks, which are enriched in Sb, Mo, Hf, U, Th, As, Li and Rb. Some of the volcanics were hydrothermally altered and enriched or depleted of many elements. Thus, the hydrothermal solutions were also suppliers of elements for the coals. It is obvious that the contents, distribution and paragenesis, of the trace elements in both Goze Delchev coals reflect the geochemical specialization of the source area, including rocks, paleo- and contemporary thermal waters.     

Improved seasonal climate forecasts for the Caribbean region using the Florida State University Synthetic Superensemble

Summary Climate variations in the Caribbean, largely manifest in rainfall activity, have important consequences for the large-scale water budget, natural vegetation, and land use in the region. The wet and dry seasons will be defined, and the important roles played by the El Ni?o-Southern Oscillation (ENSO) and the North Atlantic Oscillation (NAO) in modulating the rainfall during these seasons will be discussed. The seasonal climate forecasts in this paper are made by 13 state of the art coupled atmosphere-ocean general circulation models (CGCMs) and by the Florida State University Synthetic Superensemble (FSUSSE), whose forecasts are obtained by a weighted combination of the individual CGCM forecasts based on a training period. The success of the models in simulating the observed 1989–2001 climatology of the various forecast parameters will be examined and linked to the models’ success in predicting the seasonal climate for individual years. Seasonal forecasts will be examined for precipitation, sea-surface temperature (SST), 2-meter air temperature, and 850 hPa u- and v-wind components during the period 1989–2001. Evaluation metrics include root mean square (RMS) error and Brier skill score. It will be shown that the FSUSSE is superior to the individual CGCMs and their ensemble mean both in simulating the 1989–2001 climatology for the various parameters and in predicting the seasonal climate of the various parameters for individual years. The seasonal climate forecasts of the FSUSSE and of the ensemble mean of the 13 state of the art CGCMs will be evaluated for years (during the period 1989–2001) that have particular ENSO and NAO signals that are known to influence Caribbean weather, particularly the rainfall. It will be shown that the FSUSSE provides superior forecasts of rainfall, SST, 2-meter air temperature, and 850 hPa u- and v-wind components during dry summers that are modulated by negative SOI and/or positive NAO indices. Such summers have become a feature of a twenty-year pattern of drought in the Caribbean region. The results presented in this paper will show that the FSUSSE is a valuable tool for forecasting rainfall and other atmospheric and oceanic variables during such periods of drought.     

Exsolution and shock microstructures of igneous pyroxene clasts in the Northwest Africa 7533 Martian meteorite

Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.     

Chemistry of the heavily urbanized Bagmati River system in Kathmandu Valley, Nepal: export of organic matter, nutrients, major ions, silica, and metals

Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH₄, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km^?2 year^?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km^?2 year^?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km^?2 year^?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering.     

Mineral inclusions in fibrous diamonds: constraints on cratonic mantle refertilization and diamond formation

We analyzed mineral microinclusions in fibrous diamonds from the Wawa metaconglomerate (Superior craton) and Diavik kimberlites (Slave craton) and compared them with published compositions of large mineral inclusions in non-fibrous diamonds from these localities. The comparison, together with similar datasets available for Ekati and Koffiefontein kimberlites, suggest a general pattern of metasomatic alteration imposed on the ambient mantle by formation of fibrous diamond. Calcium and Fe enrichment of peridotitic garnet and pyroxenes and Fe enrichment of olivine associated with fibrous diamond-forming fluids contributes to refertilization of the cratonic mantle. Saline—carbonatitic—silicic fluid trapped by fibrous diamonds may represent one of the elusive agents of mantle refertilization. Calcium enrichment of peridotitic garnet and pyroxenes is expected in local mantle segments during fibrous diamond production, as Ca in the carbonatitic fluids is deposited into the surrounding mantle when oxidized carbon is reduced to diamond. Harzburgitic garnet evolves towards Ca-rich compositions even when it interacts with Ca-poor saline fluids. An unusual trend of Mg enrichment to Fo_95–98 is observed in some olivine inclusions in Wawa fibrous diamonds. The trend may result from the carbonatitic composition of the fluid that promotes crystallization of magnesian olivine and preferentially oxidizes the fayalite component. We propose a generic model of fibrous and non-fibrous diamond formation from carbonatitic fluids that explains enrichment of the mantle in mafic magmaphile and incompatible elements and accounts for locally metasomatized compositions of diamond inclusions.     

Coral reef ecosystems protect shore from high-energy waves under climate change scenarios

Coral reefs and other coastal ecosystems such as seagrasses and mangroves are widely recognized to provide protection against the devastating effects of strong waves associated with tsunamis and storms. The predicted warming climate brings to fore the role of these ecosystems in providing protection against stronger typhoons that can result in more devastating waves of greater amplitude. We performed a model simulation of storm generated waves on a Philippine reef, which is located along the path of tropical storms, i.e., at least 10 typhoons on the average pass through the study site yearly. A model to simulate wave propagation was developed using Simulating Waves Nearshore (SWAN) and DELFT3D-WAVE computer simulation software. Scenarios involving local monsoonal wind forcing and storm conditions were simulated. In addition, as climate change may also result to increased relative sea level, a 0.3 m and 1 m rise in sea level scenarios were also used in the wave model simulations. Results showed that the extensive reef system in the site helped dissipate wave energy that in turn reduced wave run-up on land. A significant reduction in wave energy was observed in both climate change, i.e., stronger wind and higher sea level, and non-climate change scenarios. This present study was conducted in a reef whose coral cover is in excellent condition (i.e., 50 to 80% coral cover). Estimates of coral reef growth are in the same order of magnitude as estimates of relative sea level rise based on tide gauge and satellite altimeter data, thus it is possible that the role of reefs in attenuating wave energy may be maintained if coral reef growth can keep up with the change in sea level. Nonetheless, to maintain reef growth, it is imperative to manage coral reef ecosystems sustainably and to eliminate the stressors that are within human control. Minimizing activities such as illegal and destructive blast and poison fishing methods, pollution and siltation, is crucial to minimize the impacts of high-energy waves that may increase with climate change.     

Cosmic factors influence on the inter-annual variations of the green 557.7 Nm line and red 630.0 Nm line nightglow intensities and their possible coupling with cloud covering at Abastumani (41.75°N, 42.82°E)

We studied the inter-annual distributions of the nightglow intensities of the thermosphere atomic oxygen red 630.0 nm and green 557.7 nm lines observed from Abastumani during cloudless nights, the planetary geomagnetic Ap index, solar F_10.7, and galactic cosmic rays (GCRs) flux. It is demonstrated that: on magnetically weakly disturbed/ quiet conditions (Ap < 12) in equinoctial months the red line intensities are minimal, while those of the green line are maximal; the red line intensity increases in May-July and is comparatively low in June, where, unlike most mid-latitude regions, the green line intensity is maximal. The red and green line intensities increase with growing solar activity but their behaviors stay the same, which is considered as a possible regional manifestation of lower and upper atmosphere vertical coupling. It was also detected that, for cloudless nights in June, the number of magnetically disturbed day-nights is maximal and the decrease of the GCRs flux is the biggest during a year.