Changes in Initial 87Sr/86Sr Ratio during Protracted Fractionation in Igneous Complexes

The Rb/Sr ratios of magmas increase significantly during fractionalcrystallization. Hence, the rate of change of the ⁸⁷Sr/⁸⁶Srratio in successive residual liquids increases as crystallizationproceeds. In slowly solidifying igneous complexes the totalchange in ⁸⁷Sr/⁸⁶Sr ratio exceeds analytical uncertainty andis manifested in several ways. Whole rock ⁸⁷Rb/⁸⁶Sr versus ⁸⁷Sr/⁸⁶Sr plots for an entire complexwill produce errorchrons, which may be improved by consideringsmall subsets of the complex. These subsets will show a generalincrease in initial ⁸⁷Sr/⁸⁶Sr with increasing average Rb/Srratio. Thus, quenched liquids, mineral ages and fractionatedcumulates from the same complex can show different ages andinitial ⁸⁷Sr/⁸⁶Sr ratios. The Murrumbidgee granitoid complex shows parallel isochronsfor geochemically controlled subsets which give an age co-incidentwith the metamorphic aureole while an isochron for the entirecomplex gives an unrealistically old age. Quenched liquids inthe Rosses granitic complex are apparently younger than theirassociated crystal accumulates using conventional isochron interpretations,but this can be reconciled within the magmatic ageing model.Increasing initial ⁸⁷Sr/⁸⁶Sr ratios with height within the BushveldComplex need not be due to several independent magmas but resultfrom slow cooling of two magmas having the same initial ratio.     

Empirical calibration of the silica–Ca-tschermak's–anorthite (SCAn) geobarometer

The pressure-sensitive equilibrium among anorthite, quartz and the Ca-tschermak component in clinopyroxene (CaAl₂SiO₆; CaTs), CaAl₂SiOCpx6+SiOQtz2=CaAl₂Si₂OPl8 (SCAn) ,can be used as a geobarometer in granulites with the proper assemblage, and has been calibrated using mineral composition data from partial melting experiments of natural assemblages and from phase equilibrium experiments on the end-member CMAS system. The experimental data cover the P – T  range 4–32  kbar and 900–1400  °C. Linear least-squares regression analysis of the experimental data resulted in the following empirical expressions for pressure in terms of composition and temperature: P = 5.066 [±0.760]+ 1300 [±800] T  −ln K 276 [±16] · T  [±2.5  kbar]or P = 6.330 [±0.116]−ln K 301 [±9]· T  [±1.0  kbar] ,where K = a PlAn a CpxCaTs  .The first equation incorporates an enthalpy term, but is less accurate than the second equation, in which the enthalpy of reaction is ignored. Application of these expressions to natural and experimental equilibrium mineral assemblages demonstrates that the empirical barometers are applicable over a wide range of pressures (≥4  kbar), temperatures (≥700  °C) and bulk compositions (Mg#≥32.5).     

Carbon fluxes in soil: long-term sequestration in deeper soil horizons

Terrestrial ecosystems represent the second largest carbon reservoir, and the C balance in terrestrial ecosystems can be directly impacted by human activities such as agricultural management practices and land-use changes. This paper focuses on the C-sequestration in soil. Although many studies showed that the concentration of SOC is much higher in the shallow soils (0-30 cm), the deeper horizons represent a much greater mass of soil and represent a huge C-storage pool. The process of preferential retention of more strongly adsorbing components, along with competitive displacement of weakly binding components are the key processes that enhance the movement of organic carbon to deeper soil horizons. DOC represents the most dynamic part of organic carbon in soils, and thus can be used as a timely indicator of the short-term change of C-sequestration. Long-term experiments have demonstrated that higher SOC levels in shallow soils would lead to increased fluxes of DOC to deeper horizons, but more data on a wider range of soils and treatment strategies are needed to fully evaluate the linkages between changes in SOC in shallow soil, vertical fluxes of DOC to deeper soil horizons, and enhanced C-inventories in deeper, slow-turnover SOC pools.     

Anatomy and evolution of a Lower Cretaceous alluvial plain: sedimentology and palaeosols in the upper Blairmore Group, south-western Alberta, Canada

The Lower Cretaceous (Albian) upper Blairmore Group is part of a thick clastic wedge that formed adjacent to the rising Cordillera in south-western Alberta. Regional transgressive intervals are superimposed on the overall regressive succession. Alluvial conglomerates, sandstones and mudstones were deposited in east-north-eastward draining fluvial systems, orientated transverse to the basin axis. Five facies associations have been identified: igneous pebble conglomerate, thick sandstone, interbedded lenticular sandstone and mudstone, thick mudstone with thin sandstone interlayers, and fossiliferous sandstone and mudstone. The facies associations are interpreted as gravelly fluvial channels, sandy fluvial channels, sand-dominated floodplains, mud-dominated floodplains, and marine shoreline deposits, respectively. Five types of palaeosols are recognized in the upper Blairmore Group based on lithology, the presence of pedogenic features (clay coatings, root traces, ferruginous nodules, slickensides, carbonate nodules) and degree of horizonization. The regional distribution of the various types of palaeosols enables a refinement of the palaeoenvironmental reconstruction permitting an assessment of the controls on floodplain evolution. In source-proximal areas, palaeosol development was inhibited by high rates of sedimentation. In source-distal locations, poor drainage resulting from high watertables, low topography and lower rates of sedimentation also inhibited palaeosol development. The best-developed palaeosols (containing Bt horizons) occur in intermediate alluvial plain positions (tectonic hinge zone) where the floodplains were most stable due to a balance between sedimentation, erosion and subsidence rates. Extrapolating from the upper Blairmore Group suggests that the tectonic hinge zone of continental foreland basins can be established by palaeosol analysis. At the hinge zone, soil development is controlled primarily by climate and tectonics and their effect on sediment supply, whereas closer to the palaeoshoreline, relative sea level fluctuations, resulting in poor drainage, may have a more significant influence.     

Policy narratives, landholder engagement, and oil palm expansion on the Malaysian and Indonesian frontiers

Over recent decades a structural transformation has affected agriculture in the frontier areas of Malaysian Borneo and Outer Island Indonesia with the rapid conversion of agricultural lands, fallows, and formerly forested areas into oil palm. These frontiers have similar positions in the international political economy of oil palm and have complementary resource endowments. In both cases, state planners face the common challenges of finding a disciplined labour force, delivering land for estate development, maintaining local legitimacy, and dealing with local contestation. Yet there are significant differences in systems of governance and policy frameworks regarding land, shifting capacity of state actors to facilitate the transformation of these agrarian frontiers, and changing degrees of local, national and international contestation. Considering the generic and the specific elements at play in each case, this paper argues that analogous policy narratives have shaped the ways in which landholders have been engaged in the process of oil palm expansion in Malaysia and Indonesia. In both cases, with the shift from state-led to neoliberal governance approaches to agricultural development, the 'frontier' has been created and transformed through policy narratives that facilitate the conversion of whole landscapes into oil palm. This has been achieved by obscuring indigenous forms of agriculture and land tenure, while creating reserves of available 'state' or 'idle' customary land, and counterpoising smallholder 'marginality' and 'backwardness' to the modernity of contemporary estate agriculture.