Sunspots: Their rotation,their expansion in the activity zone,their links with the giant convective cells

The rotational properties of sunspots during the time interval 1977–1986 (solar cycle 21) are studied; only sunspot groups older than 4 days have been the object of this research. We have looked systematically for any kind of anomaly or fine structure in the differential rotation latitudinal profile and any significant change occurring during the course of the solar cycle.Some latitudinal bands are found where the angular rotation rate, rather than decreases according to its overall tendency, increases or is constant with the latitude. The differential rotation profile is, therefore, finely structured. The whole fine-structure pattern is affected by a slow equatorward shift. It is suggested that these fine structure features are due to the Coriolis forces acting on the meridional motions associated with giant toroidal convective cells. Some of the properties of such cells are inferred.Moreover, while the spot zone shifts equatorward, it is found to expand poleward; this expansion occurs by the addition of new belts of activity on the poleward side of the pre-existing active zone. The active zone is therefore found to consist, at the maximum activity epoch, of three different belts of spot production, each of them being centered around a local maximum-activity latitude; each of these centroids of activity is hypothesized to lie where a couple of meridional streams - associated with giant cells - converge. The activity belts are independent of each other as far as their activation, maximum, and end time, as well as their lifetime and level of activity are concerned. The angular rotation rate is correlated, in each belt, with the local level of activity.     

Chemical characterization of fine particulate matter during peak PM10 episodes in Apulia (South Italy)

Some peak PM10 episodes, occurred during PM monitoring campaigns performed on October 2005 and February and June 2006 in Bari town, have been characterized. Moreover back trajectories of air masses and Principal Component Analyses were applied. Three of the peak PM10 episodes investigated were related to local emissions of primary pollutants during poor atmospheric dispersion conditions. The other two peak PM10 episodes considered are related with long range transport air masses toward Apulia region: in one case the chemical characterization and the back trajectories analysis indicate that high PM10 value detected is due to the Saharan dust advection in the Apulia region; in the other case air masses with different origin give rise to high PM10 value.Moreover PM10 daily mean concentrations, presented in this paper collected from January 2005 to August 2007 and obtained by automatic device in six stations of air quality monitoring networks in Bari territory, do not show a seasonal trend for PM10 concentrations, contrary to the PM10 trend shown in the towns of North Italy. This can be explained mostly considering that our region presents generally meteo-climatic conditions that favour pollutants dispersion.     

The amphipod Talitrus saltator as a bioindicator of human trampling on sandy beaches

The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.     

Separation of magnetic anomalies into induced and remanent magnetization contributions

Inversion of magnetic data is complicated by the presence of remanent magnetization, and it provides limited information about the magnetic source because of the insufficiency of data and constraint information. We propose a Fourier domain transformation allowing the separation of magnetic anomalies into the components caused by induced and remanent magnetizations. The approach is based on the hypothesis that each isolated source is homogeneous with a uniform and specific Koenigsberger ratio. The distributions of susceptibility and remanent magnetization are subsequently recovered from the separated anomalies. Anomaly components, susceptibility distribution and distribution of the remanent and total magnetization vectors (direction and intensity) can be achieved through the processing of the anomaly components. The proposed method therefore provides a procedure to test the hypotheses about target source and magnetic field, by verifying these models based on available information or a priori information from geology. We test our methods using synthetic and real data acquired over the Zhangfushan iron-ore deposit and the Yeshan polymetallic deposit in eastern China. All the tests yield favourable results and the obtained models are helpful for the geological interpretation.