Disequilibrium in the Ross of Mull Contact Metamorphic Aureole, Scotland: a Consequence of Polymetamorphism

The Ross of Mull pluton consists of granites and granodioritesand intrudes sediments previously metamorphosed at amphibolitefacies. The high grade and coarse grain size of the protolithis responsible for a high degree of disequilibrium in many partsof the aureole and for some unusual textures. A band of metapelitecontained coarse garnet, biotite and kyanite prior to intrusion,and developed a sequence of textures towards the pluton. InZone I, garnet is rimmed by cordierite and new biotite. In ZoneII, coarse kyanite grains are partly replaced by andalusite,indicating incomplete reaction. Coronas of cordierite + muscovitearound kyanite are due to reaction with biotite. In the higher-gradeparts of this zone there is complete replacement of kyaniteand/or andalusite by muscovite and cordierite. Cordierite chemistryindicates that in Zone II the stable AFM assemblage (not attained)would have been cordierite + biotite + muscovite, without andalusite.The observed andalusite is therefore metastable. Garnet is unstablein Zone II, with regional garnets breaking down to cordierite,new biotite and plagioclase. In Zone III this breakdown is welladvanced, and this zone marks the appearance of fibrolite andK-feldspar in the groundmass as a result of muscovite breakdown.Zone IV shows garnet with cordierite, biotite, sillimanite,K-feldspar and quartz. Some garnets are armoured by cordieriteand are inferred to be relics. Others are euhedral with Mn-richcores. For these, the reaction biotite + sillimanite + quartz garnet + cordierite + K-feldspar + melt is inferred. Usinga petrogenetic grid based on the work of Pattison and Harte,pressure is estimated at 3·2 kbar, and temperature atthe Zone II–III boundary at 650°C and in Zone IV asat least 750°C. KEY WORDS: contact metamorphism; disequilibrium     

Reuse of waste water: impact on water supply planning / Remploi de l'eau résiduaire: influence sur la planification des systèmes de distribution des eaux

Abstract

As the urban population of the world increases and demand on easily developable water supplies are exceeded, cities have recourse to a range of management alternatives to balance municipal water supply and demand. These alternatives range from doing nothing to modifying either the supply or the demand variable in the supply-demand relationship. The reuse or recycling of urban waste water in many circumstances may be an economically attractive and effective management strategy for extending existing supplies of developed water, for providing additional water where no developable supplies exist and for meeting water quality effluent discharge standards. The relationship among municipal, industrial and agricultural water use and the treatment links which may be required to modify the quality of a municipal waste effluent for either recycling or reuse purposes is described. A procedure is described for analysing water reuse alternatives within a framework of regional water supply and waste water disposal planning and management.     

Emplacement and Differentiation of the York Haven Diabase Sheet, Pennsylvania

Many of the high-Ti quartz-normative tholeiitic intrusive sheetsin the early Mesozoic rift basins of the Eastern USA exhibitlateral differentiation from mafic cumulate units, through diabase,to relatively evolved iron-rich rock types. We have investigateda representative example in detail, the York Haven sheet inthe Gettysburg basin of south–central Pennsylvania. Itranges in thickness from 330 m to 675 m, and we have sampledit from base to top along four separate stratigraphic sectionsevenly spaced over the extent of the intrusion. The easternmostsection (York Haven) is entirely basaltic bronzite cumulate(average 15 vol. % bronzite), whereas the westernmost (ReesersSummit) consists of diabase and low-MgO diabase with a middleto upper ‘sandwich zone’ of ferrogabbro. The interveningsections feature rock types transitional between the two end-membersequences. Chemically, the rock series shows a gradual eastto west depletion of compatible elements (Mg, Ca, Ni, and Cr),and enrichment of incompatible elements [Ti, Fe, Na, K, P, Cu,Zr, Th, Ta, Hf, Sb, Cs, As, platinum group elements (PGEs),and rare earth elements (REEs)]. We suggest two main processes for the trends observed in theYork Haven sheet. First, flow differentiation during ascentand lateral injection of the parental magma produced a tongueof basaltic bronzite cumulate that thins from southeast to northwestand passes laterally into diabase, and, at the distal end ofthe intrusion, into low-MgO diabase. Then, in the latter stagesof crystallization, densitydriven hydrothermal fluids transportedincompatible elements westward, into structurally higher partsof the intrusion. Reaction of this residual aqueous fluid withpartly crystallized low-MgO diabase produced a zone of ferrogabbrorich in hydrothermal replacement products (e.g., Cl-amphibole,biotite, ferrohypersthene, and skeletal ilmenite) and precipitates(e.g., quartz, fayalite, Cl-apatite, sulfides, and PGE minerals). ^* Present address: US Geological Survey, Hawaiian Volcano Observatory, Hawaii National Park, Hawaii 96718