Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.     

Calderas,landslides and paleo-canyons on Piton de la Fournaise volcano (La Réunion Island,Indian Ocean)

Based upon a re-interpretation of previous data and a new field campaign, a structural evolution is proposed for the early history of Piton de la Fournaise volcano from 500,000 to 50,000 years. Conceptually, it is shown that the formation of a caldera in which lava flows are contained inside the caldera depression, gives time for erosion to excavate deep canyons on the external slopes of the volcano, for example, the Rivière des Remparts, the Rivière Langevin and the Rivière de l'Est canyons on Piton de la Fournaise volcano. These canyons are infilled when lavas, filling the caldera and overflowing its rim, are able again to flow on the external slopes of the volcano. In the past, this excavating/infilling process has occurred twice following the formation of the Rivière des Remparts and Morne Langevin calderas. The formation of the third caldera, the Plaine des Sables caldera, was followed by the excavation of the current canyons. In addition to this process, two large landslides have been documented in the field. The first, which happened about 300,000 years ago, is apparently the first episode of the break up of Piton de la Fournaise volcano, predating the formation of the four large calderas. The second landslide, which occurred 150,000 years ago and is considered to be less extensive, has carried away the entire southern flank of the Rivière des Remparts caldera.     

Synthesis of seismicity studies for western Alaska

An examination of the Alaskan earthquake catalogs revealed that from 1928 through 1965, twelve earthquakes of magnitudes (M) in the range 5.6 to 7.3 were located in and around Seward Peninsula region of western Alaska. Moreover, a number of earthquakes of M < 5.0 were found to distribute over the same area. Further investigation of the seismicity employing a local seismographic network in the above area showed a higher level of onshore and offshore seismic activity than had been previously recognized. A number of clusters of earthquakes have been identified. Some of them are located in the epicentral areas of past strong earthquakes (M > 5.5) and some are located in areas traversed by mapped faults. The nature of the seismicity as identified with the local network data is primarily crustal over the entire study area. Investigation of focal mechanisms of isolated strong earthquakes or clusters of small earthquakes show normal faulting as the dominant mode of strain energy release in the western part of Alaska. Moreover, in areas lying, approximately, south and north of Kotzebue Sound, the principal components of horizontal stresses tend to orient in the NW-SE and WNW-ESE directions, respectively.     

Relocation of shallow earthquakes in southern Alaska using Joint Hypocenter Determination method

A subset of 2660 shallow earthquakes (0–50 km) that occurred from 1988 to 1996 in south central Alaska between 155°W and 145°W and 59°N and 63°N was relocated using the joint hypocenter determination (JHD) method. Both P- and S-wave observations recorded by the regional seismic network were used. Events were relocated in twenty different groups based on their geographic location and depth using two velocity models. As a result of the relocation, the majority of the hypocenters shifted downward, while the epicenter locations did not change significantly. The distribution of the shallow subduction zone earthquakes indicates the existence of two seismically independent blocks, with one block occupying the northeastern part and the other occupying the central and western parts of the study area. The boundary between the blocks is marked by a 15 to 20 km wide seismicity gap to the southeast of 149.5°W and 62°N. The analysis of the fault plane solutions for shallow subduction zone earthquakes shows that an overwhelming majority of the solutions represent normal, oblique-normal or strike-slip faulting with predominant WNW-ESE orientation of T-axes. This indicates a down-dip extensional regime for the subducting slab at shallow depths. Very few earthquakes yielded fault plane solutions consistent with thrusting on a contact zone between the overriding and subducting plates. This result may be an indication that currently either the strain energy is not released at the contact zone or it is associated with aseismic motion.     

Impact of Hydropower Regulation on River Water Composition in Northern Sweden

Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10–20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself.     

Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.     

Coal mining‐derived ochres in the UK: a potential selenium trap

Thanks to the pioneering research of Paul Younger over the past 20 years, acid mine drainage in the UK has been recognized as a major environmental issue. Acid mine drainage and hydrous ferric oxide deposition are environmental hazards resulting from centuries of extensive coal mining activities across the UK. Oxidative weathering of pyrite in coal from spoil heaps and exposed bedrock can liberate trace elements, releasing them into local water systems. In addition to posing an environmental threat through water and ground contamination, ochres can also act as a remediation material, trapping elements such as selenium. Trace elements with a close association to iron oxides, such as selenium, may fix to the fine‐grained ochre materials, resulting in hyper‐enriched ochres. Selenium in coals has been known to cause an environmental issue in areas of North America but is also an important commodity for solar cells and nanotechnologies. Coal‐bearing areas of the UK, such as Northumberland, are known to contain a high selenium content, and coal‐derived ochres in these regions also contain significant selenium. The widespread occurrence of ochres in UK coal‐mining regions may therefore present a unique ‘E tech’ trace element source and prevent a toxicity problem for which they were once thought to be responsible.     

Extension tardi-orogénique et formation des bassins intracontinentaux: le bassin stéphanien des Cévennes

Résumé

Le bassin carbonifère des Cévennes, voisin du décrochement sénestre de Villefort, a été étudié en intégrant les données sédimentologiques, les données structurales du socle et du remplissage, ainsi que les données de la pétrologie métamorphique du socle. Le remplissage du bassin est contrôlé par des failles subméridiennes induisant une subsidence localisée en début d’ouverture. Cette subsidence devient plus régionale en fin d’histoire. Un grenat mangane- sifère est associé aux minéraux du faciès schistes verts, des blastes d’andalousite recoupent l’ensemble. Cette association minéralogique indique un gradient de température de 50°C/km. Ce gradient est semblable au gradient estimé dans le bassin sur la matière organique. La schistosité porte trois familles de linéation : 1- une famille à biotite-chlorite-quartz, orientée N45 ± 20° et associée à la mise en place des nappes cévenoles; 2- une famille à minéraux phylliteux dont l’orientation est située autour de N90 et associée à l’ouverture du bassin; 3- une famille à minéraux phylliteux orientée NO horizontale sur des plans de schistosité redressés près de la faille de Villefort. La schistosité régionale est affectée par des plis asymétriques, des bandes de cisaillement et des zones cata- clasées, le tout ayant une cinématique en faille normale vers l’Est. Les relations entre ces différentes structures suggèrent un continuum de déformation depuis des niveaux ductiles jusqu’à des niveaux fragiles. Le remplissage du bassin est affecté par des décrochements parallèles à la faille de Ville- fort. Le bassin des Cévennes s’est donc ouvert dans un contexte extensif est-ouest sur une croûte épaissie. La région a ensuite été reprise par des décrochements nord-sud dont celui de Villefort.