A calderas field at the Marifil Formation, new volcanogenic interpretation, Norpatagonian Massif, Argentina

Major volcanogenic structures within the Marifil Formation allowed to determine the location of a claderas field that spreads along 400 kilometers. This field has at least three large calderas with diameters near to 100 kilometers, recognizable by regional distribution of associated dikes and rhyolite lava flows present at the caldera border that separates a monotonous ignimbritic plateau from a depressed (150 meters) inner volcanic collapsed caldera. The Marifil ignimbritic plateau cover more than 50,000 square kilometers with thicknesses that reach 800 meters. Associated with these plateau ignimbrites there is an important fluorite mineralization.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Argon isotope fractionation induced by stepwise heating

Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by ⁴⁰Ar-³⁹Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by ³⁸Ar/³⁶Ar and ⁴⁰Ar/³⁶Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric ⁴⁰Ar/³⁶Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems.In ⁴⁰Ar-³⁹Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly precise dating technique. Our results also indicate the importance of thermally activated diffusion as a possible fractionation mechanism, e.g., for hydrothermal gas exhalations, or for carbonaceous carrier phases such as “Q” in meteorites that have been suggested as carriers of highly fractionated noble gas residues from the early solar nebula.     

Quantifying Organization of Atmospheric Turbulent Eddy Motion Using Nonlinear Time Series Analysis

Using three methods from nonlinear dynamics, we contrast the level of organization inthe vertical wind velocity (w) time series collected in the atmospheric surface layer(ASL) and the canopy sublayer (CSL) for a wide range of atmospheric stability ()conditions. The nonlinear methods applied include a modified Shannon entropy, waveletthresholding, and mutual information content. Time series measurements collected overa pine forest, a hardwood forest, a grass-covered forest clearing, and a bare soil, desertsurface were used for this purpose. The results from applying all three nonlinear timeseries measures suggest that w in the CSL is more organized than that in the ASL, and that as the flows in both layers evolve from near-neutral to near-convective conditions, the level of organization increases. Furthermore, we found that the degree of organization in w associated with changes in is more significant than the transition from CSL to ASL.     

Linear discriminant analysis to describe the relationship between rainfall and landslides in Bogotá, Colombia

Bogotá is located in the central Andean region of Colombia, which is frequently affected by landslide processes. These processes are mostly triggered during the rainy season in the city. This fact remarks the importance of determining what rain-derived parameters (e.g. intensity, antecedent rain, daily rain) are better related with the occurrence of landslides. For this purpose, the linear discriminant analysis (LDA), a technique derived from multivariate statistics, was used. The application of this type of analysis led to obtain simple mathematical functions that represent the probability of occurrence of landslides in Bogotá. The functions also allow to identify the most relevant variables derived from records of rainfall linked to the generation of landslides. A proof of concept using the proposed methodology was done using historic rainfall data from a 9-km² area of homogenous climatology and geomorphology in the south part of Bogotá. Landslides needed to be grouped for the LDA. Each one of these grouping categories represents landslides that occurred in similar geomorphologic conditions. Another set of events with no landslides was generated synthetically. Results of the proof of concept show that rainfall parameters such as normalized rainfall intensity I _MAP, normalized daily rainfall R _MAP and rainy-days normal RDN have the best statistical correlation with the landslides observed in the zone of analysis.     

The Juchatengo complex: an upper-level ophiolite assemblage of late Paleozoic age in Oaxaca,southern Mexico

International Journal of Earth Sciences - The Juchatengo complex (JC) suite is located between the Proterozoic Oaxacan complex to the north and the Xolapa complex to the south, and was amalgamated...     

