Compositional trends among IID irons; their possible formation from the P-rich lower magma in a two-layer core

Group IID is the fifth largest group of iron meteorites and the fourth largest magmatic group (i.e., that formed by fractional crystallization). We report neutron-activation data for 19 (of 21 known) IID irons. These confirm earlier studies showing that the group has a relatively limited range in Ir concentrations, a factor of 5. This limited range is not mainly due to incomplete sampling; Instead, it seems to indicate low solid/liquid distribution coefficients reflecting very low S contents of the parental magma, the same explanation responsible for the limited range in group IVA. Despite this similarity, these two groups have very different volatile patterns. Group IVA has very low abundances of the volatile elements Ga, Sb and Ge whereas in group IID Ga and Sb abundances are the highest known in a magmatic group of iron meteorites and Ge abundances are the second highest (after group IIAB). Group IID appears to be the only large magmatic group having high volatile abundances but low S. In the volatile-depleted groups IVA and IVB it is plausible that S was lost as a volatile from a chondritic precursor material. Because group IID seems to have experienced minimal loss of volatiles, we suggest that S was lost as an early melt having a composition near that of the Fe–FeS eutectic (315 mg/g S). When temperatures had risen 400–500 K higher P-rich melts formed, became gravitationally unstable, and drained through the first melt to form an inner core that was parental to the IID irons. As discussed by [Kracher, A., Wasson, J.T., 1982. The role of S in the evolution of the parental cores of the iron meteorites. Geochim. Cosmochim. Acta 46, 2419–2426], it is plausible that a metal-rich inner core and a S-rich outer core could coexist metastably because stratification near the interface permitted only diffusional mixing. The initial liquidus temperature of the inner, P-rich core is estimated to have been 1740 K; after >60% crystallization the increase in P and the decrease in temperature may have permitted immiscibility with the S-rich outer core. We have not recognized samples of the outer core.     

Shock stage distribution of 2280 ordinary chondrites—Can bulk chondrites with a shock stage of S6 exist as individual rocks?

The brecciation and shock classification of 2280 ordinary chondrites of the meteorite thin section collection at the Institut für Planetologie (Münster) has been determined. The shock degree of S3 is the most abundant shock stage for the H and LL chondrites (44% and 41%, respectively), while the L chondrites are on average more heavily shocked having more than 40% of rocks of shock stage S4. Among the H and LL chondrites, 40–50% are “unshocked” or “very weakly shocked.” Considering the petrologic types, in general, the shock degree is increasing with petrologic type. This is the case for all meteorite groups. The main criteria to define a rock as an S6 chondrite are the solid‐state recrystallization and staining of olivine and the melting of plagioclase often accompanied by the formation of high‐pressure phases like ringwoodite. These characteristics are typically restricted to local regions of a bulk chondrite in or near melt zones. In the past, the identification of high‐pressure minerals (e.g., ringwoodite) was often taken as an automatic and practical criterion for a S6 classification during chondrite bulk rock studies. The shock stage classification of many significantly shocked chondrites (>S3) revealed that most ringwoodite‐bearing rocks still contain more than 25% plagioclase (74%). Thus, these bulk chondrites do not even fulfill the S5 criterion (e.g., 75% of plagioclase has to be transformed into maskelynite) and have to be classified as S4. Studying chondrites on typically large thin sections (several cm²) and/or using samples from different areas of the meteorites, bulk chondrites of shock stage S6 should be extremely rare. In this respect, the paper will discuss the probability of the existence of bulk rocks of S6.     

Shock deformation confirms the impact origin for the Cerro do Jarau,Rio Grande do Sul,Brazil, structure

Cerro do Jarau is a conspicuous, circular morpho‐structural feature in Rio Grande do Sul State (Brazil), with a central elevated core in the otherwise flat “Pampas” terrain typical for the border regions between Brazil and Uruguay. The structure has a diameter of approximately 13.5 km. It is centered at 30^o12′S and 56^o32′W and was formed on basaltic flows of the Cretaceous Serra Geral Formation, which is part of the Paraná‐Etendeka Large Igneous Province (LIP), and in sandstones of the Botucatu and Guará formations. The structure was first spotted on aerial photographs in the 1960s. Ever since, its origin has been debated, sometimes in terms of an endogenous (igneous) origin, sometimes as the result of an exogenous (meteorite impact) event. In recent years, a number of studies have been conducted in order to investigate its nature and origin. Although the results have indicated a possible impact origin, no conclusive evidence could be produced. The interpretation of an impact origin was mostly based on the morphological characteristics of the structure; geophysical data; as well as the occurrence of different breccia types; extensive deformation/silicification of the rocks within the structure, in particular the sandstones; and also on the widespread occurrence of low‐pressure deformation features, including some planar fractures (PFs). A detailed optical microscopic analysis of samples collected during a number of field campaigns since 2007 resulted in the disclosure of a large number of quartz grains from sandstone and monomict arenite breccia from the central part of the structure with PFs and feather features (FFs), as well as a number of quartz grains exhibiting planar deformation features (PDFs). While most of these latter grains only carry a single set of PDFs, we have observed several with two sets, and one grain with three sets of PDFs. Consequently, we here propose Cerro do Jarau as the seventh confirmed impact structure in Brazil. Cerro do Jarau, together with Vargeão Dome (Santa Catalina state) and Vista Alegre (Paraná State), is one of very few impact structures on Earth formed in basaltic rocks.     

Accretionary lapilli from the Sudbury impact event

Meteorite impact‐generated accretionary lapilli are not well studied. The recently discovered distal ejecta from the 1850 Ma Sudbury impact event contain abundant accretionary lapilli generated during the impact and deposited at great distances from the crater. We petrographically and geochemically examined lapilli from five sites (McClure, Connors Creek, Hwy 588, Pine River, and Grand Trunk Pacific, approximately 480–750 km from the center of the Sudbury structure). The compositions of quartz, K‐feldspar, calcite, biotite, and chlorite minerals are similar to each other in all of the samples, although the relative proportions of the minerals vary from site to site. The lapilli occur in a matrix of coarse‐grained quartz, carbonate, and feldspar grains. Zonation within lapilli appears to be due to grain size distribution rather than compositional variation. The inner zones are coarser grained than outer zones. The relative abundances of calcite, phyllosilicates, and feldspars are similar in each zone within individual lapilli. A meteoritic component is indicated by up to 1.8 ppb Ir in one lapillus from the Pine River site, and Ni and Cr ratios are on a chondritic trend line for many of the lapilli. Mechanisms previously proposed for accretionary lapilli formation seem inadequate to explain deposition of distal accretionary lapilli resulting from impact events. A new mechanism for upper atmospheric accretion is proposed, whereby ash ejected from impact events concentrates at altitudes of neutral buoyancy, where it then accretes and is deposited later than ballistically emplaced particles. Likely, multiple processes are taking place in the chaotic postimpact environment.     

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.     

Field verification of a theoretical model to predict the dynamic response of a soft clay deposit

A 40-m thick clay deposit was subjected to sinusoidal excitations using a foundation block and an eccentric mass type vibrator. The response of the foundation block and the surrounding soil was measured using geophones inside the soil and on the surface. The phase shift between the excitation signal and the response signal, the accelerations of the foundation block and the particle velocities in the soil are compared with those obtained from a frequency-dependent numerical model based on the exact analytical solution for the boundary value problem of a rectangular foundation resting on a linear elastic halfspace.