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1.
C. Moreno R. Sáez F. González G. Almodóvar M. Toscano G. Playford A. Alansari S. Rziki A. Bajddi 《Mineralium Deposita》2008,43(8):891-911
The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south
of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The
hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern
orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized
as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal
gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation
of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition
and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical
data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary
below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization
of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age
of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints. 相似文献
2.
L. Moreno J. J. Durán M. A. Casermeiro J. R. Quintana Ma A. Fernández 《Environmental Geology》2008,54(3):465-477
Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored
to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the
best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate
is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is
almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil
and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass
discharged was relatively large (COD 14,656 g/m2, NO3 85 g/m2, NO2 4 g/m2, NH4 2,425 g/m2, PO4 1,143 g/m2, K 1,531 g/m2, B 63 g/m2). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO4 94.4%, K 59.17%, N
total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was
eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts
of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of
the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water,
and are proposed as the best indicators. 相似文献
3.
A. van Geen K. Radloff Z. Aziz Z. Cheng M.R. Huq K.M. Ahmed B. Weinman S. Goodbred H.B. Jung Y. Zheng M. Berg P.T.K. Trang L. Charlet J. Metral D. Tisserand S. Guillot S. Chakraborty A.P. Gajurel B.N. Upreti 《Applied Geochemistry》2008
One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored. 相似文献
4.
Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (FeR) in the absence and presence of 2 μM Dp, FeR being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H2O2 and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for FeR. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for FeR, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of FeR ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column. 相似文献
5.
6.
J. Nicholson I. Broker J. A. Roelvink D. Price J. M. Tanguy L. Moreno 《Coastal Engineering》1997,31(1-4)
Five different coastal area morphodynamic models have been set up to run on the same offshore breakwater layout and an intercomparison carried out on the hydrodynamic and morphodynamic output produced by each scheme. In addition, the predicted morphodynamics was checked against available laboratory and field data.It is concluded that the models are capable of producing realistic estimates for the dominant morphodynamic features associated with offshore breakwaters. Coupling of the wave, current and sediment transport components of each scheme is shown to yield bathymetry which attains a state of equilibrium, unlike models which are based on the initial transport field only. 相似文献
7.
Spectroscopic observations in the spectral region 6000–6600 » of major belts and zones of Jupiter have been carried out at Calar Alto Observatory (Spain) during the 1987 opposition, in support to the International Jupiter Watch Program. More than a hundred long-slit, medium resolution spectra have been taken at the coudé focus of the 1.52 m telescope. The longitudinal and latitudinal distribution of the equivalent widths of the methane and ammonia absorption bands at 6190 » and 6450 » have been investigated. Unlike the CH4-6190 » band, the longitudinal distribution in the NH3-6450 » band shows asymmetries in some of the Jovian regions analyzed, being the absorption greater at West than at East limbs. These results are interpreted in terms of inhomogeneous scattering models by the simultaneous variation of the NH3 cloud optical thickness and its altitude level. The north-south scans show little latitudinal dependence on absorption in both methane and ammonia bands, although some relationship could be established between the absorption and relative continuum reflectivity variation.
Also at Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Granada, Campus Universitario Fuentenueva, Granada, Spain. 相似文献
Resumen Se presentan los resultados obtenidos de las observaciones espectroscópicas de las principales zonas y cinturones de Júpiter realizadas durante la oposición de 1987 como una contribución al International Jupiter Watch Program. Las observaciones fueron llevadas a cabo haciendo uso del foco coudé del telescopio de 1.52 m del observatorio hispanoalemán de Calar Alto (España), habiéndose obtenido algo más de cien espectros, de resolución media, en la región espectral de 6000–6600 ». Se exponen los resultados de las anchuras equivalentes de las bandas de absorción del metano en 6190 » y del amoniaco en 6450 », estudiándose, al mismo tiempo, la distribución tanto longitudinal como latitudinal de las mismas. Mientras que los resultados para la banda del metano presentan un comportamiento simétrico en todas las regiones analizadas, las anchuras equivalentes para la banda NH3-6450 » presentan un comportamiento asimétrico en algunas regiones del planeta, con una mayor absorción hacia el limbo del oeste que hacia el del este. Los resultados son interpretados en base a un modelo de scattering no homogéneo, variando, simultáneamente, el espesor óptico y la altitud de la nube de amoniaco. Los espectros tomados en la dirección norte-sur, aunque presentan una dependencia latitudinal pequeña en la absorción de las bandas mencionadas, sugieren una relación entre la absorción y las variaciones de reflectividad en el continuo.