Impacts of Wildlife on Agriculture: A Spatial-Based Analysis and Economic Assessment for Reducing Damage

Over the last few years, the impacts of wildlife on agriculture have constantly been growing, in particular in areas close to woodland and in hunting ban zones (“refuge effect”). Public administrations have difficulty in meeting the growing requests for crop damage compensation. The development of appropriate measures to control this trend—starting from the understanding of the dynamics concerned—is crucial. The aim of this study was, therefore, to analyze damage at regional scale and define common local actions. In particular, the study involved different steps that define a spatial-based classification of risk levels, integrating statistical methods (principal component analysis and receiver operating characteristic) with multi-criteria evaluation (MCE) in a geographic information system (GIS). It turns out that, in the study area, the very high-risk zones affect 8.83% of used agricultural areas; about 97% of them concentrated in the first 400 m from the most suitable habitats. A selected cluster of 11 test areas within these zones allowed us to assess the cost-effectiveness of integrated prevention and control actions (IPCA) with respect to the compensation of the damage. The analysis shows cost of IPCA to be nearly twice the actual cost incurred by the public administration to compensate partially the damage. The comparison with the estimated damage shows the overall economic convenience of the proposed investment with significant differences depending on the areas. Thus, we suggest reaching an “agro-ecological” balance starting from actions on specific areas; if they produce the desired effects, they could be progressively extended to other areas with gradual investments (adaptive management).

     

Monte Verde,South-Central Chile: Stratigraphy,climate change,and human settlement

Two sedimentary units are recognized by means of stratigraphic and sedimentological analyses at Monte Verde, a late Pleistocene archeological site with stone tools and well-preserved wood artifacts and botanical remains, that lies southwest of Lago Llanquihue and north of the Golfo de Reloncavi in the southern end of the Chilean Central graben. the geological evidence shows that at no time after 33,000 yr B.P., and perhaps since the first Llanquihue advance (before 56,000 yr B.P.), was the Monte Verde area covered by ice. Influences of two glacial advances at 20,000 and 15,000-14,500 yr B.P. are recognized at the site; effects of the Varas Interstade, however, are not identified. Rapid climatic change took place after the end of the Llanquihue Glaciation. It was shortly interrupted by a cool, wet period around 10,000 yr B.P., after which a well-documented Hypsithermal (8270-4750 yr B.P.) accompanied by pyroclastic vulcanism followed. The evidence indicates that around 13,000 yr B.P. 1) the site occupants settled on the sandy point bars and beaches of the old creek channel and 2) the area was habitated during cool and wet conditions similar to those that prevail in the area today. Evidence for reconstruction of the paleo-environment and climate of the terminal Pleistocene and the preliminary implications of these findings for understanding the human occupation at Monte Verde are discussed.     

Seismic stratigraphy of Lago Puyehue (Chilean Lake District): new views on its deglacial and Holocene evolution

Prior to the collection of a series of sediment cores, a high- and very-high-resolution reflection seismic survey was carried out on Lago Puyehue, Lake District, South-Central Chile. The data reveal a complex bathymetry and basin structure, with three sub-basins separated by bathymetric ridges, bedrock islands and interconnected channels. The sedimentary infill reaches a thickness of >200 m. It can be sub-divided into five seismic-stratigraphic units, which are interpreted as: moraine, ice-contact or outwash deposits (Unit I), glacio-lacustrine sediments rapidly deposited in a proglacial or subglacial lake at the onset of deglaciation (Unit II), lacustrine fan deposits fed by sediment-laden meltwater streams in a proglacial lake (Unit III), distal deposits of fluvially derived sediment in an open, post-glacial lake (Unit IV) and authigenic lacustrine sediments, predominantly of biogenic origin, that accumulated in an open, post-glacial lake (Unit V). This facies succession is very similar to that observed in other glacial lakes, and minor differences are attributed to an overall higher depositional energy and higher terrigenous input caused by the strong seismic and volcanic activity in the region combined with heavy precipitation. A long sediment core (PU-II core) penetrates part of Unit V and its base is dated as 17,915 cal. yr. BP. Extrapolation of average sedimentation rates yields an age of ca. 24,750 cal. yr. BP for the base of Unit V, and of ca. 28,000 cal. yr. BP for the base of Unit IV or for the onset of open-water conditions. This is in contrast with previous glacial-history reconstructions based on terrestrial records, which date the complete deglaciation of the basin as ca. 14,600 cal. yr. BP. This discrepancy cannot be easily explained and highlights the need for more lacustrine records from this region. This is the second in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre and E. Chapron.