Distribution and reactivity of oxyanions (Sb, As, V, Mo) in the surface freshwater reaches of the Gironde Estuary (France)

The present work reports on the temporal variations of Sb, As, V and Mo concentrations in the surface freshwater reaches of the Gironde Estuary (SW France). Dissolved (<0.2 and <0.02 μm) and particulate Sb, As, V and Mo concentrations were measured in samples collected with high temporal resolution (every 30 min) during two consecutive tides at a fixed station located upstream of the city of Bordeaux and the maximum turbidity zone (MTZ). In addition, measurements of suspended particulate matter concentration, physico-chemical parameters, Cl⁻ concentration, water depth, current velocity and particulate Th concentration were performed either at the same time resolution or continuously. The data obtained suggested that variations in particulate As, V and Mo concentrations were most probably related to tidal cycling near the sampling site of fine grained particles from the MTZ located downstream. Significant differences in the behavior of the dissolved target oxyanions, mostly present in the <0.02 μm fraction, occurred. The behavior of Sb was conservative. Variations of the dissolved As and V concentrations showed similar cycling trends, strongly related to tidal cycles. These As and V cycles were interpreted as a mixing between upstream freshwater and downstream water enriched in dissolved As and V by desorption from the MTZ particles. The observed trend in the variation of the dissolved Mo was more complex than that of As and Sb and attributed to the mixing of the water bodies mentioned above coupled to a point source input of dissolved Mo from an intra-estuarine source. The contribution of this suspected Mo source to the dissolved Mo concentrations measured at the sampling site was estimated from the ratio of dissolved Mo to dissolved As concentrations. The additional dissolved Mo signal, coupled to the monitored ebb and flood length and associated current velocities, suggested an anthropogenic input which may derive from industrial activity near the city of Bordeaux. Extrapolating these results to the annual scale suggested that this dissolved Mo may be equivalent to 45-90% of the annual dissolved Mo flux into the Garonne Branch, highlighting the importance to further investigate the origin and behavior of Mo in the fluvial estuary near Bordeaux.     

Three-dimensional reconstruction of fluvial surface sedimentology and topography using personal mobile laser scanning

High-resolution quantification of fluvial topography has been enabled by a number of geomatics technologies. Hyperscale surveys with spatial extents of <1 km² have been widely demonstrated by means of terrestrial laser scanning (TLS) and structure-from-motion (SfM) photogrammetry. Recent advances in the development and integration of global navigation satellite system (GNSS), inertial measurement unit (IMU) and lightweight laser scanning technologies are now resulting in the emergence of personal mobile laser scanners (MLS) that have the potential to increase data acquisition and processing rates by one to two orders of magnitude compared to TLS/SfM, and thus challenge the recent dominance of these technologies. This investigation compares a personal MLS survey using a Leica Pegasus Backpack that integrates Velodyne Puck VLP-16 sensors, and a multi-station static TLS survey using a Riegl VZ-1000 scanner, to produce digital elevation models (DEMs) and surface sedimentology maps. The assessment is undertaken on a 500 m long reach of the braided River Feshie. Comparison to 107 independent real-time kinematic (RTK)-GNSS check points resulted in similar mean error (ME) and standard deviation error (SDE) for TLS (ME = −0.025 m; SDE = 0.038 m) and personal MLS (ME = −0.014 m; SDE = 0.019 m). Direct cloud-to-cloud (C2C) comparison between a sample of TLS and personal MLS observations (2.8 million points) revealed that C2C distances follow a sharply decreasing Burr distribution (a = 2.35, b = 3.19, rate parameter s = 9.53). Empirical relationships between sub-metre topographic variability and median sediment grain size (10–100 mm) demonstrate that surface roughness from personal MLS can be used to map median grain size. Differences between TLS and personal MLS empirical relationships suggest such relationships are dependent on survey technique. Personal MLS offers distinct logistical advantages over SfM photogrammetry and TLS for particular survey situations and is likely to become a widely applied technique. © 2019 John Wiley & Sons, Ltd.     

Chemical characteristics of groundwater around two massive sulphide deposits in an area of previous mining contamination, Iberian Pyrite Belt, Spain

A detailed chemical study of groundwater was carried out to elucidate the processes controlling the oxidation and dissolution of sulphide minerals at two massive sulphide deposits in the Iberian Pyrite Belt (IPB), i.e. the mined La Zarza deposit and the unmined Masa Valverde deposit. It was found that major-element compositions varied according to the hydrological regime, La Zarza being in a relatively high area with groundwater recharge (and disturbance due to the human factor) and Masa Valverde being in a relatively low area with groundwater discharge. The variations mainly concern pH, Eh, SO₄ and Na concentrations. Metal concentrations were determined (a) by ICP-MS after filtration, and (b) in some cases by voltammetric measurement of Cu, Pb, Zn, Cd and Mn using the Voltammetric In situ Profiling (VIP) System, which allows detection of only the mobile fractions of trace elements (i.e., free metal ions and small labile complexes a few nanometers in size). If one compares the results obtained by each of the two methods, it would appear that the groundwater shows significant enhancement of metal solubility through complexing with organic matter and/or adsorption onto colloids and/or small particles. In areas of sulphide oxidation, however, this solubility enhancement decreases according to Cu>Zn>Cd>Pb. Under very low redox conditions, the attained metal concentrations can be several orders of magnitude (up to 10⁸–10⁹ for Cu and 10²–10³ for Pb) larger than those expected from equilibrium with respect to sulphide minerals as calculated with the EQ3NR geochemical code; Zn concentrations, however, are close to equilibrium with respect to sphalerite. The implication of these results is discussed with respect both to mineral exploration and to environmental issues.