Also at Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Granada, Campus Universitario Fuentenueva, Granada, Spain. 相似文献
8.
9.
We compare two geophysical survey measurements of the same type made at different times in order to characterize the change in the geological medium during the elapsed time. The aim of this study is to develop a strategy using a full non-linear inversion algorithm as the interpretation tool. In this way, not only the location and the form of the changes are recovered, but also the changes in the material parameters of the geological medium can be estimated. In order to solve this fully non-linear problem, the so-called ‘multiplicative regularized contrast source inversion’ (MR-CSI) method is employed. The unique property of this iterative method is that it does not solve the forward problem at each iterative step. This makes it possible to use the non-linear inversion algorithm for large-scale computation problems. The numerical results show that by taking into account the non-linear nature of the problem, interpretation of the time-lapse data can be significantly improved, compared with that obtained using linear inversion. 相似文献
10.
Vp and Vs values have been measured experimentally and calculated for granulite-facies lower crustal xenoliths from central Ireland close to the Caledonian Iapetus suture zone. The xenoliths are predominantly foliated and lineated metapelitic (garnet–sillimanite–K-feldspar) granulites. Their metapelitic composition is unusual compared with the mostly mafic composition of lower crustal xenoliths world-wide. Based on thermobarometry, the metapelitic xenoliths were entrained from depths of c. 20–25 ± 3.5 km and rare mafic granulites from depths of 31–33 ± 3.4 km. The xenoliths were emplaced during Lower Carboniferous volcanism and are considered to represent samples of the present day lower crust.Vp values for the metapelitic granulites range between 6.26 and 7.99 km s− 1 with a mean value of 7.09 ± 0.4 km s− 1. Psammite and granitic orthogneiss samples have calculated Vp values of 6.51 and 6.23 km s− 1, respectively. Vs values for the metapelites are between 3.86 and 4.34 km s− 1, with a mean value of 4.1 ± 0.15 km s− 1. The psammite and orthogneiss have calculated Vs values of 3.95 and 3.97 km s− 1, respectively.The measured seismic velocities correlate with density and with modal mineralogy, especially the high content of sillimanite and garnet. Vp anisotropy is between 0.15% and 13.97%, and a clear compositional control is evident, mainly in relation to sillimanite abundance. Overall Vs anisotropy ranges from 1% to 11%. Poisson's ratio (σ) lies between 0.25 and 0.35 for the metapelitic granulites, mainly reflecting a high Vp value due to abundant sillimanite in the sample with the highest σ. Anisotropy is probably a function of deformation associated with the closure of the Iapetus ocean in the Silurian as well as later extension in the Devonian. The orientation of the bulk strain ellipsoid in the lower crust is difficult to constrain, but lineation is likely to be NE–SW, given the strike-slip nature of the late Caledonian and subsequent Acadian deformation.When corrected for present-day lower crustal temperature, the experimentally determined Vp values correspond well with velocities from the ICSSP, COOLE I and VARNET seismic refraction lines. Near the xenolith localities, the COOLE I line displays two lower crustal layers with in situ Vp values of 6.85–6.9 and 6.9–8.0 km s− 1, respectively. The upper (lower velocity) layer corresponds well with the metapelitic granulite xenoliths while the lower (higher velocity) layer matches that of the basic granulite xenoliths, though their metamorphic pressures suggest derivation from depths corresponding to the present-day upper mantle. 相似文献